0000000000267238

AUTHOR

Gian Piero Pollini

showing 4 related works from this author

Tetramethylguanidine (TMG)-catalyzed addition of dialkyl phosphites to α,β-unsaturated carbonyl compounds, alkenenitriles, aldehydes, ketones and imi…

1998

Abstract Tetramethylguanidine-catalyzed addition of dialkyl phosphites to α,β-unsaturated carbonyl compounds, alkenenitriles, aldehydes and ketones constitutes a practical route to a variety of phosphonate synthons. The very mild conditions employed, together with the short reaction times, make the procedure highly versatile and tolerant to a range of functionalities. The proposed methodology is also convenient for the preparation of α-aminophosphonates.

chemistry.chemical_compoundChemistryOrganic ChemistryDrug DiscoverySynthonOrganic chemistryBiochemistryPhosphonateCatalysis
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ChemInform Abstract: Tetramethylguanidine (TMG)-Catalyzed Addition of Dialkyl Phosphites to α,β-Unsaturated Carbonyl Compounds, Alkenenitriles, Aldeh…

2010

Abstract Tetramethylguanidine-catalyzed addition of dialkyl phosphites to α,β-unsaturated carbonyl compounds, alkenenitriles, aldehydes and ketones constitutes a practical route to a variety of phosphonate synthons. The very mild conditions employed, together with the short reaction times, make the procedure highly versatile and tolerant to a range of functionalities. The proposed methodology is also convenient for the preparation of α-aminophosphonates.

HydroxylationHydroborationchemistry.chemical_compoundchemistrySilylationSynthonOrganic chemistryGeneral MedicinePhosphonateCatalysisChemInform
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ChemInform Abstract: Facile Synthesis of 2-Nitroalkanols by Tetramethylguanidine (TMG)- Catalyzed Addition of Primary Nitroalkanes to Aldehydes and A…

2010

Abstract Tetramethylguanidine-catalyzed addition of primary nitroalkanes to aldehydes and alicyclic ketones constitutes a practical means to perform the nitro-aldol reaction (Henry reaction). The very mild conditions employed, together with the short reaction times, make the procedure tolerant of a range of functionalities and highly versatile for the synthesis of a variety of 2-nitroalkanols.

chemistry.chemical_classificationAlicyclic compoundAddition reactionPrimary (chemistry)Nitroaldol reactionChemistryOrganic chemistryGeneral MedicineCatalysisChemInform
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Facile synthesis of 2-nitroalkanols by tetramethylguanidine (TMG)-catalyzed addition of primary nitroalkanes to aldehydes and alicyclic ketones

1997

Abstract Tetramethylguanidine-catalyzed addition of primary nitroalkanes to aldehydes and alicyclic ketones constitutes a practical means to perform the nitro-aldol reaction (Henry reaction). The very mild conditions employed, together with the short reaction times, make the procedure tolerant of a range of functionalities and highly versatile for the synthesis of a variety of 2-nitroalkanols.

chemistry.chemical_classificationAlicyclic compoundPrimary (chemistry)Nitroaldol reactionChemistryOrganic ChemistryDrug DiscoveryOrganic chemistryBiochemistryCatalysisTetrahedron Letters
researchProduct