0000000001298906

AUTHOR

Laura Cañadillas-delgado

showing 92 related works from this author

All-cis-1,2,3,4,5,6-cyclohexanehexacarboxylate two-dimensional gadolinium(III) complexes: Synthesis, X-ray crystal structure and magnetic properties

2010

Abstract The first gadolinium(III) complexes with the trideprotonated form of the 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H3clhex3−) of formulae [Gd(H3clhex)(H2O)4]n·3nH2O (1) and [Gd(H3clhex)(H2O)4]n·6nH2O (2) have been prepared through the gel technique and their structures determined by single crystal X-ray diffraction. The structure of 1 is made up of 63 honey-comb layers which are generated by [Gd(H2O)4]3+ cations and H3clhex3− anions acting as three-fold nodes and three-fold connectors, respectively. The structure of 2 consists of a [44,62] two-dimensional network extended in the ac plane where the H3clhex−3 groups act as four-fold connectors and the [Gd(H2O)4]3+ units as four-fol…

LigandGadoliniumchemistry.chemical_elementCrystal structureAtmospheric temperature rangeInorganic ChemistryCrystalCurie's lawCrystallographychemistryMaterials ChemistryMetal-organic frameworkPhysical and Theoretical ChemistrySingle crystalPolyhedron
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Copper(II)-methylmalonate complexes with unidentate N-donor ligands: Syntheses, structural characterization and magnetic properties

2009

Abstract Two new methylmalonate-bridged copper(II) complexes with the formulas [Cu(3-Ipy)(Memal)(H 2 O)] ( 1 ) and [Cu(2,4′-bpy)(Memal)(H 2 O)] · 3H 2 O ( 2 ) [Memal = methylmalonate dianion, 3-Ipy = 3-iodopyridine, 2,4′-bpy = 2,4′-bipyridine] have been synthesized and characterized by X-ray diffraction. Both compounds crystallize in the monoclinic space group P 2 1 / n and Z  = 4, with unit cell parameters a  = 8.5874(13) A, b  = 7.1738(14) A, c  = 19.093(5) A, β  = 99.509(15)° in 1 and a  = 17.375(4) A, b  = 7.3305(14) A, c  = 14.247(3) A, β  = 111.409(15)° in 2 . The structures of 1 and 2 consist of zigzag chains of anti-syn carboxylate-bridged copper(II) ions running along the b directi…

DenticityHydrogen bondCoordination polymerchemistry.chemical_elementAtmospheric temperature rangeCrystal engineeringMagnetic susceptibilityCopperInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryMaterials ChemistryPhysical and Theoretical ChemistryMonoclinic crystal systemPolyhedron
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Interplay between spin crossover and proton migration along short strong hydrogen bonds

2021

The iron(ii) salt [Fe(bpp)2](isonicNO)2·HisonicNO·5H2O (1) (bpp = 2,6-bis(pyrazol-3-yl)pyridine; isonicNO = isonicotinate N-oxide anion) undergoes a partial spin crossover (SCO) with symmetry breaking at T1 = 167 K to a mixed-spin phase (50% high-spin (HS), 50% low-spin (LS)) that is metastable below T2 = 116 K. Annealing the compound at lower temperatures results in a 100% LS phase that differs from the initial HS phase in the formation of a hydrogen bond (HB) between two water molecules (O4W and O5W) of crystallisation. Neutron crystallography experiments have also evidenced a proton displacement inside a short strong hydrogen bond (SSHB) between two isonicNO anions. Both phenomena can al…

ChemistryCrystallographyMaterials scienceSpin trappingHydrogen bondSpin crossoverMetastabilityExcited stateMoleculeGeneral ChemistryActivation energyLIESSTChemical Science
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Crystal growth and structural remarks on malonate-based lanthanide coordination polymers

2016

The synthesis, structural characterization and thermal study of new coordination polymers (CPs) of formula [Ln2(mal)3(H2O)5]·2H2O [Ln = Ho (1·2H2O), Tb (1a), Dy (1b), Er (1c) and Yb (1d); mal = malonate], [Ln2(mal)3(H2O)6] [Ln = Sm (2) and Ce (2a)], [Ce2(mal)3(H2O)6]·2H2O (3·2H2O) and [Ce2(mal)3(H2O)3]·2H2O (4·2H2O) are presented. Complexes 1–4 have been also characterized by single crystal X-ray diffraction. The structure of 2 was previously reported (Elsegood, M. R. J., Husain, S., Private Communication, 2014) and it is very close to that of 3. In the light of these results and those previously reported in the literature for malonate-containing lanthanide(III) complexes, a detailed overvi…

Lanthanidechemistry.chemical_classificationMaterials science010405 organic chemistryHydrogen bondSupramolecular chemistryCrystal growthGeneral ChemistryCrystal structurePolymer010402 general chemistryCondensed Matter Physics01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographyMalonatechemistryGeneral Materials ScienceSingle crystalCrystEngComm
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Novel malonate-containing coordination compounds with ligands having N-And NO-donors: Synthesis, structures, and magnetic properties

2012

In our efforts to tune the structures of mixed-ligands malonate-containing coordination compounds, four copper(II) and two high-spin cobalt(II) complexes of formulas [Cu(mal)(H 2O)(dpo)] n (1), [Cu 2(mal) 2(H 2O) 2(dpp)] n · 7nH 2O (2), [Cu 2(mal) 2(H 2O) 2-(bpe)] n · 2nH 2O (3), {[Cu(mal) 2(H 2O) 2][Cu(dien)]} n · 4nH 2O (4)[Co 2(mal) 2(H 2O) 6(dpo)] ·2H 2O(5) and [Co(mal)(H 2O)(phen)] n · 2nH 2O (6) [H 2mal = malonic acid, dpo =4,4'-bipyridine-N,N'-dioxide, dpp = 2,3-bis(pyridyl)pyrazine, bpe =1,2-bis(4-pyridyl)ethylene, dien = diethylenetriamine and phen = 1,10-phenanthroline] have been synthesized and structurally characterized by X-ray diffraction on single crystals. Complexes 1, 2, 4,…

chemistry.chemical_classificationDenticityPyrazineLigandStereochemistryBridging ligandGeneral ChemistryMalonic acidCondensed Matter PhysicsCoordination complexchemistry.chemical_compoundMalonatechemistryDiethylenetriamineGeneral Materials ScienceCrystal Growth and Design
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Intramolecular ferro- and antiferromagnetic interactions in oxo-carboxylate bridged digadolinium(iii) complexes

2010

Two new digadolinium(III) complexes with monocarboxylate ligands, [Gd2(pac)6(H2O)4] (1) and [Gd2(tpac)6(H2O)4] (2) (Hpac = pentanoic acid and Htpac = 3-thiopheneacetic acid), have been prepared and their structures determined by X-ray diffraction on single crystals. Their structures consist of neutral and isolated digadolinium(III) units, containing six monocarboxylate ligands and four coordinated water molecules, the bridging skeleton being built by a muO(1):kappa2O(1)O(2) framework. This structural pattern has already been observed in the parent acetate-containing compound [Gd2(ac)6(H2O)4] x 4 H2O (3) whose structure and magnetic properties were reported elsewhere (L. Cañadillas-Delgado, …

StereochemistryGadoliniumchemistry.chemical_elementAtmospheric temperature rangeMagnetic susceptibilitySquare antiprismInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryIntramolecular forceAntiferromagnetismMoleculeCarboxylateDalton Transactions
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A step further in the comprehension of the magnetic coupling in gadolinium(III)-based carboxylate complexes

2013

Three new gadolinium(III) complexes of formula [Gd4(bta) 3(H2O)16]n·12nH2O (1), [Gd4(bta)3(H2O)12] n·18nH2O (2) and [Gd2(H 2bta)(bta)(H2O)2]n·4nH 2O (3) (H4bta = 1,2,4,5-benzenetetracarboxylic acid) have been synthesized and their structures determined by X-ray diffraction. 1 and 3 are three-dimensional compounds whereas 2 exhibits a two-dimensional structure. The ability of the bta4- to adopt different coordination modes accounts for these high dimensionalities although it precludes a rational structural design. The structures of 1-3 have in common the double oxo-carboxylate bridge between gadolinium(III) ions (μ-O: κ2O,O′) either as a discrete units (1 and 2) or as a chain (3) and one (3)…

DiffractionMetal–organic frameworksStereochemistryGadoliniumchemistry.chemical_elementMagneto–structural correlationsAtmospheric temperature rangeInductive couplingIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMaterials ChemistryAntiferromagnetismMetal-organic frameworkCarboxylatePhysical and Theoretical ChemistryMolecular magnetismGadolinium(III)Polyhedron 52: 321-332 (2013)
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A heteropentanuclear oxalato-bridged [ReIV 4GdIII] complex: synthesis, crystal structure and magnetic properties

2012

The compound (NBu 4) 5[Gd III{Re IVBr 4(μ-ox)} 4(H 2O)]·H 2O (1), with intramolecular antiferromagnetic coupling, is the first Re(iv) system incorporating a 4f ion. © 2012 The Royal Society of Chemistry.

StereochemistryChemistryMetals and AlloysGeneral ChemistryCrystal structureCatalysisAntiferromagnetic couplingSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyIntramolecular forceMaterials ChemistryCeramics and Composites
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Neutron diffraction studies of the molecular compound [Co 2(bta)]n (H4bta =1,2,4,5-benzenetetracarboxylic acid): In the quest of canted ferromagnetism

2013

The exchange mechanism and magnetic structure of the organic-inorganic layered molecule-based magnet [Co2(bta)]n (1) (H 4bta =1,2,4,5-benzenetetracarboxylic acid) have been investigated through variable-temperature magnetic susceptibility measurements and supported with a series of neutron diffraction experiments. Cryomagnetic studies have shown an antiferromagnetic ordering at a transition temperature of 16 K that is followed by the appearance of a weak ferromagnetism below 11 K. The weak antiferromagnetic interlayer interaction plays an important role in this system in spite of the long interlayer separation. A ferromagnetic ordering is induced by applied magnetic fields greater than 1800…

Condensed matter physicsMagnetic structureChemistryTransition temperatureNeutron diffractionMagnetic susceptibilityMagnetic fieldInorganic ChemistryCondensed Matter::Materials ScienceNuclear magnetic resonanceFerromagnetismMagnetAntiferromagnetismCondensed Matter::Strongly Correlated ElectronsPhysical and Theoretical ChemistryInorganic Chemistry
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Dicopper(II) Metallacyclophanes with Electroswitchable Polymethyl-Substitutedpara-Phenylene Spacers

2013

Double-stranded anionic dinuclear copper(II) metallacyclic complexes of the paracyclophane type [Cu2L2]4- have been prepared by the CuII-mediated self-assembly of different para-phenylenebis(oxamato) bridging ligands with either zero-, one-, or four-electron-donating methyl substituents (L=N,N′-para- phenylenebis(oxamate) (ppba; 1), 2-methyl- N,N′-para-phenylenebis(oxamate) (Meppba; 2), and 2,3,5,6-tetramethyl- N,N′-para-phenylenebis(oxamate) (Me4ppba; 3)). These complexes have been isolated as their tetra-n-butylammonium (1 a-3 a), lithium(I) (1 b-3 b), and tetraphenylphosphonium salts (1 c-3 c). The X-ray crystal structures of 1 a and 3 c show a parallel-displaced π-stacked conformation w…

Organic electronicsBromineOrganic electronicsOrganic Chemistrychemistry.chemical_elementGeneral ChemistryPhotochemistryCopperCatalysislaw.inventionIonDensity functional calculationsCrystallographychemistryMetallacycleslawPhenyleneIntramolecular forceMagnetic propertiesCyclic voltammetryElectron paramagnetic resonanceCopperRedox propertiesChemistry - A European Journal
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Well-resolved unusual alternating cyclic water tetramers embedded in a crystal host

2008

Infinite network involving two hydrogen-bonded tetrameric water rings (S4 and D2h) in a (4,4)-square grid crystal host

CrystalCrystallographyChemistryQuantitative Biology::Molecular NetworksGeneral Materials ScienceGeneral ChemistryCondensed Matter PhysicsHost (network)CrystEngComm
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Study of the influence of the bridge on the magnetic coupling in cobalt(II) complexes.

2009

Two new cobalt(II) complexes of formula [Co(2)(bta)(H(2)O)(6)](n) x 2nH(2)O (1) and [Co(phda)(H(2)O)](n) x nH(2)O (2) [H(4)bta = 1,2,4,5-benzenetetracarboxylic acid, H(2)phda = 1,4-phenylenediacetic acid] have been characterized by single crystal X-ray diffraction. Compound 1 is a one-dimensional compound where the bta(4-) ligand acts as 2-fold connector between the cobalt(II) ions through two carboxylate groups in para-conformation. Triply bridged dicobalt(II) units occur within each chain, a water molecule, a carboxylate group in the syn-syn conformation, and an oxo-carboxylate with the mu(2)O(1);kappa(2)O(1),O(2) coordination mode acting as bridges. Compound 2 is a three-dimensional comp…

Models MolecularStereochemistrychemistry.chemical_elementCobaltAtmospheric temperature rangeCrystallography X-RayInductive couplingIonInorganic Chemistrychemistry.chemical_compoundCrystallographyMagneticschemistryFerromagnetismOrganometallic CompoundsMoleculeCarboxylatePhysical and Theoretical ChemistryCobaltSingle crystalInorganic chemistry
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Oligo-m-phenyleneoxalamide Copper(II) Mesocates as Electro-Switchable Ferromagnetic Metal–Organic Wires

2010

Double-stranded copper(II) string complexes of varying nuclearity, from di- to tetranuclear species, have been prepared by the CuII-mediated self-assembly of a novel family of linear homo- and heteropolytopic ligands that contain two outer oxamato and either zero (1 b), one (2 b), or two (3 b) inner oxamidato donor groups separated by rigid 2-methyl-1,3-phenylene spacers. The X-ray crystal structures of these CuIIn complexes (n=2 (1 d), 3 (2 d), and 4 (3 d)) show a linear array of metal atoms with an overall twisted coordination geometry for both the outer CuN2O2 and inner CuN4 chromophores. Two such nonplanar all-syn bridging ligands 1 b–3 b in an anti arrangement clamp around the metal ce…

MetalCrystallographyFerromagnetismStereochemistryChemistryvisual_artOrganic Chemistryvisual_art.visual_art_mediumchemistry.chemical_elementGeneral ChemistryCopperCatalysis
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The Role of Order-Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron (II)…

2012

Neutron diffraction studies have been carried out to shed light on the unprecedented order-disorder phase transition (ca. 155 K) observed in the mixed-valence iron(II)-iron(III) formate framework compound [NH 2(CH3)2]n[FeIIIFe II(HCOO)6]n. The crystal structure at 220 K was first determined from Laue diffraction data, then a second refinement at 175 K and the crystal structure determination in the low temperature phase at 45 K were done with data from the monochromatic high resolution single crystal diffractometer D19. The 45 K nuclear structure reveals that the phase transition is associated with the order-disorder of the dimethylammonium counterion that is weakly anchored in the cavities …

Phase transitionMagnetic structureChemistryNeutron diffraction02 engineering and technologyGeneral ChemistryCrystal structure010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistryCatalysis0104 chemical sciencesCrystallographyColloid and Surface ChemistryFerrimagnetismX-ray crystallographyMultiferroics0210 nano-technologySingle crystal
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Metal-organic coordination frameworks based on mixed methylmalonate and 4,4′-bipiridine ligands: synthesis, crystal structure and magnetic properties

2010

Five new complexes of formulae [M2(4,4′-bpy)(Memal)2X2]n [M = Fe(III) (2), Mn(II) (3), Co(II) (4), Ni(II) (5) and Zn(II) (6), and X = Cl−/OH− (2) and H2O (3–6); 4,4′-bpy = 4,4′-bipyridine and Memal = methylmalonate dianion] have been synthesized by following the previously reported procedure for [Cu2(4,4′-bpy)(Memal)2(H2O)2]n (1). Moreover, two new phases of the Cu(II)/Memal/4,4′-bpy system, namely {[Cu(4,4′-bpy)2][Cu(4,4′-bpy)2(Memal)(NO3)(H2O)]}n·nNO3·3.5nH2O (7) and [Cu(4,4′-bpy)2(Memal)(H2O)]n·nH2O (8), were obtained by varying the synthetic conditions. They were all structurally characterized by single crystal X-ray diffraction, and the magnetic properties of 2–5, 7 and 8 were investig…

DenticityLigandchemistry.chemical_elementGeneral ChemistryCrystal structureCopperCatalysisMetalCrystallographychemistry.chemical_compoundchemistryvisual_artMaterials Chemistryvisual_art.visual_art_mediumAntiferromagnetismCarboxylateSingle crystalNew Journal of Chemistry
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Ferromagnetic coupling and magnetic anisotropy in oxalato-bridged trinuclear chromium(iii)-cobalt(ii) complexes with aromatic diimine ligands

2010

Two novel heterotrinuclear chromium(III)-cobalt(II) complexes of formula {[Cr(III)(bpy)(ox)(2)](2)Co(II)(Me(2)bpy)}.2H(2)O (1) and {[Cr(III)(phen)(ox)(2)](2)Co(II)(Me(2)bpy)}.1.5H(2)O (2) [ox = oxalato, bpy = 2,2'-bipyridine, Me(2)bpy = 6,6'-dimethyl-2,2'-bipyridine, and phen = 1,10-phenanthroline] have been synthesized using the "complex-as-ligand/complex-as-metal" strategy. The X-ray crystal structure of 2 consists of neutral oxalato-bridged Cr(III)(2)Co(II) bent entities formed by the coordination of two anionic [Cr(III)(phen)(ox)(2)](-) complexes through one of their oxalato groups toward a cationic cis-[Co(II)(Me(2)bpy)](2+) complex. The three tris(chelated), six-coordinated metal atom…

ChromiumModels MolecularOxalatesMolecular StructureChemistryStereochemistrySupramolecular chemistryStereoisomerismCobaltCrystal structureCrystallography X-RayLigandsMagnetic susceptibilityInorganic ChemistryMagneticsCrystallographyMagnetic anisotropyIntramolecular forceOrganometallic CompoundsAnisotropyAntiferromagnetismMolecular orbitalIminesDiimineDalton Trans.
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Synthesis, crystal structures and magnetic properties of tricyanomethanide-containing copper(II) complexes

2008

The preparation, crystal structures and magnetic properties of the copper(II) complexes of formula [Cu(pyim)(tcm)(2)](n) (1), [Cu(bpy)(tcm)(2)](n) (2), [Cu(4)(bpz)(4)(tcm)(8)] (3), {[Cu(terpy)(tcm)].tcm}(n) (4) and {[Cu(2)(tppz)(tcm)(4)].3/2H(2)O}(n) (5) [pyim = 2-(2-pyridyl)imidazole, tcm = tricyanomethanide, bpy = 2,2'-bipyridine, bpz = 2,2'-bipyrazine, terpy = 2,2':6',2''-terpyridine and tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine] are reported. Complexes, 1, 2 and 4 are uniform copper(II) chains with single- (1 and 4) and double-(2) micro-1,5-tcm bridges with values of the intrachain copper-copper separation of 7.489(1) (1), 7.520(1) and 7.758(1) (2) and 7.469(1) A (4). Each copper atom …

Inorganic Chemistrychemistry.chemical_compoundCrystallographyDenticityPyrazineOctahedronChemistryOctahedral molecular geometrychemistry.chemical_elementImidazoleCrystal structureCopperSquare pyramidal molecular geometryDalton Transactions
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Dinuclear and two- and three-dimensional gadolinium(III) complexes with mono- and dicarboxylate ligands: synthesis, structure and magnetic properties

2009

Three new gadolinium(III) complexes with carboxylate ligands of formula [Gd2(ac)6(H2O)4]·2H2O (1), [Gd2(ac)2(fum)2(H2O)4]n (2) and [Gd2(ox)(fum)2(H2O)4]n·4nH2O (3) (ac = acetate, fum = fumarate and ox = oxalate) have been prepared and their structures determined by X-ray diffraction on single crystals. The structure of 1 is made up of discrete centrosymmetric di-µ-oxo(carboxylate acetate)digadolinium(III) units with an intramolecular Gd⋯Gd separation of 4.1589(3) A. Each gadolinium atom in 1 is nine-coordinated with two water molecules and seven carboxylate-oxygen atoms from four acetate ligands building a monocapped square antiprism environment. Compound 2 exhibits a sheet-like structure, …

StereochemistryGadoliniumchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsMagnetic susceptibilityOxalateSquare antiprismchemistry.chemical_compoundCrystallographychemistryIntramolecular forceAntiferromagnetismMoleculeGeneral Materials ScienceCarboxylateCrystEngComm
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Influence of the presence of divalent first-row transition metal ions on the structure of sodium(i) salts of 1,2,3,4-benzenetetracarboxylic acid (H4b…

2006

Three different sodium(I)-containing salts of 1,2,4,5-benzenetetracarboxylic (H4bta) of formula [Na4(bta)(H2O)12] (1), [Na2M(H2bta)2(H2O)8]·2H2O] [M = Mn (2) and Ni (3)] were synthesized and their structures were solved by single crystal X-ray diffraction methods. Compound 1 crystallises in orthorhombic system, space group Pc21b with a = 6.9997(4) A, b = 16.4260(9) A, c = 20.3312(18) A, V = 476.30(15) A3 and Z = 4. Compounds 2 and 3 crystallize in the monoclinic system, space group C2/m with a = 7.3778(4) A, b = 20.1493(6) A, c = 10.4963(4) A, β = 103.466(8)°, V = 1517.5(11) A3 and Z = 2 for 1 and a = 7.2862(4) A, b = 20.1165(7) A, c = 10.4032(3) A, β = 103.366(9)°, V = 1483.52(11) A3 and Z…

StereochemistryLigandChemistryHydrogen bondMetal ions in aqueous solutionGeneral ChemistryCondensed Matter Physicslaw.inventionCrystallographylawMoleculeGeneral Materials ScienceOrthorhombic crystal systemCrystallizationIsostructuralMonoclinic crystal systemCrystEngComm
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Synthesis, structural analysis, and magnetic properties of ethylmalonate-manganese(II) complexes

2011

12 páginas, 10 figuras, 6 tablas.-- et al.

EthyleneDenticityLigandStereochemistrychemistry.chemical_elementManganeseInorganic ChemistryMetalchemistry.chemical_compoundCrystallographychemistryvisual_artvisual_art.visual_art_mediumAntiferromagnetismPhysical and Theoretical ChemistryEnantiomerSingle crystal
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Solid-State Aggregation of Metallacyclophane-Based MnIICuII One-Dimensional Ladders

2012

Two distinct one-dimensional (1) and two-dimensional (2) mixed-metal-organic polymers have been synthesized by using the "complex-as-ligand" strategy. The structure of 1 consists of isolated ladderlike Mn(II)(2)Cu(II)(2) chains separated from each other by neutral Mn(II)(2) dimers, whereas 2 possesses an overall corrugated layer structure built from additional coordinative interactions between adjacent Mn(II)(2)Cu(II)(2) ladders. Interestingly, 1 and 2 show overall ferri- and antiferromagnetic behavior, respectively, as a result of their distinct crystalline aggregation in the solid state.

Models Molecularchemistry.chemical_classificationManganeseMolecular StructureTemperatureSolid-statePolymerCrystallography X-RayInorganic ChemistryCrystallographychemistryOrganometallic CompoundsAntiferromagnetismPhysical and Theoretical ChemistryLayer (electronics)CopperInorganic Chemistry
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Synthesis, crystal structure, and magnetic characterization of the three-dimensional compound [Co2(cbut)(H2O) 3]n (H4cbut = 1,2,3,4- cyclobutanetetra…

2014

A novel cobalt(II) complex of formula [Co2(cbut)(H 2O)3]n (1) (H4cbut = 1,2,3,4-cyclobutanetetracarboxylic acid) has been synthesized under hydrothermal conditions and its crystal structure has been determined by means of synchrotron radiation and neutron powder diffraction. The crystal structure of 1 consists of layers of cobalt(II) ions extending in the bc-plane which are pillared along the crystallographic a-axis through the skeleton of the cbut 4- ligand. Three crystallographically independent cobalt(II) ions [Co(1), Co(2), and Co(3)] occur in 1. They are all six-coordinate with four carboxylate-oxygens [Co(1)-Co(3)] and two cis-[Co(1)] or trans-water molecules [Co(2) and Co(3)] buildin…

ChemistryLigandchemistry.chemical_elementCrystal structureHydrothermal circulationIonInorganic ChemistryCrystallographychemistry.chemical_compoundOctahedronMoleculeCarboxylatePhysical and Theoretical ChemistryCobalt
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Dinuclear, tetranuclear and one-dimensional pyrazine-based copper(II) complexes: preparation, X-ray structure and magnetic properties.

2009

The preparation, crystal structures and magnetic properties of the copper(II) complexes of formula [Cu(2)(tppz)(H(2)O)(2)(CF(3)SO(3))(4)] (1), [Cu(tppz)(CrO(4))](n) x 3nH(2)O (2) and [Cu(4)(tppz)(4)(H(2)O)(4)(MoO(4))(2)](CF(3)SO(3))(4) x 7 H(2)O (3) [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine] are reported. Complex 1 is a dinuclear species where tppz adopts a bis-tridentate bridging mode with an intramolecular copper-copper separation of 6.5221(6) A. Each copper(II) ion in 1 has an elongated octahedral geometry with three tppz nitrogen atoms and a water molecule in the equatorial positions and two triflate oxygen atoms occupying the axial sites. Complex 2 is a uniform copper(II) chain where…

Inorganic Chemistrychemistry.chemical_compoundCrystallographychemistryPyrazineOctahedronIntramolecular forceOctahedral molecular geometrychemistry.chemical_elementMoleculeCrystal structureCopperSquare pyramidal molecular geometryDalton transactions (Cambridge, England : 2003)
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Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(iii) complexes with 2,3-quinoxalinediolate ligands

2012

The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(iii) ions in basic media in air affords a new family of carbonato-bridged M 2 III compounds (M = Pr, Gd and Dy), the Dy 2 III analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets. This journal is © 2012 The Royal Society of Chemistry.

Lanthanidechemistry.chemical_classificationLigandChemistryInorganic chemistryMetals and AlloysGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCoordination complexCrystallographyMagnetMaterials ChemistryCeramics and CompositesMagnetic relaxationChemical Communications
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A three-dimensional copper(ii) 12-metallacrown-4 complex with malonomonohydroxamic acid (H3mmh) as a ligand

2011

Slow diffusion of an ethanolic solution of copper(ii) into an aqueous solution of partially deprotonated malonodihydroxamic acid (H4mdh) affords the pentanuclear complex of formula {[K(H2O) 2]2[Cu5(mmh)4]}n (1) (H3mmh = malonomonohydroxamic acid) which is formed by 12-MC-4 metallacrown units with the fifth copper(ii) ion being placed at the center of the square metallacrown unit. The dianionic pentacopper(ii) planar entity interacts with diaquapotassium(i) counterions through the carboxylate-oxygen atoms resulting in a neutral three-dimensional structure. Magnetic susceptibility measurements in the temperature range 1.9-300 K for 1 show the occurrence of relatively strong antiferromagnetic …

LigandInorganic chemistrychemistry.chemical_elementGeneral ChemistryCopperMagnetic susceptibilityCatalysislaw.inventionMetalCrystallographyDeprotonationchemistrylawvisual_artMaterials Chemistryvisual_art.visual_art_mediumAntiferromagnetismElectron paramagnetic resonanceMetallacrownNew Journal of Chemistry
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Photoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(ii) anthracenophane

2011

Thermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(ii) anthracenophane upon UV light irradiation and heating; the two CuII ions (SCu = 1/2) that are antiferromagnetically coupled in the dicopper(ii) metallacyclic precursor (ON state) become uncoupled in the corresponding [4+4] photocycloaddition product (OFF state), as substantiated from both experimental and theoretical studies. © 2011 The Royal Society of Chemistry.

010405 organic chemistryChemistryMetals and AlloysLight irradiation[CHIM.MATE]Chemical Sciences/Material chemistryGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesCatalysisAntiferromagnetic coupling0104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyMaterials ChemistryCeramics and CompositesChemical Communications
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Cobalt(II) Sheet-Like Systems Based on Diacetic Ligands: from Subtle Structural Variances to Different Magnetic Behaviors

2009

The preparation, X-ray crystallography, and magnetic investigation of the compounds [Co(H(2)O)(2)(phda)](n) (1), [Co(phda)](n) (2), and [Co(chda)](n) (3) [H(2)phda = 1,4-phenylenediacetic acid and H(2)chda = 1,1-cyclohexanediacetic acid] are described herein. The cobalt atoms in this series are six- (1) and four-coordinated (2 and 3) in distorted octahedral (CoO(6)) and tetrahedral (CoO(4)) environments. The structures of 1-3 consists of rectangular-grids which are built up by sheets of cobalt atoms linked through anti-syn carboxylate bridges, giving rise to either a three-dimensional structure across the phenyl ring (1 and 2) or to regularly stacked layers with the cyclohexyl groups acting…

Stereochemistrychemistry.chemical_elementRing (chemistry)Magnetic fieldIonInorganic ChemistryCrystallographychemistry.chemical_compoundOctahedronFerromagnetismchemistryTetrahedronCarboxylatePhysical and Theoretical ChemistryCobaltInorganic Chemistry
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Syntheses, crystal structures and magnetic properties of five new manganese(ii) complexes: Influence of the conformation of different alkyl/aryl subs…

2014

et al.

chemistry.chemical_classificationDenticityStereochemistrychemistry.chemical_elementGeneral ChemistryManganeseCrystal structureCondensed Matter PhysicsCrystallographychemistry.chemical_compoundMalonatechemistryGeneral Materials ScienceCarboxylateSingle crystalAlkylSpin canting
researchProduct

Temperature- and pressure-dependent structural study of {Fe(pmd) 2[Ag(CN)2 ]2}n spin-crossover compound by neutron Laue diffraction

2014

The effect of pressure (up to 0.17GPa) on the spin-crossover compound {Fe(pmd)2[Ag(CN)2]2} n [orthorhombic isomer (II), pmd = pyrimidine] has been investigated by temperature- and pressure-dependent neutron Laue diffraction and magnetometry. The cooperative high-spin ↔ low-spin transition, centred at ca 180K at ambient pressure, is shifted to higher temperatures as pressure is applied, showing a moderate sensitivity of the compound to pressure, since the spin transition is displaced by ca 140KGPa-1. The space-group symmetry (orthorhombic Pccn) remains unchanged over the pressure-temperature (P-T) range studied. The main structural consequence of the high-spin to low-spin transition is the c…

Pressure-temperatureChemistryMetals and AlloysSpin transitionChromophoreChromophoresAtomic and Molecular Physics and OpticsSpin-crossover compoundsElectronic Optical and Magnetic MaterialsCrystallographyOctahedronSpin crossoverX-ray crystallographyMaterials ChemistryNeutronOrthorhombic crystal systemMagnetic materialsAmbient pressure
researchProduct

Redox switching of the antiferromagnetic coupling in permethylated dicopper(ii) paracyclophanes

2012

A unique magnetic electroswitching behavior has been observed in an oxamato-based permethylated dicopper(II) paracyclophane; upon reversible one-electron oxidation of the double tetramethyl-substituted p-phenylenediamidate bridging skeleton, the spin alignment of the two Cu(II) ions (S(Cu) = ½) changes from antiparallel (OFF) to parallel (ON) in the resulting dicopper(II) π-radical cation species.

ChemistryMetals and AlloysGeneral ChemistryPhotochemistryRedoxCatalysisAntiferromagnetic couplingSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyMaterials ChemistryCeramics and CompositesAntiparallel (electronics)Chemical Communications
researchProduct

Dicopper(II) metallacyclophanes with photoswitchable oligoacene spacers: a joint experimental and computational study on molecular magnetic photoswit…

2018

Dinuclear copper(II) complexes of the metallacyclophane-type, (nBu4N)4[Cu2(2,6-anba)2] (1) and (nBu4N)4[Cu2(1,5-naba)2]·4H2O (2) with photoactive 2,6-anthracene-(2,6-anba) and 1,5-naphthalenebis(oxamate) (1,5-naba) bridging ligands, are reported. They undergo a thermally reversible, solid-state photomagnetic (ON/OFF) switching between the moderately strong antiferromagnetically coupled dicopper(II) species and the corresponding magnetically uncoupled [4+4] photocycloaddition product. Density functional calculations give further insights on the intramolecular (“pseudo-bimolecular”) photocycloaddition reaction of the two facing 2,6-anthracene or 1,5-naphthalene spacers in this novel family of…

Spintronics010405 organic chemistryChemistryIntermetallicchemistry.chemical_elementOligoacenes010402 general chemistry01 natural sciencesCopper0104 chemical sciencesIonPhotochemical reactivityCrystallographyDensity functional calculationsIntramolecular forceMagnetic propertiesMaterials ChemistryAntiferromagnetismPhotochemical reactivityPhysical and Theoretical ChemistryCopper
researchProduct

Synthesis, crystal structure and magnetic characterization of a series of CuII-LnIII heterometallic [Ln = La, Ce, Pr, Nd and Sm) metal-organic compou…

2013

The synthesis and structural characterization of five Cu(II)-Ln(III) heteronuclear metal-organic frameworks of formula {[Ln4Cu 4(H2O)26(bta)5]·mH 2O}n and {[Ln4Cu4(H 2O)24(bta)5]·pH2O} n [Ln = LaIII (1A/1B), CeIII (2A/2B), Pr III (3A/3B), NdIII (4A/4B) and SmIII (5A/5B) with m/p = 20 (1A)/16 (1B), 18 (2A)/16 (2B), 14 (3A)/16 (3B), 22 (4A)/16 (4B) and 21 (5A)/14 (5B); H4bta =1,2,4,5-benzenetetracarboxylic acid (1-5)] have been performed. These compounds present a single-crystal to single-crystal phase transition from expanded A phases toward the B shrinking networks, which is triggered only in the presence of a dry environment. This phase transition is accompanied by a compression of the cry…

MetalPhase transitionCrystallographyHeteronuclear moleculeChemistryvisual_artCell volumevisual_art.visual_art_mediumGeneral Materials ScienceGeneral ChemistryCrystal structureCondensed Matter PhysicsSingle crystalCrystal Growth and Design
researchProduct

Synthesis, crystal structure and magnetic properties of the cyclic tetranuclear compound [Cu4(pz)4(hppa)2(H2O)4] [pz = pyrazolate; hppa = R,S-2-hydro…

2019

Abstract The synthesis, X-ray structure and magnetic properties of the neutral tetranuclear copper(II) complex of formula [Cu4(pz)4(hppa)2(H2O)4] (1) [Hpz = pyrazole and hppa = R,S-2-hydroxo-2-phenyl-2-(1-pyrazolyl)acetate] are reported. Remarkably, the structure of 1 reveals the presence of the S- and R-forms of the new hppa ligand which is formed in situ in the complex reaction between copper(II), pyrazole and phenylmalonate in water:methanol solvent mixture under ambient conditions. The two crystallographically independent copper(II) ions [Cu(1)/Cu(2)] are five-coordinate in square pyramidal surroundings. Three nitrogen atoms, from two pz groups and one hppa ligand and one oxygen atom of…

010405 organic chemistrychemistry.chemical_elementCrystal structurePyrazole010402 general chemistry01 natural sciencesMagnetic susceptibilityCopperSquare pyramidal molecular geometry0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMaterials ChemistryAntiferromagnetismMoleculeCarboxylatePhysical and Theoretical ChemistryPolyhedron
researchProduct

Influence of the coligand in the magnetic properties of a series of copper(ii)–phenylmalonate complexes

2014

This work presents a series of layered systems based on phenylmalonate-containing copper(II) complexes and different coligands. Eight compounds [Cu(L)(Phmal)]n where L = pyrimidine (pym, 1) pyrazine (pyz, 2), 3-cyanopyridine (3-CNpy, 3), 4-cyanopyridine (4-CNpy, 4), 3-fluoropyridine (3-Fpy, 5), 3-chloropyridine (3-Clpy, 6), 3-bromopyridine (3-Brpy, 7) and 3-iodopyridine (3-Ipy, 8), have been synthesized and magneto-structurally characterized. The coligands selected not only modify the coordination environment of the metal ion, blocking or extending the polymerization, but also interact with the phenyl ring of the phenylmalonate ligand and dramatically affect the crystal packing through weak…

PyrazineStereochemistryLigandchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsRing (chemistry)Magnetic susceptibilityCopperchemistry.chemical_compoundCrystallographysymbols.namesakechemistrysymbolsPhenyl groupGeneral Materials ScienceVan der Waals radiusCarboxylateCrystEngComm
researchProduct

Metallosupramolecular approach toward multifunctional magnetic devices for molecular spintronics

2015

Abstract The work presented in this review constitutes a successful extension of our group's research on the chemistry and physics of dinuclear copper(II) metallacyclophanes with aromatic polyoxalamide ligands. The design and synthesis of metallacyclic complexes that contain multiple electro- and photoactive (either metal- or ligand-based) spin carriers and the study of their spectroscopic and magnetic properties as well as their redox and photochemical activity are of large interest in the multidisciplinary field of metallosupramolecular chemistry. In doing this, a ligand design approach has been followed which is based on the copper(II)-mediated self-assembly of bis(oxamato) bridging liga…

Spintronics010405 organic chemistryChemistryLigandMagnetismSupramolecular chemistryMolecular electronicsNanotechnology010402 general chemistryElectrochemistry01 natural sciences0104 chemical sciencesInorganic ChemistryMagnetochemistryMaterials ChemistryMolecule[CHIM]Chemical SciencesPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUS
researchProduct

Inside Cover: Oligo-m-phenyleneoxalamide Copper(II) Mesocates as Electro-Switchable Ferromagnetic Metal-Organic Wires (Chem. Eur. J. 43/2010)

2010

MetalFerromagnetismChemistryvisual_artOrganic ChemistryInorganic chemistryvisual_art.visual_art_mediumchemistry.chemical_elementCover (algebra)General ChemistryCopperCatalysisChemistry - A European Journal
researchProduct

Low-dimensional copper(II) complexes with the trinucleating ligand 2,4,6-tris(di-2-pyridylamine)-1,3,5-triazine: synthesis, crystal structures, and m…

2010

The preparation and structural characterization of three new copper(II) complexes of formula [Cu(3)(dipyatriz)(2)(H(2)O)(3)](ClO(4))(6) x 2 H(2)O (1), {[Cu(4)(dipyatriz)(2)(H(2)O)(2)(NO(3))(2)(ox)(2)](NO(3))(2) x 2 H(2)O}(n) (2), and [Cu(6)(dipyatriz)(2)(H(2)O)(9)(NO(3))(3)(ox)(3)](NO(3))(3) x 4 H(2)O (3) [dipyatriz = 2,4,6-tris(di-2-pyridylamine)-1,3,5-triazine and ox = oxalate] are reported. The structure of 1 consists of trinuclear units [Cu(3)(dipyatriz)(2)(H(2)O)(3)](6+) and uncoordinated perchlorate anions. The two dipyatriz molecules in 1 act as tris-bidentate ligands with the triazine cores being in a quasi eclipsed conformation. Each copper atom in 1 exhibits a distorted square pyr…

Eclipsed conformationDenticityLigandchemistry.chemical_elementCrystal structureCopperSquare pyramidal molecular geometryInorganic ChemistryPerchloratechemistry.chemical_compoundCrystallographychemistryPhysical and Theoretical ChemistryTriazineInorganic chemistry
researchProduct

Synthesis, structural analysis, and thermal and spectroscopic studies of methylmalonate-containing zinc(II) complexes

2012

The synthesis, crystal structure, thermal analysis and spectroscopic studies of five zinc(II) complexes of formulae [Zn(Memal)(H2O)]n (1) and [Zn2(L)(Memal)2(H2O)2]n (2-5) [H2Memal = methylmalonic acid, and L = 4,4′-bipyridine (4,4′-bpy) (2), 1,2-bis(4-pyridyl)ethylene (bpe) (3), 1,2-bis(4-pyridyl)ethane (bpa) (4) and 4,4′-azobispyridine (azpy) (5)] are presented here. The crystal structure of 1 is a three-dimensional arrangement of zinc(II) cations interconnected by methylmalonate groups adopting the μ3-κ2O:κO’:κO”:κO”’ coordination mode to afford a rare (10,3)-d utp-network. The structures of the compounds 2-5 are also three-dimensional and they consist of corrugated square layers of meth…

ChemistryStereochemistryLigandGeneral Chemical Engineeringchemistry.chemical_elementGeneral ChemistryZincCrystal structureCrystal engineeringFluorescence spectroscopyCrystallographyOctahedronMoleculeThermal analysisComptes Rendus Chimie
researchProduct

Novel cobalt(II) coordination polymers based on 1,2,4,5-benzenetetracarboxylic acid and extended bis-monodentate ligands

2009

Four new high-spin cobalt(II) complexes of formulae [Co2(bta)(4,4′-bpy)2(H2O)2]n (1), {Hbpe[Co(Hbta)(bpe)(H2O)2]}n (2), {[Co(H2bta)(azpy)(H2O)2]·azpy}n (3) and {[Co2(bta)(bpa)2(H2O)4]·8H2O}n (4) with H4bta = 1,2,4,5-benzenetetracarboxylic acid, 4,4′-bpy = 4,4′-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethene, azpy = 4,4′-azobispyridine and bpa = trans-1,2-bis(4-pyridyl)ethane, have been prepared and characterized by single crystal X-ray diffraction. Compounds 1–4 exhibit two-dimensional networks where the fully (1 and 4) or partially (2 and 3) deprotonated tetracarboxylic ligand connects two (2 and 3) or four (1 and 4) cobalt(II) ions through two trans-carboxylate (1–3) or all the carboxyla…

DenticityLigandInorganic chemistrychemistry.chemical_elementGeneral ChemistryCondensed Matter Physicschemistry.chemical_compoundCrystallographyDeprotonationchemistryOctahedronMoleculeGeneral Materials ScienceCarboxylateCobaltSingle crystalCrystEngComm
researchProduct

Two-Dimensional 3d–4f Heterometallic Coordination Polymers: Syntheses, Crystal Structures, and Magnetic Properties of Six New Co(II)–Ln(III) Compounds

2014

Six new heterometallic cobalt(II)-lanthanide(III) complexes of formulas [Ln(bta)(H2O)2]2[Co(H2O) 6]·10H2O [Ln = Nd(III) (1) and Eu(III) (2)] and [Ln2Co(bta)2(H2O)8] n·6nH2O [Ln = Eu(III) (3), Sm(III) (4), Gd(III) (5), and Tb(III) (6)] (H4bta = 1,2,4,5-benzenetretracaboxylic acid) have been synthesized and characterized via single-crystal X-ray diffraction. 1 and 2 are isostructural compounds with a structure composed of anionic layers of [Ln(bta)(H2O)2]n n- sandwiching mononuclear [Co(H2O)6]2+ cations plus crystallization water molecules, which are interlinked by electrostatic forces and hydrogen bonds, leading to a supramolecular three-dimensional network. 3-6 are also isostructural compou…

LanthanideHydrogen bondSupramolecular chemistrychemistry.chemical_elementCrystal structurelaw.inventionInorganic ChemistryCrystallographychemistrylawMoleculePhysical and Theoretical ChemistryCrystallizationIsostructuralCobaltInorganic Chemistry
researchProduct

The construction of open GdIII metal–organic frameworks based on methanetriacetic acid: New objects with an old ligand

2010

11 páginas, 11 figuras, 2 esquemas.-- et al.

LanthanideGadoliniumchemistry.chemical_elementGadoliniumAcetatesCrystallography X-RayLigandsLanthanoid Series ElementsTopologyCatalysisMagnetic propertiesOrganometallic CompoundsMolecular StructureMetal–organic frameworksLigandOrganic ChemistryGeneral ChemistryTrigonal prismatic molecular geometryX-ray diffractionCrystallographychemistryOctahedronTripodal ligandX-ray crystallographyMetal-organic framework
researchProduct

CCDC 1984964: Experimental Crystal Structure Determination

2020

Related Article: Verónica Jornet-Mollá, Carlos Giménez-Saiz, Laura Cañadillas-Delgado, Dmitry S. Yufit, Judith A. K. Howard, Francisco M. Romero|2021|Chemical Science|12|1038|doi:10.1039/D0SC04918B

Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1984962: Experimental Crystal Structure Determination

2020

Related Article: Verónica Jornet-Mollá, Carlos Giménez-Saiz, Laura Cañadillas-Delgado, Dmitry S. Yufit, Judith A. K. Howard, Francisco M. Romero|2021|Chemical Science|12|1038|doi:10.1039/D0SC04918B

Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 294297: Experimental Crystal Structure Determination

2016

Related Article: Fernando S. Delgado, Pablo Lorenzo-Luís, Jorge Pasán, Laura Cañadillas-Delgado, Oscar Fabelo, María Hernández-Molina, Antonio D. Lozano-Gorrín, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2016|CrystEngComm|18|7831|doi:10.1039/C6CE01360K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-malonato)-(malonato)-penta-aqua-di-holmium dihydrate]Experimental 3D Coordinates
researchProduct

CCDC 983489: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado, Juan Rodríguez-Carvajal, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|5674|doi:10.1021/ic500443t

Space GroupCrystallographycatena-(bis(mu6-Cyclobutane-1234-tetracarboxylato)-bis(mu2-aqua)-tetra-aqua-tetra-cobalt)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 294298: Experimental Crystal Structure Determination

2016

Related Article: Fernando S. Delgado, Pablo Lorenzo-Luís, Jorge Pasán, Laura Cañadillas-Delgado, Oscar Fabelo, María Hernández-Molina, Antonio D. Lozano-Gorrín, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2016|CrystEngComm|18|7831|doi:10.1039/C6CE01360K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-malonato)-hexa-aqua-di-samarium]Experimental 3D Coordinates
researchProduct

CCDC 1984958: Experimental Crystal Structure Determination

2020

Related Article: Verónica Jornet-Mollá, Carlos Giménez-Saiz, Laura Cañadillas-Delgado, Dmitry S. Yufit, Judith A. K. Howard, Francisco M. Romero|2021|Chemical Science|12|1038|doi:10.1039/D0SC04918B

Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 958829: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu6-benzene-1245-tetracarboxylato)-(mu2-benzene-1245-tetracarboxylate)-hexacosakisaqua-tetra-copper-tetra-lanthanium icosahydrate]Experimental 3D Coordinates
researchProduct

CCDC 958833: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu6-benzene-1245-tetracarboxylato)-(mu2-benzene-1245-tetracarboxylate)-hexacosakisaqua-tetra-copper-tetra-samarium henicosahydrate]Experimental 3D Coordinates
researchProduct

CCDC 984262: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(bis(mu-benzene-1245-tetracarboxylato)-octaaqua-cobalt(ii)-di-europium(iii) hexahydrate)
researchProduct

CCDC 958838: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu6-benzene-1245-tetracarboxylato)-(mu4-benzene-1245-tetracarboxylate)-tetracosakisaqua-tetra-copper-tetra-samarium tetradecahydrate]Experimental 3D Coordinates
researchProduct

CCDC 996269: Experimental Crystal Structure Determination

2014

Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu~3~-Phenylmalonato)-(pyrazine)-copper)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 996270: Experimental Crystal Structure Determination

2014

Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu~3~-Phenylmalonato)-(nicotinonitrile)-copper)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 996271: Experimental Crystal Structure Determination

2014

Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu~3~-Phenylmalonato)-(isonicotinonitrile)-copper)Experimental 3D Coordinates
researchProduct

CCDC 937587: Experimental Crystal Structure Determination

2014

Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~3~-methylmalonato)-aqua-manganese]Experimental 3D Coordinates
researchProduct

CCDC 984263: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu-benzene-1245-tetracarboxylato)-octaaqua-cobalt(ii)-di-samarium(iii) hexahydrate)Experimental 3D Coordinates
researchProduct

CCDC 996274: Experimental Crystal Structure Determination

2014

Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu~3~-Phenylmalonato)-(3-iodopyridine)-copper)Experimental 3D Coordinates
researchProduct

CCDC 1984961: Experimental Crystal Structure Determination

2020

Related Article: Verónica Jornet-Mollá, Carlos Giménez-Saiz, Laura Cañadillas-Delgado, Dmitry S. Yufit, Judith A. K. Howard, Francisco M. Romero|2021|Chemical Science|12|1038|doi:10.1039/D0SC04918B

Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 945084: Experimental Crystal Structure Determination

2013

Related Article: Laura Cañadillas-Delgado , Oscar Fabelo , J. Alberto Rodríguez-Velamazán , Marie-Hélène Lemée-Cailleau , Sax A. Mason , Emilio Pardo , Francesc Lloret , Jiong-Peng Zhao , Xian-He Bu , Virginie Simonet , Claire V. Colin , and Juan Rodríguez-Carvajal|2012|J.Am.Chem.Soc.|134|19772|doi:10.1021/ja3082457

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[hexakis(mu2-Formato)-iron(ii)-iron(iii)]Experimental 3D Coordinates
researchProduct

CCDC 937589: Experimental Crystal Structure Determination

2014

Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H

Space GroupCrystallographycatena-[(mu~4~-diethylmalonato)-(mu~2~-aqua)-manganese]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1832988: Experimental Crystal Structure Determination

2020

Related Article: Verónica Jornet-Mollá, Carlos Giménez-Saiz, Laura Cañadillas-Delgado, Dmitry S. Yufit, Judith A. K. Howard, Francisco M. Romero|2021|Chemical Science|12|1038|doi:10.1039/D0SC04918B

Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 984264: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(bis(mu-benzene-1245-tetracarboxylato)-octaaqua-cobalt(ii)-di-gadolinium(iii) hexahydrate)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 958834: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679

catena-[tetrakis(mu6-benzene-1245-tetracarboxylato)-(mu4-benzene-1245-tetracarboxylate)-tetracosakisaqua-tetra-copper-tetra-lanthanium hexadecahydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 949613: Experimental Crystal Structure Determination

2018

Related Article: María Castellano, Wdeson P. Barros, Jesús Ferrando-Soria, Miguel Julve, Francesc Lloret, Jorge Pasán, Catalina Ruiz-Pérez, Laura Cañadillas-Delgado, Rafael Ruiz-Garcia, Joan Cano|2018|J.Coord.Chem.|71|675|doi:10.1080/00958972.2018.1433827

Space GroupCrystallographyCrystal Systemtetrakis(tetra-n-butylammonium) bis(mu-22'-(naphthalene-15-diyldiimino)bis(oxoacetato))-di-copper(ii) tetrahydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 937590: Experimental Crystal Structure Determination

2014

Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu~4~-butylmalonato)-aqua-manganese]Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 958835: Experimental Crystal Structure Determination

2014

Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679

Space GroupCrystallographyCrystal Systemcatena-[tetrakis(mu~6~-benzene-1245-tetracarboxylato)-(mu~4~-benzene-1245-tetracarboxylate)-tetracosakisaqua-tetra-copper-tetra-cerium hexadecahydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1984957: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
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CCDC 1475076: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-malonato)-triaqua-di-cerium dihydrate]Experimental 3D Coordinates
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CCDC 937591: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~4~-benzylmalonato)-aqua-manganese]Experimental 3D Coordinates
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CCDC 958832: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu6-benzene-1245-tetracarboxylato)-(mu2-benzene-1245-tetracarboxylate)-hexacosakisaqua-tetra-copper-tetra-neodymium docosahydrate]Experimental 3D Coordinates
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CCDC 945083: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[hexakis(mu2-Formato)-iron(ii)-iron(iii)]Experimental 3D Coordinates
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CCDC 1832962: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
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CCDC 1984960: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(26-bis(1H-pyrazol-3-yl)pyridine)-iron(ii) bis(1-oxopyridine-4-carboxylate) 1-oxopyridine-4-carboxylic acid pentahydrateCell ParametersExperimental 3D Coordinates
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CCDC 937588: Experimental Crystal Structure Determination

2014

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CCDC 294299: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-malonato)-hexa-aqua-di-cerium dihydrate]Experimental 3D Coordinates
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CCDC 958831: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tetrakis(mu~6~-benzene-1245-tetracarboxylato)-(mu~2~-benzene-1245-tetracarboxylate)-hexacosakis(aqua)-tetra-copper-tetra-praseodymium tetradecahydrate]Cell ParametersExperimental 3D Coordinates
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CCDC 984260: Experimental Crystal Structure Determination

2014

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researchProduct

CCDC 958836: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu~6~-benzene-1245-tetracarboxylato)-(mu~4~-benzene-1245-tetracarboxylate)-tetracosakisaqua-tetra-copper-tetra-praseodymium hexadecahydrate]Experimental 3D Coordinates
researchProduct

CCDC 996272: Experimental Crystal Structure Determination

2014

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CCDC 1984963: Experimental Crystal Structure Determination

2020

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CCDC 952343: Experimental Crystal Structure Determination

2013

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CCDC 984265: Experimental Crystal Structure Determination

2014

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CCDC 1911272: Experimental Crystal Structure Determination

2019

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2014

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2014

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2014

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