Phosphororganische Verbindungen, XXVII. Olefinbildung bei der Autoxydation metallierter Phosphinoxyde, Phosphin‐ und Phosphonsäureester (Sulfone und Sulfoxyde)

6533b7d6fe1ef96bd1266ea5

RESEARCH PRODUCT

Phosphororganische Verbindungen, XXVII. Olefinbildung bei der Autoxydation metallierter Phosphinoxyde, Phosphin‐ und Phosphonsäureester (Sulfone und Sulfoxyde)

Hellmut Hoffmann H. Ertel Günter Klahre Leopold Horner Vicente G. Toscano

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Phosphinoxyde, Phosphin- und Phosphonsaureester, deren α-standige Methylengruppe durch Alkalimetall substituiert ist, sind autoxydabel. Steht ein Benzylrest am Phosphor, so entstehen in hohen Ausbeuten die entsprechenden Stilbene. Fur den Reaktionsverlauf werden zwei Moglichkeiten erortert. Metalliertes Phenyl-benzyl-sulfon bzw. -sulfoxyd werden durch Autoxydation in Sulfinat und Benzoat gespalten.

year	journal	country	edition	language
1961-08-01	Chemische Berichte

https://doi.org/10.1002/cber.19610940809

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