Phosphororganische Verbindungen, XXXV. PO‐aktivierte Verbindungen als Olefinierungsreagentien

6533b827fe1ef96bd1285a08

RESEARCH PRODUCT

Phosphororganische Verbindungen, XXXV. PO‐aktivierte Verbindungen als Olefinierungsreagentien

Walter Klink Hellmut Hoffmann Leopold Horner Vicente G. Toscano H. Ertel

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Mit metallierten Mono- und Bis-phosphon- und -phosphinsaureestern sowie Phosphinoxyden werden Mono- bzw. Bis-Olefinierungen von Carbonylverbindungen durchgefuhrt. Phosphonsaureester mit gesattigtem Alkylrest werden durch das Metallierungsmittel gespalten und sind im Gegensatz zu den Alkylphosphinoxyden als Olefinierungsreagentien ungeeignet. Der Einflus verschiedener Faktoren wie Metallierungsmittel, Molverhaltnis, Temperatur und Losungsmittel auf den Reaktionsverlauf wird untersucht.

year	journal	country	edition	language
1962-03-01	Chemische Berichte

https://doi.org/10.1002/cber.19620950302

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