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RESEARCH PRODUCT

Intercalation of two-dimensional oxalate-bridged molecule-based magnets into layered double hydroxide hosts

Eugenio CoronadoJosé Ramón Galán-mascarósAntonio RiberaCarlos Marti-gastaldoEfrén Navarro-moratalla

subject

Materials scienceIntercalation (chemistry)Inorganic chemistryGeneral ChemistryOxalateMetalCrystallographychemistry.chemical_compoundchemistryFerrimagnetismvisual_artMaterials Chemistryvisual_art.visual_art_mediumAntiferromagnetismHydroxideMoleculeMolecule-based magnets

description

Here we report the intercalation of a MnII–CrIII oxalate-bridged extended network into the interlamellar space offered by a ZnII–AlIII LDH host. This material exhibits ferrimagnetic ordering below 3 K from dominant antiferromagnetic interactions between metallic centres through the oxalate linker. Our result opens the door for the design of a completely new sort of hybrid magnetic multilayers from molecule-based magnets and layered inorganic flexible hosts, where the intrinsic properties of both sub-layers can be combined.

yearjournalcountryeditionlanguage
2010-01-01Journal of Materials Chemistry
https://doi.org/10.1039/c0jm01722a