Phosphororganische Verbindungen, XVI. Wege zur Darstellung primärer, sekundärer und tertiärer Phosphine

6533b862fe1ef96bd12c75c8

RESEARCH PRODUCT

Phosphororganische Verbindungen, XVI. Wege zur Darstellung primärer, sekundärer und tertiärer Phosphine

Leopold Horner Hellmut Hoffmann Peter Beck

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Fur die Darstellung von Phosphinen auf reduktivem Wege ergeben sich die folgenden Moglichkeiten: Tertiare phosphine: aus phosphinoxyden und Phosphinchloriden (R3PCI2) mit LiAIH4 bzw. Na, aus phosphinsulfiden mit Na, NaH, LiAlH4 und Raney-Nickel. — Sekundare phosphine:aus sek. Chlorphosphinen (R2PCI), Trichlorphosphoranen (R2PCI3), phosphinsaurechloriden (R2POCI) Phosphinsauren bzw. deren Estern (R2PO.OR), Phosphinigsauren (R2POH) mit LiAIH4 (evtl. Na). — Primare Phosphine:aus primaren Chlorphosphinen (RPCI2), Phosphonsaurechloriden (RPOCI2), Phosphonsaureestern (RPO(OR)2) und Phosphonigsauren (RP(OH)2) mit LiAIH4, LiH und Natrium.

year	journal	country	edition	language
1958-08-01	Chemische Berichte

https://doi.org/10.1002/cber.19580910803

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