6533b86cfe1ef96bd12c7ffa

RESEARCH PRODUCT

Theoretical modeling of Langmuir monolayers

Harald LangeFriederike SchmidC. Stadler

subject

Condensed Matter::Soft Condensed MatterAmphiphilic moleculechemistry.chemical_compoundLangmuirColloid and Surface ChemistryMonomerPlanarchemistryChemical physicsMonolayerMonte Carlo methodPhysical chemistry

description

Abstract We study coarse-grained continuum models for Langmuir monolayers by self-consistent field theory and by Monte Carlo simulations. Amphiphilic molecules are represented by stiff chains of monomers with one end grafted to a planar surface. In particular, we discuss the origin of successive fluid–fluid transitions, the possible origin of tilt order and the factors which determine the direction of tilt.

https://doi.org/10.1016/s0927-7757(98)00315-x