Search results for " Coating."
showing 10 items of 2558 documents
Asymmetric [N–I–N]+halonium complexes in solution?
2020
Assessment of the solution equilibria of [bis(pyridine)iodine(I)]+ complexes by ESI-MS and NMR reveals the preference of iodine(I) to form complexes with a more basic pyridine. Mixtures of symmetric [bis(pyridine)iodine(I)]+ complexes undergo statistical ligand exchange, with a predominant entropic driving force favoring asymmetric systems. The influence of ligand basicity, concentration, temperature, and ligand composition is evaluated. Our findings are expected to facilitate the investigations, and the supramolecular and synthetic applications of halonium ions’ halogen bonds. peerReviewed
Potent affinity material for tracing acetone and related analytes based on molecular recognition by halogen bonds.
2014
Affinity materials based on halogen bonds turned out to be a powerful tool for the molecular recognition of acetone or related carbonyl compounds in the presence of ubiquitous protic molecules. The superior selectivity and sensitivity were found by the gravimetric detection of volatile organic compounds by quartz crystal microbalances.
Atomic Layer Deposition of Aluminum Oxide on TiO2 and Its Impact on N3 Dye Adsorption from First Principles
2011
The atomic layer deposition of aluminum oxide on an OH-terminated TiO2(101) anatase surface was studied employing density functional theory calculations. The formation of the Al2O3−TiO2 interface during the first atomic layer deposition cycle was modeled by studying the dissociative adsorption of an Al(CH3)3 precursor, followed with a H2O-pulse reaction step that changes the surface termination. Calculations provide evidence for the formation of a discontinuous, atomically rough aluminum oxide layer after the first cycle. To explore the role of the aluminum oxide layer on adsorption of a ruthenium-based N3 dye molecule, various adsorption geometries were investigated. Calculations show that…
Inhibitoren der Korrosion 25(1) - Über die Rolle der Kationen in Neutralsalzen bei der Korrosion von Eisenwerkstoffen in Gegenwart von Sauerstoff
1979
Die Geschwindigkeit des Sauerstoffverbrauchs bei der Korrosion von jeweils 500 mg DAB6-Eisenpulver wird in Abhangigkeit von der Art des Kations in Neutralsalzen (Chloriden) unter Standardbedingungen bestimmt. In Gegenwart von Alkali-, Quartaren Ammonium, Quartaren Phosphonium-und Erdalkalichloriden ist die Geschwindigkeit des Sauerstoffverbrauches vergleichbar gros. Mit Zink-, Cadmium-, Nickel-und Kobaltchloriden wird aber im Bereich von pH5 bis pH7 eine uberraschend grose Verzogerung der Sauerstoffaufnahme beobachtet. Es handelt sich mit hoher Wahrscheinlichkeit um eine Blockade der kathodischen Bezirke in der Eisengrenzflache durch Abscheidung der schwerloslichen basischen Hydroxyde von Z…
Iron(iii) oxamato-catalyzed epoxidation of alkenes by dioxygen and pivalaldehyde
1997
A new iron(III)–carbonato monomeric complex of orthophenylenebis( oxamato) (opba) 1 is synthesized, and spectroscopically and structurally characterized; it is a moderately efficient non-heme catalyst for the aerobic epoxidation of alkenes with co-oxidation of pivalaldehyde. Ruiz Garcia, Rafael, Rafael.Ruiz@uv.es ; Fernandez Picot, Isabel, Isabel.Fernandez@uv.es ; Pedro Llinares, Jose Ramon, Jose.R.Pedro@uv.es
Tetraiodoethynyl resorcinarene cavitands as multivalent halogen bond donors
2014
The first examples of iodoethynyl resorcinarene cavitands as rigid 3D halogen bond (XB) donor molecules are presented. These concave macrocycles form strong, RXB = 0.78–0.83, halogen bonds with dioxane oxygen, pyridine nitrogen and a bromide anion in tetraproropyl ammonium bromide resulting in deep cavity cavitand structures.
Graphitically encapsulated cobalt nanocrystal assemblies
2010
Graphitically encapsulated cobalt nanocrystal assemblies are chemically prepared by one-pot reaction at380 degrees C followed by a reversed etching process to produce porous graphitic structure for revealing their self-assembling nature.
Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons.
2019
True trimorphic cocrystals, i.e. multi-component molecular crystals of identical composition that exhibit three polymorphic structures, are exceedingly rare and so far no halogen-bonded cocrystal system has been reported to exhibit trimorphism. Here we describe a unique example of a trimorphic cocrystal exhibiting both hydrogen and halogen bonds in which the differences between polymorphs reveal their orthogonality, evident by the apparently independent variation of well-defined hydrogen- and halogen-bonded motifs. peerReviewed
Effect of air on oxygen p-doped graphene on SiO2
2016
Stability in ambient air or in vacuum-controlled atmosphere of molecular oxygen-induced p-type doping of graphene monolayer on SiO2 substrate on Si is investigated by micro-Raman spectroscopy and atomic force microscopy (AFM). The Raman 2D and G bands spectral positions and amplitude ratio are affected by the permanence in air atmosphere in a time scale of months whereas the vacuum safely maintains the doping effects determined through Raman bands. No morphological effects are induced by the doping and post-doping treatments. A reactivity of ambient molecular gas with stably trapped oxygen is suggested to induce the doping modification. (C) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Production of Phosphorescent Coatings on 6082 Aluminum Using Sr0.95Eu0.02Dy0.03Al2O4-δ Powder and Plasma Electrolytic Oxidation
2019
In this study, a new approach for producing phosphorescent aluminum coatings was studied. Using the plasma electrolytic oxidation (PEO) process, a porous oxide coating was produced on the Al6082 aluminum alloy substrate. Afterwards, activated strontium aluminate (SrAl2O4: Eu2+, Dy3+) powder was filled into the cavities and pores of the PEO coating, which resulted in a surface that exhibits long-lasting luminescence. The structural and optical properties were studied using XRD, SEM, and photoluminescence measurements. It was found that the treatment time affects the morphology of the coating, which influences the amount of strontium aluminate powder that can be incorporated into the coating …