Search results for " atom"

showing 10 items of 1526 documents

Svina noteikšanas iespējas asinīs ar instrumentālajām analīzes metodēm, izmantojot dažādus paraugu sagatavošanas veidus

2017

Svina noteikšanas iespējas asinīs ar instrumentālajām analīzes metodēm, izmantojot dažādus paraugu sagatavošanas veidus. Ribkinska L., darba vadītājas Dr. med. Inese Mārtiņsone un Dr. Chem. Agnese Osīte. Maģistra darbs, 45 lappuses, 18 attēli, 12 tabulas, 45 literatūras avoti, 18 pielikumi. Latviešu valodā. Maģistra darbā ir apkopota literatūra par instrumentālajām analīzes metodēm (ETAAS un ICP-MS), paraugu sagatavošanas metodēm un svina toksisko iedarbību uz cilvēka veselību. Eksperimentālajā daļā veikta svina masas koncentrācijas noteikšana asinīs, izmantojot dažādus paraugu sagatavošanas veidus. Paraugu sagatavošanas metodēm veikta to salīdzināšana, kā arī rezultātu pareizības kontrolei…

SVINSELEKTROTERMĀLĀ ATOMABSORBCIOMETRIJA (ETAAS)ASINISINDUKTĪVI SAISTĪTĀS PLAZMAS MASSPEKTROMETRIJA (ICP-MS)PARAUGU SAGATAVOŠANAĶīmija
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The gas-phase chemiionization reaction between samarium and oxygen atoms: A theoretical study

2004

The Sm + O chemiionization reaction has been investigated theoretically using a method that allows for correlation and relativistic effects. Potential energy curves have been calculated for several electronic states of SmO and SmO+. Comparison with available spectroscopic and thermodynamic values for these species is reported and a mechanism for the chemiionization reaction Sm + O is proposed. The importance of spin–orbit coupling in the excited states of SmO, in allowing this chemiionization reaction to take place, has been revealed by these calculations. This paper shows the metal-plus-oxidant chemiionization reaction.

SamariumExcited statesGeneral Physics and Astronomychemistry.chemical_elementRelativistic correctionsPotential energyOxygenOxygenSamariumAtom-atom reactionsOxygen atomchemistryPotential energy surfacesExcited stateIonizationddc:540OxidationSpin-orbit interactionsPhysical and Theoretical ChemistryAtomic physicsRelativistic quantum chemistryChain reactionIonisationThe Journal of Chemical Physics
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From single fiber to macro-level mechanics: A structural finite-element model for elastomeric fibrous biomaterials

2014

In the present work, we demonstrate that the mesoscopic in-plane mechanical behavior of membrane elastomeric scaffolds can be simulated by replication of actual quantified fibrous geometries. Elastomeric electrospun polyurethane (ES-PEUU) scaffolds, with and without particulate inclusions, were utilized. Simulations were developed from experimentally-derived fiber network geometries, based on a range of scaffold isotropic and anisotropic behaviors. These were chosen to evaluate the effects on macro-mechanics based on measurable geometric parameters such as fiber intersections, connectivity, orientation, and diameter. Simulations were conducted with only the fiber material model parameters a…

ScaffoldFabricationMaterials scienceFinite elements methodPolymersPolyestersmicrostructureFinite Element AnalysisPolyurethanesBiomedical EngineeringBiocompatible MaterialsMicroscopy Atomic ForceElastomercaffoldArticleBiomaterialsMaterials TestingElasticity (economics)Composite materialAnisotropyMesoscopic physicsTissue EngineeringTissue Scaffoldstissue engineering.Polyethylene TerephthalatesIsotropyMechanicsElasticityFinite element methodMechanics of MaterialselectrospunAnisotropyStress MechanicalJournal of the Mechanical Behavior of Biomedical Materials
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4-(3H)-quinazolinones N-3 substituted with a five membered heterocycle: A promising scaffold towards bioactive molecules

2020

Abstract The quinazolinone nucleus represents, among the class of fused heterocycles, a very important scaffold to obtain molecules with biological activities. A review of literature revealed how such kind of fused heterocycles, coming from natural or synthetic source, are associated with a wide range of biological activities. This review is mainly directed towards the 4-(3H)-quinazolinones N-3 substituted with a five membered heterocycle in which all the possible combinations of nitrogen, sulfur and oxygen atoms are present.

ScaffoldNitrogenBioactive moleculesAnti-Inflammatory AgentsAntitubercular Agentschemistry.chemical_elementAntineoplastic Agents01 natural sciencesAntioxidants03 medical and health scienceschemistry.chemical_compoundAnti-Infective AgentsDrug DiscoveryAnimalsHumansMoleculeBenzothiazolesQuinazolinoneQuinazolinones030304 developmental biologyPharmacology0303 health sciencesMolecular Structure010405 organic chemistryOrganic ChemistryN-3 substituted-4-(3H)-quinazolinones five membered heterocycle bioactive systemGeneral MedicineSettore CHIM/08 - Chimica FarmaceuticaSulfurCombinatorial chemistryBronchodilator Agents0104 chemical sciencesOxygenThiazolesOxygen atomchemistryAnticonvulsantsSulfurEuropean Journal of Medicinal Chemistry
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Fast apparent oscillations of fundamental constants

2019

Precision spectroscopy of atoms and molecules allows one to search for and to put stringent limits on the variation of fundamental constants. These experiments are typically interpreted in terms of variations of the fine structure constant $\alpha$ and the electron to proton mass ratio $\mu=m_e/m_p$. Atomic spectroscopy is usually less sensitive to other fundamental constants, unless the hyperfine structure of atomic levels is studied. However, the number of possible dimensionless constants increases when we allow for fast variations of the constants, where "fast" is determined by the time scale of the response of the studied species or experimental apparatus used. In this case, the relevan…

Scale (ratio)Atomic Physics (physics.atom-ph)530 PhysicsFOS: Physical sciencesGeneral Physics and Astronomy02 engineering and technologyAtomic spectroscopyElectron53001 natural sciencesPhysics - Atomic PhysicsHigh Energy Physics - Phenomenology (hep-ph)0103 physical sciencesddc:530Physics::Atomic Physics010306 general physicsHyperfine structurePhysicsHigh Energy Physics::PhenomenologyAtoms in moleculesFine-structure constantSense (electronics)021001 nanoscience & nanotechnology530 PhysikHigh Energy Physics - PhenomenologyAtomic physics0210 nano-technologyDimensionless quantity
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<title>Scanning probe microscopy of nanocrystalline iridium oxide thin films</title>

2003

Structural investigations of nanocrystalline iridium oxide thin films, prepared by dc magnetron sputtering technique were performed by scanning probe microscopy (SPM). SPM studies, using both atomic force microscopy (AFM) and scanning tunnelling microscopy (STM), indicate that the thin films are composed of grains with a size of about 20-50 nm. Fine crystallinity and small RMS microroughness of the films, being well below 2 nm, make iridium oxide thin films promising candidates for nanolithographic applications. The possibility to perform nanolithograhpic processes at a scale of less than 150 nm was successfully examined in AFM and STM modes.© (2003) COPYRIGHT SPIE--The International Societ…

Scanning probe microscopyMaterials scienceScanning confocal electron microscopyScanning ion-conductance microscopyNanotechnologyConductive atomic force microscopyScanning capacitance microscopyPhotoconductive atomic force microscopyVibrational analysis with scanning probe microscopyNanocrystalline materialSPIE Proceedings
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Tunable Polarons in Bose-Einstein Condensates

2017

A toolbox for the quantum simulation of polarons in ultracold atoms is presented. Motivated by the impressive experimental advances in the area of ultracold atomic mixtures, we theoretically study the problem of ultracold atomic impurities immersed in a Bose-Einstein condensate mixture (BEC). The coupling between impurity and BEC gives rise to the formation of polarons whose mutual interaction can be effectively tuned using an external laser driving a quasi-resonant Raman transition between the BEC components. Our scheme allows one to change the effective interactions between polarons in different sites from attractive to zero. This is achieved by simply changing the intensity and the frequ…

ScienceFOS: Physical sciencesQuantum simulatorPolaron01 natural sciencesSettore FIS/03 - Fisica Della MateriaArticle010305 fluids & plasmaslaw.inventionsymbols.namesakeImpurityUltracold atomlaw/dk/atira/pure/subjectarea/asjc/10000103 physical sciencesPhysics::Atomic PhysicsGeneral010306 general physicsCondensed Matter::Quantum GasesPhysicsQuantum PhysicsMultidisciplinaryCondensed Matter::OtherPolaronsQRLaser3. Good healthCoupling (physics)Quantum Gases (cond-mat.quant-gas)symbolsMultidisciplinary ultracold atoms polaronsMedicine-----Atomic physicsCondensed Matter - Quantum GasesQuantum Physics (quant-ph)Raman spectroscopyBose–Einstein condensateScientific Reports
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Temperature and Isotopic Mass Dependence of the Direct Band Gap in Semiconductors: LCAO Calculations

2000

SemiconductorCondensed matter physicsbusiness.industryChemistryLinear combination of atomic orbitalsBand gapDirect and indirect band gapsAtomic physicsCondensed Matter PhysicsbusinessSemimetalElectronic Optical and Magnetic Materialsphysica status solidi (b)
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Novel bioactive bromopyrrole alkaloids from the Mediterranean sponge Axinella verrucosa

2005

The Mediterranean sponge Axinella verrucosa has been investigated for its alkaloid composition and has been found to produce a complex mixture of bromopyrrole alkaloids. Along with the previously isolated compounds 5-18, four novel alkaloids of this class, compounds 1-4, have been isolated, and their structures established through spectroscopic methods. Compounds 1-4 were found to display neuroprotective activity against the agonists serotonin and glutamate in vitro.

SerotoninSpectrometry Mass Electrospray Ionizationendocrine systemAxinella verrucosaMagnetic Resonance SpectroscopyStereochemistryClinical BiochemistryThin layerGlutamic AcidPharmaceutical ScienceSpectrometry Mass Fast Atom BombardmentPharmacognosycomplex mixturesBiochemistryAnimal originPyrrole derivativesNatural productCell LineAlkaloidsBromopyrrole alkaloidDrug DiscoveryAnimalsPyrrolesheterocyclic compoundsMolecular BiologyNeuronsMarine spongeMolecular StructurebiologyChemistryorganic chemicalsAlkaloidOrganic ChemistryQuisqualic AcidBiological activitybiology.organism_classificationPoriferaSpongeNeuroprotective activity.Axinella verrucosaMolecular MedicineCalciumChromatography Thin LayerSerotonin AntagonistsExcitatory Amino Acid Antagonists
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La ricerca dei componenti ultimi della materia:l'approccio filosofico, quello chimico e quello fisico

2010

Settore CHIM/01 - Chimica Analiticastruttura della materia particelle teoria atomico-molecolare storia della chimica
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