Search results for " liberation"

showing 10 items of 76 documents

Validation of Dissolution Testing with Biorelevant Media: An OrBiTo Study.

2017

Dissolution testing with biorelevant media has become widespread in the pharmaceutical industry as a means of better understanding how drugs and formulations behave in the gastrointestinal tract. Until now, however, there have been few attempts to gauge the reproducibility of results obtained with these methods. The aim of this study was to determine the interlaboratory reproducibility of biorelevant dissolution testing, using the paddle apparatus (USP 2). Thirteen industrial and three academic laboratories participated in this study. All laboratories were provided with standard protocols for running the tests: dissolution in FaSSGF to simulate release in the stomach, dissolution in a singl…

IndolesInterlaboratory reproducibilityChemistry PharmaceuticalPhenylcarbamatesPharmaceutical ScienceIbuprofen02 engineering and technologyPharmacology030226 pharmacology & pharmacyBiopharmaceuticsTosyl Compounds03 medical and health sciences0302 clinical medicineDrug DiscoveryIntestine SmallDissolution testingTransfer modelDissolutionSulfonamidesChromatographyChemistryReproducibility of ResultsHydrogen-Ion Concentration021001 nanoscience & nanotechnologyDrug LiberationSolubilityGastric MucosaMolecular Medicine0210 nano-technologyTabletsMolecular pharmaceutics
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Extended release and enhanced bioavailability of moxifloxacin conjugated with hydrophilic cellulose ethers.

2015

Macromolecular prodrugs (MPDs) of moxifloxacin were fabricated based on hydroxypropylcellulose (HPC) and hydroxyethylcellulose (HEC). UV/Vis spectrophotometry was employed to determine covalently loaded drug content (DC) of each conjugate. The degree of substitution (DS) of moxifloxacin attained ranged from 0.27 to 0.38 (HPC) and 0.19 to 0.26 (HEC) per anhydroglucose unit (AGU), respectively. Transmission electron microscopic analyses showed that HPC-moxifloxacin conjugates self-assembled into nanowires of ∼ 30 nm diameters while HEC-moxifloxacin conjugates self-assembled into nanoparticles of 150-350 nm. In vitro drug release studies revealed that 15 and 49% moxifloxacin release occurred f…

MalePolymers and PlasticsKineticsMoxifloxacinBiological Availability02 engineering and technology010402 general chemistry01 natural scienceschemistry.chemical_compoundPharmacokineticsMoxifloxacinSpectrophotometryMaterials ChemistrymedicineAnimalsheterocyclic compoundsProdrugsCelluloseCelluloseChromatographymedicine.diagnostic_testOrganic Chemistrybiochemical phenomena metabolism and nutritionProdrugbacterial infections and mycoses021001 nanoscience & nanotechnology0104 chemical sciencesBioavailabilityDrug LiberationKineticschemistryDelayed-Action PreparationsRabbits0210 nano-technologyHydrophobic and Hydrophilic Interactionsmedicine.drugConjugateFluoroquinolonesCarbohydrate polymers
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Hyaluronic acid and beta cyclodextrins films for the release of corneal epithelial cells and dexamethasone

2016

In this work we prepared hydrogels based on hyaluronic acid and β-cyclodextrins to sustain the release of both corneal epithelial cells and dexamethasone. This steroid is administered as eye drops several times per day to reduce the risk of rejection in the post operative period after the cornea transplantation and cell release techniques. Hydrogels were produced by crosslinking an amino derivative of hyaluronic acid, with the divinyl sulfone derivative of β-cyclodextrins, this last employed as a crosslinker and solubilizing agent. Drug release studies revealed that dexamethasone containing samples are able to extend the release of this drug for at least five days. Biological studies, condu…

Materials Chemistry2506 Metals and AlloysPolymers and Plasticsmedicine.medical_treatmentCellBeta-CyclodextrinsCell release systemmacromolecular substances02 engineering and technologyPharmacology010402 general chemistry01 natural sciencesDexamethasoneSteroidCorneachemistry.chemical_compoundCorneaHyaluronic acidMaterials ChemistrymedicineCorneal woundHumansHyaluronic acid hydrogelHyaluronic AcidDexamethasoneCells CulturedDrug CarriersPolymers and Plasticbeta-CyclodextrinsOrganic Chemistrytechnology industry and agricultureEpithelial CellsHydrogelsAnatomy021001 nanoscience & nanotechnologyeye diseases0104 chemical sciencesTransplantationDrug Liberationmedicine.anatomical_structurechemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoSelf-healing hydrogelssense organs0210 nano-technologymedicine.drug
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Hyaluronic Acid-Based Micelles as Ocular Platform to Modulate the Loading, Release, and Corneal Permeation of Corticosteroids

2017

The aim of this work is to prepare hyaluronic acid-based micelles as a platform to load corticosteroid drugs and to improve their corneal permeation after administration on the ocular surface. Three amphiphilic derivatives of hyaluronic acid (HA) are synthesized using different amounts of hexadecylamine (C16 -NH2 ). HAC16 a, HAC16 b, and HAC16 c derivatives are able to form micelles by the cosolvent evaporation method and to entrap corticosteroids (dexamethasone, triamcinolone, triamcinolone acetonide). HAC16 a and HAC16 b micelles show the best results in terms of drug loading and particle size. They are also able to improve drug release compared to free drug solution or suspension. In add…

Materials Chemistry2506 Metals and AlloysTriamcinolone acetonidePolymers and PlasticsAdministration Ophthalmic02 engineering and technologyTriamcinolone01 natural sciencesMicelleDexamethasoneCorneachemistry.chemical_compoundDrug Delivery SystemsAdrenal Cortex HormonesHyaluronic acidMaterials ChemistryCorticosteroidAminesCells CulturedMicellesDrug CarriersChemistryPermeation021001 nanoscience & nanotechnology0210 nano-technologyDrug carriermedicine.drugBiotechnologyTranscorneal enhancerHyaluronic acidBioengineering010402 general chemistryPermeabilityBiomaterialsPolymeric micelleAmphiphilemedicineMucoadhesionAnimalsHumansGlucocorticoidsPolymers and PlasticOcular administrationBiomaterialHydrocarbons0104 chemical sciencesDrug LiberationSettore CHIM/09 - Farmaceutico Tecnologico ApplicativoBiophysicsCattleEx vivo
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Chitosan-coated mesoporous MIL-100(Fe) nanoparticles as improved bio-compatible oral nanocarriers

2017

Nanometric biocompatible Metal-Organic Frameworks (nanoMOFs) are promising candidates for drug delivery. Up to now, most studies have targeted the intravenous route, related to pain and severe complications; whereas nanoMOFs for oral administration, a commonly used non-invasive and simpler route, remains however unexplored. We propose here the biofriendly preparation of a suitable oral nanocarrier based on the benchmarked biocompatible mesoporous iron(III) trimesate nanoparticles coated with the bioadhesive polysaccharide chitosan (CS). This method does not hamper the textural/structural properties and the sorption/release abilities of the nanoMOFs upon surface engineering. The interaction …

Materials scienceBiocompatibilityBioadhesiveQuímica organometàl·licaNanoparticleAdministration OralNanotechnology02 engineering and technologySurface engineering010402 general chemistry01 natural sciencesFerric CompoundsArticleChitosanchemistry.chemical_compoundHumansChitosanMultidisciplinaryNanotecnologia021001 nanoscience & nanotechnology3. Good health0104 chemical sciencesDrug LiberationKineticsLysergic Acid DiethylamideEnterocyteschemistryDrug deliveryNanoparticlesNanocarriersCaco-2 Cells0210 nano-technologyMesoporous material
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Folic acid-functionalized graphene oxide nanosheets via plasma etching as a platform to combine NIR anticancer phototherapy and targeted drug deliver…

2020

PEGylated graphene oxide (GO) has shown potential as NIR converting agent to produce local heat useful in breast cancer therapy, since its suitable photothermal conversion, high stability in physiological fluids, biocompatibility and huge specific surface. GO is an appealing nanomaterial for potential clinical applications combining drug delivery and photothermal therapy in a single nano-device capable of specifically targeting breast cancer cells. However, native GO sheets have large dimensions (0.5-5 mu m) such that tumor accumulation after a systemic administration is usually precluded. Herein, we report a step-by-step synthesis of folic acid-functionalized PEGylated GO, henceforth named…

Materials scienceBiocompatibilityPlasma GasesCell SurvivalInfrared RaysBioengineeringNanotechnologyAntineoplastic Agents02 engineering and technology010402 general chemistrySettore CHIM/04 - Chimica Industriale01 natural sciencesNANOMEDICINECell LinePolyethylene GlycolsBiomaterialsBreast cancerBreast cancerFolic AcidCell MovementmedicineNANOPARTICLESABLATIONHumansDoxorubicinCANCER-CELLSAGENTSGraphene oxideDrug Carrierstechnology industry and agriculturePhotothermal therapyPhototherapy021001 nanoscience & nanotechnologymedicine.disease0104 chemical sciencesNanostructuresDrug LiberationTargeted drug deliverySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoMechanics of MaterialsDoxorubicinCancer cellDrug deliveryDoxorubicin HydrochlorideGraphiteSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologySYSTEMmedicine.drugMaterials scienceengineering. C, Materials for biological applications
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Spray-Drying, Solvent-Casting and Freeze-Drying Techniques: a Comparative Study on their Suitability for the Enhancement of Drug Dissolution Rates.

2019

Purpose Solid dispersions (SDs) represent the most common formulation technique used to increase the dissolution rate of a drug. In this work, the three most common methods used to prepare SDs, namely spray-drying, solvent-casting and freezedrying, have been compared in order to investigate their effect on increasing drug dissolution rate. Methods Three formulation strategies were used to prepare a polymer mixture of polyvinyl-alcohol (PVA) and maltodextrin (MDX) as SDs loaded with the following three model drugs, all of which possess a poor solubility: Olanzapine, Dexamethasone, and Triamcinolone acetonide. The SDs obtained were analysed and compared in terms of drug particle size, drug-lo…

Materials scienceDrug Compoundingdissolution rate . freeze-drying . solid dispersion . solvent-casting method . spray-dryingPharmaceutical Science02 engineering and technology030226 pharmacology & pharmacyTriamcinolone AcetonideDexamethasoneExcipients03 medical and health sciencesFreeze-dryingchemistry.chemical_compound0302 clinical medicinePolysaccharidesPharmacology (medical)Dissolution testingSolubilityDesiccationDissolutionPharmacologyOrganic Chemistry021001 nanoscience & nanotechnologyMaltodextrinSolventDrug LiberationFreeze DryingChemical engineeringchemistryPharmaceutical PreparationsSolubilityOlanzapineSpray dryingPolyvinyl AlcoholSolventsMolecular MedicineParticle size0210 nano-technologyBiotechnologyPharmaceutical research
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Mechanical, degradation and drug-release behavior of nano-grained Fe-Ag composites for biomedical applications.

2018

Abstract An original fabrication route of high-strength bulk Fe-5Ag and Fe-10Ag nanocomposites with enhanced degradation rate is reported. Near fully dense materials with fine nanostructures and uniform distribution of Ag nanoparticles were obtained employing high energy attrition milling of Fe-Ag2O powder blends followed by cold sintering – high pressure consolidation at ambient temperature that allowed the retention of the nanoscale structure. Annealing in hydrogen flow at 550 °C resulted in enhanced ductility without coarsening the nanostructure. The strength in compression of Fe5Ag and Fe10Ag nanocomposites was several-fold higher than the values reported for similar composites with mic…

Materials scienceNanostructureHot TemperatureSilverAnnealing (metallurgy)Cell SurvivalIronBiomedical EngineeringSinteringMetal Nanoparticles02 engineering and technology010402 general chemistry01 natural sciencesCorrosionBiomaterialsFlexural strengthVancomycinNano-ElectrochemistryHumansComposite materialMechanical PhenomenaDrug CarriersNanocompositeOsteoblasts021001 nanoscience & nanotechnologyGrain size0104 chemical sciencesCorrosionDrug LiberationMechanics of Materials0210 nano-technologyJournal of the mechanical behavior of biomedical materials
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HPMA-based block copolymers promote differential drug delivery kinetics for hydrophobic and amphiphilic molecules.

2015

Abstract We describe a method how polymeric nanoparticles stabilized with (2-hydroxypropyl)methacrylamide (HPMA)-based block copolymers are used as drug delivery systems for a fast release of hydrophobic and a controlled release of an amphiphilic molecule. The versatile method of the miniemulsion solvent-evaporation technique was used to prepare polystyrene (PS) as well as poly-d/l-lactide (PDLLA) nanoparticles. Covalently bound or physically adsorbed fluorescent dyes labeled the particles’ core and their block copolymer corona. Confocal laser scanning microscopy (CLSM) in combination with flow cytometry measurements were applied to demonstrate the burst release of a fluorescent hydrophobic…

Materials sciencePolymersPolyestersBiomedical EngineeringNanoparticleFluorescent Antibody TechniqueNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesBiochemistryBiomaterialschemistry.chemical_compoundSurface-Active AgentsDrug Delivery SystemsAmphiphileCopolymerMethacrylamideHumansMolecular BiologyDrug CarriersGeneral MedicineLipid Droplets021001 nanoscience & nanotechnologyControlled release0104 chemical sciencesMiniemulsionDrug LiberationKineticschemistryDrug deliveryBiophysicsMethacrylatesNanoparticlesPolystyrenesNanocarriers0210 nano-technologyHydrophobic and Hydrophilic InteractionsBiotechnologyHeLa CellsActa biomaterialia
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Process parameters of microsphere preparation based on propylene carbonate emulsion-precursors.

2020

This study aimed for a detailed understanding of the impact of different process parameters involved during celecoxib-loaded microsphere preparation based on propylene carbonate emulsion-precursors.Microspheres were prepared by a modified emulsification-solvent extraction method. Performed investigations included polymer solubility and viscosity, microsphere size, morphology and stability, propylene carbonate content as well as celecoxib solid state, content and release.Rough-walled round microspheres with sizes between 21 µm and 122 µm and an internal sponge-like structure filled with residual propylene carbonate (content between 1.9 ± 0.1% and 6.7 ± 0.5% w/w) were obtained. Encapsulation …

Materials sciencePolymersSurface PropertiesChemistry PharmaceuticalDrug CompoundingPharmaceutical ScienceBioengineering02 engineering and technologyPolypropylenes030226 pharmacology & pharmacyMicrosphere03 medical and health scienceschemistry.chemical_compound0302 clinical medicineColloid and Surface ChemistryLactic AcidPhysical and Theoretical ChemistryParticle SizeDrug CarriersCalorimetry Differential ScanningViscosityOrganic Chemistry021001 nanoscience & nanotechnologyMicrospheresPLGADrug LiberationchemistryChemical engineeringSolubilityCelecoxibScientific methodPropylene carbonateEmulsionMicroscopy Electron ScanningSolventsEmulsions0210 nano-technologyPolyglycolic AcidJournal of microencapsulation
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