Search results for "41"

A conformationally adaptive macrocycle : conformational complexity and host–guest chemistry of zorb[4]arene

2018

Large amplitude conformational change is one of the features of biomolecular recognition and is also the basis for allosteric effects and signal transduction in functional biological systems. However, synthetic receptors with controllable conformational changes are rare. In this article, we present a thorough study on the host–guest chemistry of a conformationally adaptive macrocycle, namely per-O-ethoxyzorb[4]arene (ZB4). Similar to per-O-ethoxyoxatub[4]arene, ZB4 is capable of accommodating a wide range of organic cations. However, ZB4 does not show large amplitude conformational responses to the electronic substituents on the guests. Instead of a linear free-energy relationship, ZB4 foll…

Applying a framework for landscape planning under climate change for the conservation of biodiversity in the Finnish boreal forest

2015

Conservation strategies are often established without consideration of the impact of climate change. However, this impact is expected to threaten species and ecosystem persistence and to have dramatic effects towards the end of the 21st century. Landscape suitability for species under climate change is determined by several interacting factors including dispersal and human land use. Designing effective conservation strategies at regional scales to improve landscape suitability requires measuring the vulnerabilities of specific regions to climate change and determining their conservation capacities. Although methods for defining vulnerability categories are available, methods for doing this …

Characterization of the LGBTI-speaking community discourse. An approach to Hispanic queer linguistics.

2020

Toda subcultura forma una comunidad lingüística particular en la que, aunque se comparta la lengua con el resto de la sociedad, varía el habla en ciertos aspectos. Es el caso de la comunidad de habla LGTBI, que se hace servir de un léxico peculiar, así como una fraseología característica, unas estructuras gramaticales especiales y, en definitiva, unos recursos pragmáticos muy llamativos que tienen como objetivo mitigar ciertos enunciados, intensificar otros en determinados contextos y construir actos de habla afiliativos que expresen solidaridad social. Por otro lado, cumple una función muy importante en la construcción identitaria de sus usuarios. En este trabajo se propone un análisis pra…

ICT mobility research in Finland: From immaterial consumption to material sustainability?

2015

Task Contexts in Dutch Mathematics Education

2020

This chapter offers a description of task contexts in mathematics education in the Netherlands. International comparative studies show that the Dutch average percentage of mathematics tasks with real-life connections per lesson exceeds any other country by far. This tradition goes back more than 500 years, when the earliest mathematics textbooks in the Dutch language consisted entirely of tasks, in which mathematics was put to use in commercial contexts. In this chapter characteristics of contexts in mathematics tasks in the Netherlands are studied. Underlying frame is the notion of usefulness, which is a perception by students on future practices outside school. A distinction is made betwe…

Efficacy and Efficiency of Italian Energy Policy: The Case of PV Systems in Greenhouse Farms

2014

The production of energy from renewable sources is a form of energy production that has less impact on the environment than the traditional one. For the farmer this new form of production represents an opportunity, especially for the economic benefits that can produce, both in terms of the incentives provided by the public operator and for higher revenues, deriving from the sale of energy back to the grid and/or the savings generated by self-consumed energy, that help to increase the farmer’s income. In this paper, we analyzed a case study of a farm that has realized a grid-connected photovoltaic (PV) system on a greenhouse. In particular, firstly the farm profitability has been estimated a…

Comparison of Hybrid Blends for Solar Cell Application

2010

In blended hybrid systems distinct micro- or nanostructured materials can be formed by phase separation. Network structures of particles or rods in a polymer matrix can be developed via self-assembly. We use this blending approach to compare active materials for application in solar cell devices. Blends were fabricated from either poly(hexylthiophene) P3HT or poly(triphenylamine) PTPA mixed with nanocrystalline TiO 2 rods. In this manner, we compare two different hole conducting polymers in their performance in photovoltaic devices, while experimental conditions are kept identical. We find that the choice of solvent and photovoltaic characterization conducted in inert atmosphere is of impor…

An Environmental Analysis of the Effect of Energy Saving, Production and Recovery Measures on Water Supply Systems under Scarcity Conditions

2015

Water is one of the primary resources provided for maintaining quality of life and social status in urban areas. As potable water is considered to be a primary need, water service has usually been managed without examining the economic and environmental sustainability of supply processes. Currently, due to increases in energy costs and the growth of environment preservation policies, reducing water leakage, energy consumption and greenhouse gas (GHG) production have become primary objectives in reducing the environmental footprint of water service. The present paper suggests the implementation of some performance indicators that show the interdependence of water loss, energy consumption and…

Sistema de monitorización en continuo a tiempo real de la concentración de oxígeno durante el batido para la producción de aceite de oliva virgen

2012

During the mechanical extraction process of Virgin Olive Oil (VOO) some important physical phenomena and enzymatic transformations occur which influence the quality of the final product. The control of process parameters is crucial to ensure the quality of VOO, therefore process monitoring and control is a fundamental requirement in the modern VOO processing industry. The present work proposes an innovative Real-Time Monitoring System (RTMS) aimed at continuously measuring the oxygen concentration during the malaxation process in order to establish a correlation with the quality of the final product obtained. This monitoring system is based on an oxygen concentration sensor directly connect…

Development of Point-to-Point Path Control in Actuator Space for Hydraulic Knuckle Boom Crane

2020

This paper presents a novel method for point-to-point path control for a hydraulic knuckle boom crane. The developed path control algorithm differs from previous solutions by operating in the actuator space instead of the joint space or Cartesian space of the crane. By operating in actuator space, almost all the parameters and constraints of the system become either linear or constant, which greatly reduces the complexity of both the control algorithm and path generator. For a given starting point and endpoint, the motion for each actuator is minimized compared to other methods. This ensures that any change in direction of motion is avoided, thereby greatly minimizing fatigue, jerky motion,…