Search results for "CONST"
showing 10 items of 7706 documents
Analytical approach for the mix design optimisation of bituminous mixtures with crumb rubber
2018
The present paper provides a basis for defining a mix design method specifically tailored to rubberised asphalt that takes into account the behaviour of crumb rubber. An analytical approach to quantifying the recovered deformation of crumb rubber in the post-compaction phase has been developed in order to adjust the number of gyrations proposed by the Superpave method for compacting specimens of hot mix asphalt using a Superpave gyratory compactor. The maximum allowable amount of rubber has been calculated. Finally, a step-by-step protocol has been proposed in order to fabricate and compact crumb rubber modified mixtures with the gyratory compactor.
First-principles calculations of the atomic and electronic structure of SrZrO3 and PbZrO3 (001) and (011) surfaces.
2010
We present the results of calculations of surface relaxations, rumplings, energetics, optical band gaps, and charge distribution for the SrZrO(3) and PbZrO(3) (001) and (011) surfaces using the ab initio code CRYSTAL and a hybrid description of exchange and correlation. We consider both SrO(PbO) and ZrO(2) terminations of the (001) surface and Sr(Pb), ZrO, and O terminations of the polar SrZrO(3) and PbZrO(3) (011) surfaces. On the (001) surfaces, we find that all upper and third layer atoms relax inward, while outward relaxations of all atoms in the second layer are found with the sole exception of the SrO-terminated SrZrO(3) (001) surface second layer O atom. Between all (001) and (011) s…
Detailed study of defects in thin fullerite films
2012
The structural investigations of fullerite films were performed using high-resolution electron microscopy, electron diffraction and electron energy loss spectroscopy and X-ray photoelectron spectroscopy. In particular defects such as dislocations, stacking faults and twins were studied in details. It was shown that fullerite films could be characterized by a face-centered cubic (f.c.c.) structure with lattice parameter a = 1.416 nm. They are distinguished for their rich polytypic structure that is caused by breaking of alteration of closely packed planes of (111) type. The quantitative method based on information theory using the “run-length encoding” algorithm was suggested to evaluate the…
Preparation and Investigation of BaSO4KMnO4 Crystals
1969
BaSO4 crystals containing KMnO4 prepared by precipitation were investigated morphologically, chemically and by X-ray diffraction. The colour of the preparations is homogeneous and stable. The colour intensity and also the amount of dissolved KMnO4 (maximum approx. 30 Mol%) increases with concentration of KMnO4 in the reaction solution to a limiting value dependent on the temperature. The lattice constants or the unit cell volume of the BaSO4–KMnO4 crystals increase with the proportion of KMnO4. The experimental values agree well with the Vegard rule for preparations up to 18 Mol% KMnO4, but with higher proportions significant departures were observed. They may easily be explained by adsorpt…
Kinetic study of the oxidation of [Fe(CN)6]4− by [Co(NH3)4pzCO2]2+ and S2O82- in the presence of the tripodal ligand Tren Aminopropil
2011
Abstract Oxidations (electron transfers) of [Fe(CN)6]4− by [Co(NH3)4pzCO2]2+ and S 2 O 8 2 - have been studied in solutions containing the receptor N,N′,N″-(aminopropil)-tris (2-aminoetil) amina [Tren Aminopropil, TAL], which can incorporate [Fe(CN)6]4− and S 2 O 8 2 - but not the cobalt complex. The results can be explained using the Bronsted equation that allows to obtain the binding constant of the transition state, a parameter that the Pseudophase Model cannot provide.
The essential identity of the framework structures of ZSM-8 and ZSM-5
1994
The crystal structures of TEA-ZSM-8 and its calcined template-free form have been studied by Rietveld analyses based on X-ray powder diffraction data. The results show that the aluminosilicate framework structure of ZSM-8 is essentially identical to that of ZSM-5. The tetraethylammonium molecule could be located in the difference Fourier analysis yielding positions similar to its TPA counterpart in ZSM-5. Lattice constants of ZSM-8 are in the same range as for ZSM-5. Contrary results are related to incorrectly indexed powder patterns. Optical investigations of ZSM-5 and ZSM-8 crystals showed that the zeolites studied here are both twinned exhibiting differently shaped twin individuals.
Model of the catalyticA+B→0reaction with surface reconstruction
2002
The $A+\stackrel{\ensuremath{\rightarrow}}{B}0$ reaction model with a surface reconstruction is analyzed. It is compared with another similar model for the ${A+1/2B}_{2}\ensuremath{\rightarrow}0$ reaction [V. N. Kuzovkov et al., J. Chem. Phys. 108, 5571 (1998)], which mimics the CO oxidation reaction on the Pt surfaces. The effect of monomer B adsorption instead of dimer ${B}_{2}$ is examined. It is shown that qualitative system features such as reactant concentration oscillations are independent of this substitution.
Principe d'égalité des créanciers. Question prioritaire de constitutionnalité sur l'arrêt du cours des intérêts par rapport au principe d'égalité des…
2013
International audience; (Com., QPC, 20 mars 2012, n° 11-23.822, F-D, LPA 15 juin 2012, p. 10, note Ph. Roussel Galle)
Compensation des créances connexes. Question prioritaire de constitutionnalité
2012
International audience; (Com., 14 septembre 2010, n° 10-40.022, arrêt F-D, JCP 2011, 360, n° 3, obs. P. Pétel ; LPA 20 déc. 2010, p. 17, obs. L.-C. Henry)
Déclaration et vérification des créances. Non-lieu à renvoi d'une question prioritaire de constitutionnalité
2019
International audience; (Com. 4 sept. 2018, n° 17-28.749, arrêt n° 820 F-D, M. Manuel Oliver P. c/ Sté Easy connect et a.)