Search results for "Ether"

showing 10 items of 986 documents

Phase Equilibria in the Systems 2-Methyl-2-propanol + Methyl 1,1-Dimethylpropyl Ether and 2-Methylpentane + 2-Methyl-2-propanol + Methyl 1,1-Dimethyl…

1999

Consistent vapor−liquid equilibrium data for the binary and ternary systems 2-methyl-2-propanol (TBA) + methyl 1,1-dimethylpropyl ether (TAME) at temperatures from 353 to 359 K and 2-methylpentane + 2-methyl-2-propanol (TBA) + methyl 1,1-dimethylpropyl ether (TAME) from 332 to 353 K are reported at 101.3 kPa. The results indicate that the systems deviate positively from ideality and that only the binary system presents an azeotrope. The ternary system is well predicted from binary data. The activity coefficients and boiling points of the solutions were correlated with composition by Wilson, UNIQUAC, NRTL, and Wisniak−Tamir equations.

Ternary numeral systemUNIQUAC2-MethylpentaneGeneral Chemical EngineeringThermodynamicsEtherGeneral ChemistryMedicinal chemistryPropanolchemistry.chemical_compoundchemistryAzeotropeNon-random two-liquid modelBinary systemJournal of Chemical & Engineering Data
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Densities, refractive indices, and derived excess properties of tert-butyl alcohol, methyl tert-butyl ether and 2-methylpentane binary and ternary sy…

2000

Abstract This paper reports experimental densities and refractive indices of the binary systems tert-butyl alcohol (TBA)+methyl tert-butyl ether (MTBE), TBA+2-methylpentane, and MTBE+2-methylpentane, and the ternary system TBA+MTBE+2-methylpentane, over the entire range of composition at 303.15 K. Excess molar volumes and changes of refractive indices were evaluated from the experimental data obtained. These derived properties were fitted to variable-degree polynomials. The experimental values of physical properties were compared with the values estimated by different methods of prediction.

Ternary numeral systemtert-Butyl alcohol2-MethylpentaneGeneral Chemical EngineeringGeneral Physics and AstronomyEtherchemistry.chemical_compoundMolar volumechemistryOrganic chemistryPhysical chemistryBinary systemPhysical and Theoretical ChemistryTernary operationMethyl tert-butyl etherFluid Phase Equilibria
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CCDC 919043: Experimental Crystal Structure Determination

2013

Related Article: María Castellano, Wdeson P. Barros, Alvaro Acosta, Miguel Julve, Francesc Lloret, Yanling Li, Yves Journaux, Giovanni De Munno, Donatella Armentano, Rafael Ruiz-García, Joan Cano|2014|Chem.-Eur.J.|20|13965|doi:10.1002/chem.201403987

Tetra-n-butylammonium bis(mu~2~-22'-((910-dioxo-910-dihydroanthracene-14-diyl)diimino)bis(oxoacetato))-di-copper(ii) acetonitrile diethyl ether solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Preparation and characterization of new low melting ammonium-based ionic liquids with ether functionality

2009

Abstract Eighteen new and three previously known but insufficiently characterized RR´3N+A− and R2R´2N+A− type (R = 2-ethoxyethyl or 4-methoxybenzyl, R´ = methyl, ethyl, n-propyl, n-butyl, n-pentyl or n-hexyl, A = Br, BF4 or PF6) quaternary ammonium (QA) salts were synthesized and characterized by using 1H and 13C NMR techniques, mass spectroscopy and elemental analysis. The bromide salts were synthesized either by treating dimethyl formamide with an ether functionalized alkyl bromide in the presence of potassium carbonate or by treating a tertiary amine with an ether functionalized alkyl bromide. The QA tetrafluoroborates and hexafluorophosphates were synthesized by metathesis reaction betw…

TetrafluoroborateTertiary amineOrganic ChemistryInorganic chemistryEtherAnalytical ChemistryInorganic ChemistryPotassium carbonatechemistry.chemical_compoundCrystallinitychemistryBromideIonic liquidPolymer chemistryThermal stabilitySpectroscopyJournal of Molecular Structure
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La stereotomia nella cattedra di Architettura statica di Carlo Giachery

2014

La scuola di architettura di Palermo, sin dalla sua fondazione nel 1779, con la creazione della cattedra di Architettura civile affidata a Giuseppe Venanzio Marvuglia, era divenuta inevitabilmente il luogo di verifica e talvolta di esplorazione dei temi legati alla pratica professionale e, quindi, all’arte del costruire. Giachery, Professore di Architettura statica e civile dal 1837 al 1865, è il primo ad avvertire, da docente, la crisi profonda del sistema didattico della scuola di architettura di Palermo isterilita dalla ricerca di astratte idealità neoclassiche e straniatasi dal processo evolutivo della cultura architettonica europea dopo la morte dei “maestri” Marviglia e Gentile. Secon…

The School of Architecture of Palermo since its founding in 1779 with the creation of the chair of Civil Architecture entrusted to Joseph Venantius Marvuglia has become the place of testing exploration of issues related to professional practice and the art of building. Carlo Giachery Professor of Static and Civil Architecture from 1837 to 1865 is the first to feel the deep crisis of the educational system of the school of architecture of Palermo. For him architecture and applied sciences to architecture found in their stereotomy confirmation of the existence of correspondent relationships in their evolutionary process. The notion of stereotomy taken by Carlo Giachery in teaching reconnects directly to the noble art of coupe des pierres. Taken together the teaching aids used to show a theoretical advance that Giachery inclined in the direction of elasticity of the materials. Noting the outcomes of teaching his students have the clear perception of how the teaching on stereotomy is the compendium of all the French tradition on the subject. With the establishment of the School of Application for Engineers and Architects in 1866 the steretomia seems to gradually lose interest in favor of the prevailing metal construction. All the wisdom of build which for centuries had been linked with art de la coupe des pierres gave way to new construction techniques and new materials.Settore ICAR/14 - Composizione Architettonica E Urbana
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Ultreya, suseya, Santiago!” Viaggio e spazialità ne La ballata dei pellegrini

2020

Per studiare dal punto di vista della geografia culturale alcuni aspetti del pellegrinaggio a Santiago de Compostela, in Spagna, il capitolo prende in considerazione un testo letterario, il romanzo autobiografico "La ballata dei pellegrini" della scrittrice francese Edith De La Héronnière, pubblicato per la prima volta nel 1993 e tradotto in italiano nel 2004. Il romanzo racconta l’esperienza del pellegrinaggio giacobeo effettuato dall’autrice negli anni Novanta assieme a tre compagni di viaggio partendo da un cammino francese. In particolare, attraverso l’analisi di alcune parti del testo, si indagano le modalità attraverso le quali la narrazione costruisce e descrive lo spazio fisico e si…

The contribution critically and from a geographical perspective discusses the connection between propaganda comics and cartoons in the period of twentieth-century totalitarianisms. The way in which space real and symbolic is implicated through the rhetoric and dialectics of power in social economic and identity dynamics is then explored. In order to study some aspects of the pilgrimage to Santiago de Compostela from the point of view of cultural geography in Spain the chapter takes into consideration a literary text the autobiographical novel "The pilgrims' ballad" by the French writer Edith De La Héronnière first published in 1993 and translated into Italian in 2004. The novel recounts the experience of the Jacobean pilgrimage carried out by the author in the nineties together with three traveling companions starting from a French journey. In particular through the analysis of some parts of the text the ways in which the narration constructs and describes the physical and symbolic space of the pilgrimage are investigated. In this way it is possible to explore the way in which peculiar attributions of meaning inscribe the experience of pilgrimage in a symbolic universe that is both personal and collective at the same time.
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La scoperta, sistemazione e conservazione della grande Iscrizione di Gortina, nell'isola di Creta (1884-1921): la protezione delle testimonianze e le…

2013

La scoperta e la conservazione della Grande Iscrizione di Gortina a Creta, da parte degli studiosi italiani, fra la fine del XIX sec. e i primi decenni del XX sec., rappresentò un grande riconoscimento scientifico-culturale per la giovane nazione italiana. Nel passato, l’isola di Creta era stata legata alla Repubblica di Venezia e anche questo rapporto favorì l’invio a Creta del giovane epigrafista F. Halbherr, il quale fra notevoli peripezie rinvenne, assieme all’epigrafista tedesco E. Fabricius, la famosa l’iscrizione nell’antica città di Gortina. L’iscrizione, fra le più antiche e complete finora conosciute in tutta Europa, conteneva le norme sulla famiglia, l’eredità e in generale i dir…

The discovery and preservation of the Great Inscription of Gortyna in Crete by Italian researchers in the late nineteenth century. and the first decades of the twentieth century. was an important cultural and scientific recognition for the young Italian nation. In the past the island of Crete had been tied to the Republic of Venice and this report also favored sending in Crete the young epigraphist F. Halbherr who among considerable vicissitudes came to together to the epigraphist german E. Fabricius the inclusion of the famous ancient city of Gortyna. The inscription among the oldest and most comprehensive so far known throughout Europe the rules contained on the family's legacy in general and the rights and duties of some of the people of the Minoan civilization (480-450 BC). The inscription was carved on blocks organic limestone a restored ancient building which later in Roman times was turned into odeon. The Laws of Gortyn were engraved on the remains of the wall forming the passageway in front of the steps of the odeon. The essay traces the events that led to the discovery and subsequent storage made by Halbherr especially with the help of archaeologist L. Pernier and finally with the help of architect E. Stefani who designed a modern cover on the top of the ambulatory of the segments containing the inscription. This coverage was made to perform during the First World War on the basis of the Italian project from the Greek Government in order to protect the membership from possible war damage but especially from vandalism. The roof brick clay of the Laws of Gortyna still serves its function and ensures the use of the monument bearing witness to the preservation of Italian culture in Greece and more generally in the world. But in Sicily in the remains of the Villa del Casale in Piazza Armerina (Enna) its elegant protection (built in 1957) is representative of a whole period of culture of the Italian restoration is removed and replaced because it has not been able to make a ongoing maintenance is due. A bad example of conservation and management of a UNESCO monument from which arise after the work for the construction of new roofs an equally insulting to the archaeological heritage and scenic Italian and world.Settore ICAR/19 - Restauro
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Parallel Calculation of CCSDT and Mk-MRCCSDT Energies.

2010

A scheme for the parallel calculation of energies at the coupled-cluster singles, doubles, and triples (CCSDT) level of theory, several approximate iterative CCSDT schemes (CCSDT-1a, CCSDT-1b, CCSDT-2, CCSDT-3, and CC3), and for the state-specific multireference coupled-cluster ansatz suggested by Mukherjee with a full treatment of triple excitations (Mk-MRCCSDT) is presented. The proposed scheme is based on the adaptation of a highly efficient serial coupled-cluster code leading to a communication-minimized implementation by parallelizing the time-determining steps. The parallel algorithm is tailored for affordable cluster architectures connected by standard communication networks such as …

Theoretical computer scienceBasis (linear algebra)Computer scienceComputationGigabit EthernetCode (cryptography)Parallel algorithmBenchmark (computing)Basis functionPhysical and Theoretical ChemistryComputer Science ApplicationsComputational scienceAnsatzJournal of chemical theory and computation
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Fabrication and Characterization of Polymeric Optical Waveguides Using Standard Silicon Processing Technology

2005

We report the fabrication and characterization of a rib polymeric waveguide having a thick layer of oxidized porous silicon as an innovative solution for the lower cladding. The waveguide was fabricated using standard silicon substrates and Si-based technology. The multimodal guiding structure has a polymethylmetacrylate (PMMA) core and the innovative lower cladding was obtained by thermal oxidation of a porous silicon layer. The waveguide does not have the upper cladding. Propagation loss measurements were performed at 1.48 /spl mu/m using the cut-back method. We obtained propagation loss of about 1.7 dB/cm, confirming the possibility to use the porous silicon oxide as the lower cladding l…

Thermal oxidationMaterials scienceFabricationSiliconbusiness.industryHybrid silicon laserchemistry.chemical_elementPorous siliconCladding (fiber optics)Waveguide (optics)Optical waveguidesOpticschemistryOptoelectronicsbusinessRefractive indexWaveguidesEthers
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Influence of the Preparation Method and Photo-Oxidation Treatment on the Thermal and Gas Transport Properties of Dense Films Based on a Poly(ether-bl…

2018

Dense films based on the hydrophobic Pebax&reg

Thermogravimetric analysisMaterials scienceCompression molding02 engineering and technology010402 general chemistryMass spectrometrylcsh:Technology01 natural sciencesArticleContact angleDifferential scanning calorimetryGeneral Materials Sciencelcsh:Microscopylcsh:QC120-168.85lcsh:QH201-278.5lcsh:TPermeation021001 nanoscience & nanotechnologyMicrostructureCastingphoto-oxidation0104 chemical sciencesChemical engineeringlcsh:TA1-2040poly(ether-block-amide) copolymerlcsh:Descriptive and experimental mechanicslcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)0210 nano-technologylcsh:TK1-9971gas transport propertiesMaterials
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