Search results for "Gate"
showing 10 items of 1811 documents
Chromo-Fluorogenic Detection of Nitroaromatic Explosives by Using Silica Mesoporous Supports Gated with Tetrathiafulvalene Derivatives
2013
[EN] Three new hybrid gated mesoporous materials (SN3-1, SNH2-2, and SN3-3) loaded with the dye [Ru(bipy)(3)](2+) (bipy=bipyridine) and capped with different tetrathiafulvalene (TTF) derivatives (having different sizes and shapes and incorporating different numbers of sulfur atoms) have been prepared. The materials SN3-1 and SN3-3 are functionalized on their external surfaces with the TTF derivatives 1 and 3, respectively, which were attached by employing the click chemistry reaction, whereas SNH2-2 incorporates the TTF derivative 2, which was anchored to the solid through an amidation reaction. The final gated materials have been characterized by standard techniques. Suspensions of these s…
Tetrathiafulvalene-Capped Hybrid Materials for the Optical Detection of Explosives
2013
[EN] Mesoporous silica microparticles capped with TTF moieties and containing a ruthenium dye in the pores were used for the turn-on optical detection of the nitroaromatic explosives Tetryl and TNT via a selective pore uncapping and release of the entrapped dye.
Enzyme-Responsive Intracellular Controlled Release Using Nanometric Silica Mesoporous Supports Capped with "Saccharides"
2010
The synthesis of new capped silica mesoporous nanoparticles for on-command delivery applications is described. The gate-like functional hybrid systems consisted of nanoscopic MCM-41-based materials functionalized on the pore outlets with different “saccharide” derivatives and a dye contained in the mesopores. A series of hydrolyzed starch products as saccharides were selected. The mesoporous silica nanoparticles S1, S2, and S3 containing the grafted starch derivatives Glucidex 47, Gludicex 39, and Glucidex 29 were synthesized. Additionally, for comparative purposes solid S4 containing lactose was prepared. Delivery studies in pure water in the presence of pancreatin or -D-galactosidase were…
Enhanced Efficacy and Broadening of Antibacterial Action of Drugs via the Use of Capped Mesoporous Nanoparticles
2013
[EN] A novel nanodevice consisting of mesoporous nanoparticles loaded with vancomycin and capped with epsilon-poly-L-lysine (epsilon-PL) was prepared and its interaction with different Gram-negative bacteria studied. A remarkable improvement in the efficacy of the antimicrobial drug epsilon-PL and a broadening of the antimicrobial spectrum of vancomycin is demonstrated.
Enzyme-Mediated Controlled Release Systems by Anchoring Peptide Sequences on Mesoporous Silica Supports
2011
[EN] Gated community: Peptides anchored to the surface of silica mesoporous supports by a valid procedure act as gatekeepers. In this way, "zero release" supports that selectively deliver the cargo in the presence of a suitable peptidase are obtained (see picture, red spheres: cargo, colored chains: peptides). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fluorogenic Sensing of Carcinogenic Bisphenol A using Aptamer-Capped Mesoporous Silica Nanoparticles
2017
[EN] Mesoporous silica nanoparticles loaded with rhodamine B and capped with a bisphenol A aptamer were used for the selective and sensitive detection of this lethal chemical. The pores of the nanoparticles are selectively opened in the presence of bisphenol A (through its selective coordination with the aptamer) with subsequent rhodamine B delivery. With this capped material a limit of detection as low as 3.5 mu m of bisphenol A was measured.
Depth profiles of aggregate centers and nanodefects in LiF crystals irradiated with 34 MeV 84Kr, 56 MeV 40Ar and 12 MeV 12C ions
2018
I. Manika, J. Maniks and R. Zabels acknowledge the national project IMIS2. A. Dauletbekova, A. Akilbekov, M. Zdorovets and A. Seitbayev acknowledge the GF AP05134257of Ministry of Education and Science the Republic of Kazakhstan.
An MDE Approach for Rapid Prototyping and Implementation of Dynamic Reconfigurable Systems
2015
This article presents a co-design methodology based on RecoMARTE, an extension to the well-known UML MARTE profile, which is used for the specification and automatic generation of Dynamic and Partially Reconfigurable Systems-on-Chip (DRSoC). This endeavor is part of a larger framework in which Model-Driven Engineering (MDE) techniques are extensively used for modeling and via model transformations, generating executable models, which are exploited by implementation tools to create reconfigurable systems. More specifically, the methodological aspects presented in this article are concerned with expediting the conception and implementation of the hardware platform and the integration of corre…
Interactive effects of emotions on performance: an exploratory study in elite skeet shooters
2021
Este estudio investiga los efectos interactivos de múltiples emociones en el rendimiento (resultado) de tres tiradores de skeet de elite. La escala de emociones agregadas Emotional State Profile-40 (ESP-40; Hanin, 2010b) evalúa las experiencias emocionales recordadas asociadas con rendimientos exitosos y pobres y con rendimientos actuales. El rendimiento actual consiste en 20 series de 25 tiros. Los resultados confirman la utilidad práctica de la escala ESP-40 en la evaluación de los efectos interactivos de cuatro categorías de emoción en el rendimiento deportivo. Las emociones recordadas fueron instrumentales en la predicción de los resultados actuales. Se discute la utilidad de la regresi…
Image analysis for detecting aggregate gradation in asphalt mixture from planar images
2012
Abstract The mechanical properties of bituminous mixture strongly depend on the gradation of the aggregate that represents the mineral skeleton of the mixture, since for open and gap-graded mixtures, stresses due to vehicles in movement on the pavement are mainly transmitted through their contacts. Internal structure of bituminous mixture is, therefore, of great interest for road and infrastructure engineering and it is appropriate to study it with recently developed image analysis method. The purpose of this study was to finalize an effective analysis of asphalt section image for automatically extracting aggregate gradation without the need of separation of the bitumen from the aggregate. …