Search results for "ICT"

showing 10 items of 7961 documents

Improved detection of melanoma antigen-specific T cells expressing low or high levels of CD8 by HLA-A2 tetramers presenting a Melan-A/Mart-1 peptide …

2001

MHC class I tetramers containing peptide epitopes are sensitive tools for detecting antigen-specific CD8(+) T-cell responses. We demonstrate here that binding of HLA-A2 tetramers to CD8(+) T cells specific for the melanoma-associated antigen Melan-A/MART-1 can be fine-tuned by altering either the bound peptide epitope or residues in the alpha 3 domain of HLA-A2, which is important for CD8 binding. Antigen-specific T cells expressing high levels of CD8 could be detected using HLA-A2 tetramers containing the peptide AAGIGILTV, an epitope which is naturally processed and presented from Melan-A/MART-1. In contrast, low CD8-expressing, antigen-specific T cells could be detected efficiently only …

chemistry.chemical_classificationCancer ResearchbiologyT-cell receptorPeptideMHC restrictionVirologyMolecular biologyEpitopeOncologychemistryAntigenMHC class IMART-1 Antigenbiology.proteinCD8International Journal of Cancer
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Self-organized nanostructures of poly(4-vinylpyridine), polyaniline and polyamides due to metal complexation

2002

Comb-shaped supramolecules are constructed using flexible polymers and semi-rigid conjugated undoped or doped conjugated polymers upon complexing Zinc dodecyl benzene sulphonate, Zn(DBS) 2 . Self-organized nanostructures are formed in the bulk due to competing attractive interactions (coordination or water mediated hydrogen bonding) and repulsive polar/nonpolar interactions, showing characteristic long periods of ca. 30 A.

chemistry.chemical_classificationConductive polymerCOORDINATIONMaterials sciencePolymers and PlasticsHydrogen bondOrganic Chemistrychemistry.chemical_elementZincPolymerConjugated systemCondensed Matter PhysicsMetalchemistry.chemical_compoundchemistrySUPRAMOLECULAR POLYMERIC MATERIALSSYSTEMSvisual_artPolyanilinePolymer chemistryPolyamideComputingMethodologies_DOCUMENTANDTEXTPROCESSINGMaterials Chemistryvisual_art.visual_art_mediumGeneralLiterature_REFERENCE(e.g.dictionariesencyclopediasglossaries)Macromolecular Symposia
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A Solution to the Problem of the Maximal Number of Symbols for Biomolecular Computer

2019

The authors present a solution to the problem of generating the maximum possible number of symbols for a biomolecular computer using restriction enzyme BbvI and ligase as the hardware, and transition molecules built of double-stranded DNA as the software. The presented solution offers an answer to the open question, in the algorithm form, of the maximal number of symbols for a biomolecular computer that makes use of the restriction enzyme BbvI.

chemistry.chemical_classificationDNA ligaseComputer sciencebusiness.industrybiomolecular systemsbiomolecular computerComputer Science ApplicationsTheoretical Computer ScienceDNA computingRestriction enzymeSoftwarechemistryArtificial IntelligencebusinessAlgorithmSoftwareInformatica
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Bacterial communities in Arctic fjelds of Finnish Lapland are stable but highly pH-dependent

2007

The seasonal and spatial variations of microbial communities in Arctic fjelds of Finnish Lapland were studied. Phospholipid fatty acid analysis (PLFA) and terminal restriction fragment analysis (T-RFLP) of amplified 16S rRNA genes were used to assess the effect of soil conditions and vegetation on microbial community structures along different altitudes of two fjelds, Saana and Jehkas. Terminal restriction fragments were additionally analysed from c . 160 cloned sequences and isolated bacterial strains and matched with those of soil DNA samples. T-RFLP and PLFA analyses indicated relatively similar microbial communities at various altitudes and under different vegetation of the two fjelds. …

chemistry.chemical_classificationEcologybiologyFatty acidVegetationbiology.organism_classificationApplied Microbiology and BiotechnologyMicrobiologyRestriction fragmentchemistryMicrobial population biologySoil pHSoil waterBotanybiology.proteinRestriction fragment length polymorphismAcidobacteriaFEMS Microbiology Ecology
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Isolation of Alkaloids from Cultured Hybrid Cells of Rauwolfia serpentina*Rhazya stricta.

1996

Two monoterpenoid indole alkaloids and four β-carbolines were isolated from a hydrid cell suspension culture generated from two Apocynaceous plants, Rauwolfia serpentina Benth. and Rhazya stricta Decaisne. This indicates that the function of alkoloid biosynthesis is retained after hybrid formation and that alkaloids not previously detected in the parental plants or cell cultures are formed.

chemistry.chemical_classificationIndole alkaloidbiologyApocynaceaeChemistryAlkaloidMonoterpeneGlycosideGeneral ChemistryGeneral MedicinePharmacognosyRhazya strictabiology.organism_classificationCell cultureDrug DiscoveryBotanyheterocyclic compoundsChemical and Pharmaceutical Bulletin
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Halloysite Nanotubes for Cleaning, Consolidation and Protection

2017

Herein, we report our recent research concerning the development of halloysite based protocols for cleaning, consolidation and protection purposes. Surface modification of halloysite cavity by anionic surfactants was explored to fabricate inorganic micelles able to solubilize hydrophobic contaminants. Hybrid dispersions based on halloysite and ecocompatible polymers were tested as consolidants for paper and waterlogged archaeological woods. Encapsulation of deacidifying and flame retardant agents within the halloysite lumen was conducted with aim to obtain nanofiller with a long-term protection ability. The results prove the suitability and versatility of halloysite nanotubes, which are per…

chemistry.chemical_classificationMaterials scienceConsolidation (soil)General Chemical Engineering02 engineering and technologyGeneral ChemistryPolymerengineering.materialThe work was financially supported by the University of Palermo. The authors have no conflicts of interest to declare.010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistryHalloysite0104 chemical scienceschemistryChemical engineeringSolubilizationMaterials ChemistryengineeringSurface modification0210 nano-technologyInorganic nanoparticlesFire retardantThe Chemical Record
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Electrooptic coefficient measurements by Mach Zehnder interferometric method: Application of Abelès matrix formalism for thin film polymeric sample d…

2013

Abstract In Mach–Zehnder interferometric (MZI) method for determination of thin organic film electrooptic ( EO ) coefficients r 13 and r 33 critical effects, like multiple internal reflections and sample thickness modulation due to electrostriction and piezoelectricity are usually overlooked. Ignoring these effects may lead to inaccurate calculation of EO coefficients from experimental data by the simplified equations. To describe the influence of the above mentioned effects on the output of a MZI containing a thin film polymer sample we have used the Abeles matrix formalism.

chemistry.chemical_classificationMaterials scienceElectrostrictionbusiness.industryPolymerMach–Zehnder interferometerPiezoelectricityAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsInterferometryOpticschemistryModulationElectrical and Electronic EngineeringPhysical and Theoretical ChemistryThin filmbusinessPhase modulationOptics Communications
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Influence of solvents on the antioxidant property of flavonoids.

2003

In polyphenols redox systems, the solvent plays a fundamental role in the chemical behaviour of these compounds. Antioxidants can react in different ways with the prooxidant molecules. We have found differences in the antioxidant capacity of flavonoids such as naringin, neohesperidin, neoericitrin, hesperidin, narirutin didymin and the related flavones naringenin, hesperetin eriodictyol and isosakuratenin, when they are in the presence of radicals and solved in water or in an alcohol mixture.

chemistry.chemical_classificationNeohesperidinNaringeninFlavonoidsNarirutinFree RadicalsHesperetinEriodictyolFlavonesAntioxidantschemistry.chemical_compoundHesperidinchemistrySolventsOrganic chemistryReactive Oxygen SpeciesNaringinOxidation-ReductionFood ScienceDie Nahrung
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Pollutant Adsorbtion and Detection: Methyl-Substituted α-Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluorom…

2018

The cover image depicts the hazard caused by chlorofluorocarbons such as CFC‐11, which are used, for example, as blowing agents for polyurethane foams, and the protective effect of the oligosaccharide, hexakis‐(2,3,6‐tri‐O‐methyl)‐α‐cyclodextrin, which is capable of binding CFC‐11 by supramolecular complexation and thus protecting the stratospheric ozone layer from the harmful trichlorofluoromethane. Further details can be found in article number 1800057 by Ralf Hellmann, Siegfried R. Waldvogel, and co‐workers.

chemistry.chemical_classificationPollutantoptical sensorsCyclodextrinTrichlorofluoromethaneGlobal challengesCFC‐11Supramolecular chemistrysupramolecular chemistrychemistry.chemical_compoundAdsorptioncyclodextrinchemistryCover PictureOrganic chemistrytrichlorofluoromethaneGlobal Challenges
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B-DNA Structure and Stability as Function of Nucleic Acid Composition. Dispersion-Corrected DFT Study of Dinucleoside-Monophosphate Single and Double…

2013

actions of the sugar-phosphate skeleton with water; (6) hydrophobic interactions of the DNA cylindrical core, made up by the hydrogen-bonded and stacked nitrogen bases, with the water solvent. Recently, there has been increasing effort in developing and applying quantum chemical methods able to reproduce the structure of native B-DNA and to correctly describe the energy involved in the intrastrand and interstrand noncovalent interactions between the nucleotide monomers. This topic has been approached by both wave function methods and density functional theory. [2] Water solvent and sodium counterions also play an important role in the formation and relative stabilization of the double-helic…

chemistry.chemical_classificationStereochemistryChemistryBase pairHydrogen bondStackingGeneral ChemistryCrystal structureFull Papersstacking interactionsNucleobaseHydrophobic effectCrystallographyDNA structuresSettore CHIM/03 - Chimica Generale E Inorganicadensity functional calculationshydrogen bondsNon-covalent interactionsDNA DFT calculations structure stabilityDensity functional theoryWatson–Crick base pairsTheoretical ChemistryGeneralLiterature_REFERENCE(e.g.dictionariesencyclopediasglossaries)
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