Search results for "Magnet"

showing 10 items of 15436 documents

Acid–base properties of functionalised tripodal polyamines and their interaction with nucleotides and nucleic acids

2010

Novel, highly positively charged tripodal polyamines with appended heterocyclic moieties revealed an intriguing panel of protonation species within the biologically relevant range. Studied compounds bind nucleotide monophosphates by mostly electrostatic interactions but only the imidazole analogue showed selectivity toward UMP in respect to other nucleotides. Strong binding of all the studied compounds to both ds-DNA and ds-RNA is to some extent selective toward the latter, showing rather rare RNA over DNA preference.

tripodal polyamines; DNA and RNA interactions; RNA selectivity; nucleotidesMagnetic Resonance SpectroscopyStereochemistryProtonation010402 general chemistry01 natural sciencesBiochemistrychemistry.chemical_compoundNucleic AcidsPolyaminesImidazoleNucleotidePhysical and Theoretical Chemistrychemistry.chemical_classificationMolecular StructureNucleotides010405 organic chemistryOrganic ChemistryWaterRNANuclear magnetic resonance spectroscopyHydrogen-Ion Concentration0104 chemical sciencesSolutionsChemistrychemistryNucleic acidThermodynamicsProtonsSelectivityDNAOrganic & Biomolecular Chemistry
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An experimental and theoretical study of a heptacoordinated tungsten(VI) complex of a noninnocent phenylenediamine bis(phenolate) ligand

2018

Abstract [W(N2O2)(HN2O2)] (H4N2O2 = N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine) with a noninnocent ligand was formed by reaction of the alkoxide precursor [W(eg)3] (eg = the 1,2-ethanediolate dianion) with two equivalents of ligand. The phenol groups on one of the ligands are completely deprotonated and the ligand coordinates in a tetradentate fashion, whereas the other ligand is tridentate with one phenol having an intact OH group. The molecular structure, magnetic measurements, EPR spectroscopy, and density functional theory calculations indicate that the complex is a stable radical with the odd electron situated on the tridentate amidophenoxide ligand. The formal ox…

tungstenDFT calculations010402 general chemistry01 natural scienceslaw.inventionInorganic Chemistrychemistry.chemical_compoundDeprotonationlawOxidation stateMaterials ChemistryMoleculePhysical and Theoretical ChemistryElectron paramagnetic resonanceta116amidophenoxide radical010405 organic chemistryLigandkompleksiyhdisteetvolframielectronic structure0104 chemical sciencesCrystallographyoxidation statesUnpaired electronchemistryAlkoxidenoninnocent ligandDensity functional theoryInorganic Chemistry Communications
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Electronic Energy Meter Based on a Tunnel Magnetoresistive Effect (TMR) Current Sensor

2017

In the present work, the design and microfabrication of a tunneling magnetoresistance (TMR) electrical current sensor is presented. After its physical and electrical characterization, a wattmeter is developed to determine the active power delivered to a load from the AC 50/60 Hz mains line. Experimental results are shown up to 1000 W of power load. A relative uncertainty of less than 1.5% with resistive load and less than 1% with capacitive load was obtained. The described application is an example of how TMR sensing technology can play a relevant role in the management and control of electrical energy.

tunnel magnetoresistance; current sensor; energy meter; power measurement; wattmeter; internet-of-thingsEngineeringMagnetoresistancepower measurementPower factorlcsh:Technology01 natural sciencesArticlelaw.inventionElectricity meterlaw0103 physical sciencescurrent sensorinternet-of-thingsGeneral Materials ScienceCurrent sensorlcsh:Microscopylcsh:QC120-168.85wattmeter010302 applied physicslcsh:QH201-278.5lcsh:Tbusiness.industrytunnel magnetoresistance010401 analytical chemistryElectrical engineeringWattmeterAC powerenergy meterLine (electrical engineering)0104 chemical sciencesTunnel magnetoresistancelcsh:TA1-2040lcsh:Descriptive and experimental mechanicslcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)businesslcsh:TK1-9971Materials; Volume 10; Issue 10; Pages: 1134
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The OLYMPUS Experiment

2014

Nuclear instruments & methods in physics research / A 741, 1 - 17 (2014). doi:10.1016/j.nima.2013.12.035

two-photon [exchange]Physics - Instrumentation and DetectorsPhysics::Instrumentation and DetectorsHadronluminosity: monitoringRecoil4-MOMENTUM TRANSFERSNuclear Experiment (nucl-ex)Nuclear ExperimentInstrumentationNuclear ExperimentPhysicsElastic scatteringLuminosity (scattering theory)ELECTROMAGNETIC FORM-FACTORSInstrumentation and Detectors (physics.ins-det)elastic scattering [cross section]positron p: elastic scatteringAntimatterdrift chamberelastic scattering [electron p]target [hydrogen]proportional chamberCROSS-SECTIONNuclear and High Energy PhysicsELECTRON-PROTONDESY DORIS StorFOS: Physical sciencesmonitoring [luminosity]time-of-flight530electron p: elastic scatteringNuclear physicsCross section (physics)RATIO(GEV/C)(2)p: form factor: ratiocalorimeterddc:530cross section: elastic scatteringactivity reporthydrogen: targetexchange: two-photonScatteringPOSITRONSDESYelastic scattering [positron p]magnetic spectrometerELECTROMAGNETIC FORM-FACTORS; PROTON ELASTIC-SCATTERING; 4-MOMENTUM TRANSFERS; ELECTRON-PROTON; CROSS-SECTION; RATIO; (GEV/C)(2); POSITRONSform factor: ratio [p]gas electron multiplierPhysics::Accelerator PhysicsPROTON ELASTIC-SCATTERINGHigh Energy Physics::Experiment
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Terapia trans-cranica ad ultrasuoni focalizzati guidati da Risonanza Magnetica: studio retrospettivo di semeiotica neuroradiologica intra-operatoria

2019

SCOPO DEL LAVORO: Valutare retrospettivamente le caratteristiche di semeiotica neuroradiologica delle lesioni indotte in pazienti sottoposti a talamotomia unilaterale del nucleo Vim mediante l’utilizzo di un sistema trans-cranico ad ultrasuoni focalizzati guidati da RM (tcMRgFUS). MATERIALI E METODI: Cinquanta pazienti sono stati sottoposti a talamotomia mediante tcMRgFUS per tremore essenziale refrattario a terapia medica (n = 39) o per tremore in malattia di Parkinson (n = 11). Esaminando sequenze FRFSE T2-pesate (2mm, no gap) acquisite sia intra-operatoriamente che nel successivo follow-up RM a 48h, è stata valutata la presenza e le dimensioni delle aree lesionali concentriche precedente…

ultrasuoni focalizzati risonanza magnetica imaging intraoperatorio talamotomia tremore essenziale parkinsonSettore MED/27 - NeurochirurgiaSettore MED/37 - NeuroradiologiaSettore MED/26 - NeurologiaSettore MED/36 - Diagnostica Per Immagini E Radioterapia
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Terapia trans-cranica ad ultrasuoni focalizzati guidati da Risonanza Magnetica (tcMRgFUS) utilizzando un sistema integrato con uno scanner RM da 1.5T…

2018

Scopo Negli ultimi anni la terapia transcranica ad ultrasuoni focalizzati guidati da risonanza magnetica (tcMRgFUS) per il trattamento di disordini neurologici quali il tremore essenziale (ET) e il Parkinson tremorigeno (PD) è stata effettuata utilizzando esclusivamente scanner RM da 3T. Presentiamo i risultati ottenuti con il primo sistema tcMRgFUS mai integrato con uno scanner RM da 1.5T. Materiali e metodi 23 pazienti (19 ET; 4 PD) sono stati selezionati per essere sottoposti a tcMRgFUS (talamotomia monolaterale; target: nucleo ventrale intermedio, VIM). I pazienti arruolati sono stati valutati prima del trattamento e 2 giorni dopo. L'efficacia del trattamento è stata valutata utilizzand…

ultrasuoni focalizzati risonanza magnetica parkinson tremore essenzialeSettore MED/27 - NeurochirurgiaSettore MED/37 - NeuroradiologiaSettore MED/26 - NeurologiaSettore MED/36 - Diagnostica Per Immagini E Radioterapia
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TRANSCRANIAL MAGNETIC RESONANCE-GUIDED FOCUSED ULTRASOUND (TCMRGFUS) CON SCANNER DA 1.5T: NOTA TECNICA

2018

Scopo La terapia dei disordini neurologici mediante tcMRgFUS è stata effettuata utilizzando esclusivamente scanner RM da 3T. Utilizzando uno scanner RM da 1.5T la qualità delle sequenze morfologiche utilizzabili per la pianificazione di questi trattamenti è risultata essere soddisfacente utilizzando la bobina body RF (quella utilizzata con scanner 3T). Tuttavia l'SNR delle sequenze utilizzate per la termometria RM è risultato inferiore allo standard accettabile per i trattamenti. È stata quindi sviluppata una bobina a 2 canali per assicurare un adeguato SNR. Presentiamo il protocollo di imaging efficacemente utilizzato per eseguire procedure tcMRgFUS con il primo sistema mai integrato …

ultrasuoni focalizzati risonanza magnetica signal-to-noise ratioSettore MED/37 - NeuroradiologiaSettore MED/36 - Diagnostica Per Immagini E RadioterapiaSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)
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Noninvasive neurostimulation methods for migraine therapy: The available evidence.

2016

Background Migraine is one of the most disabling neurological disorders. The current pharmacological armamentarium is not satisfying for a large proportion of patients because the responder rate does not exceed 50% on average and the most effective drugs often induce intolerable side effects. During recent years, noninvasive central and peripheral neuromodulation methods have been explored for migraine treatment. Overview A review of the available evidence suggests that noninvasive neuromodulation techniques could be beneficial for migraine patients. The transcranial stimulation methods allow modulating selectively cortical activity and can thus be curtailed to the patient’s pathophysiologi…

vagus nervesneurology (clinical)orbital stimulationmedicine.medical_specialtymedicine.medical_treatmentMigraine DisordersTranscranial Direct Current Stimulation03 medical and health sciences0302 clinical medicinePhysical medicine and rehabilitationmedicineHumans030212 general & internal medicineMigraine treatmentDeep transcranial magnetic stimulationNeurostimulationtranscranial direct current stimulation; transcranial magnetic stimulation; transcutaneous suprave stimulation; evidence-based medicine; humans; migraine disorders; transcranial direct current stimulation; transcranial magnetic stimulation; transcutaneous electric nerve stimulation; treatment outcome; neurology (clinical)orbital stimulation; vagus nervesEvidence-Based MedicineTranscranial direct-current stimulationbusiness.industryGeneral Medicinemedicine.diseaseTranscranial Magnetic StimulationNeuromodulation (medicine)Transcranial magnetic stimulationTreatment OutcomeMigraineAnesthesiaTranscutaneous Electric Nerve StimulationNeurology (clinical)business030217 neurology & neurosurgeryVagus nerve stimulationtranscutaneous suprave stimulationCephalalgia : an international journal of headache
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Perimenopausal women show modulation of excitatory and inhibitory neuromuscular mechanisms.

2021

Background Menopausal transition exposes women to an early decline in muscle force and motor function. Changes in muscle quality and function, especially in lower limbs, are crucial, as they expose individuals to increased risk of falls. To elucidate some of the related neuromuscular mechanisms, we investigated cortical inhibition and peripheral muscle twitch force potentiation in women during the early and late stages of perimenopause. Methods Participants were 63 women aged 48–55 years categorized as early (EP, n = 25) or late (LP, n = 38) perimenopausal according to serum follicle-stimulating hormone (FSH) levels and menstrual diaries. EP women had an irregular menstrual cycle and FSH  2…

vaihdevuodetlcsh:Public aspects of medicinemenopauselcsh:RA1-1270follikkelia stimuloiva hormoniEvoked Potentials MotorTMS silent periodlcsh:Gynecology and obstetricsTranscranial Magnetic StimulationPerimenopauseikääntyminenhermo-lihastoimintamotor cortextwitch force potentiationHumansMotor cortexFemalefollicle-stimulating hormoneMenopauseMuscle SkeletalFollicle-stimulating hormoneTwitch force potentiationlcsh:RG1-991lihasvoimaResearch ArticleBMC women's health
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Vascular Risk Factors in Mild Cognitive Impairment Subtypes

2007

<i>Background and Aim:</i> To investigate the role of vascular risk factors in different subtypes of mild cognitive impairment (MCI) in a multicentric, clinic-based, cross-sectional study. <i>Methods:</i> Two-hundred and seven subjects with MCI were included in the study: 33 with single non-memory MCI (snmMCI), 42 with multiple-domain amnestic MCI (mdMCI-a) and 132 with amnestic MCI (aMCI). Several clinical vascular risk factors and magnetic resonance imaging (MRI) brain lesions were evaluated. <i>Results:</i> snmMCI showed a higher frequency of ischaemic heart disease and of transient ischaemic attack (TIA)/stroke, a higher Hachinski ischaemic score and …

vasculopatia cerebralemedicine.medical_specialtymild cognitive impairment; demenza; vasculopatia cerebraleCognitive Neurosciencebehavioral disciplines and activitiesWhite matterDegenerative diseasemild cognitive impairmentInternal medicinemental disordersmedicineDementiaRisk factorPsychiatryStrokemedicine.diagnostic_testCognitive disorderMagnetic resonance imagingmedicine.diseaseHyperintensitynervous system diseasesPsychiatry and Mental healthmedicine.anatomical_structureCardiologydemenzaGeriatrics and GerontologyPsychology
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