Search results for "Microwave"

Effects of Weak Links in the Nonlinear Microwave Response of MgB2 Superconductor

2006

We report experimental results of second-harmonic (SH) response at microwave frequency in several ceramic MgB2 samples, prepared by different methods. The SH signal has been investigated as a function of the temperature and DC magnetic field. The investigation has been carried out at low magnetic fields, where nonlinear processes arising from motion of Abrikosov fluxons are ineffective. We show that the low-temperature SH emission is ascribable to processes involving weak links. Comparison among the peculiarities of the SH signal radiated by the different samples shows that the presence of weak links strongly depends on the sample preparation method, as well as the purity and morphology of …

Microwave Surface Resistance of High-Tc Superconductors near Liquid Nitrogen Temperature

2011

Multi-residue analysis of 30 currently used pesticides in fine airborne particulate matter (PM 2.5) by microwave-assisted extraction and liquid chrom…

2009

A confirmatory and rapid procedure has been developed for the determination of 30 currently used pesticides (CUP) in fine airborne particulate matter (PM 2.5) at trace level. The proposed method includes extraction of PM 2.5-bound pesticides by microwave-assisted extraction (MAE) followed by a direct injection into LC-MS/MS. The main parameters affecting the MAE extraction (time, temperature and volume of solvent) were optimised using statistical design of experiments (DoE). The matrix effect was also evaluated. Recoveries ranged from 72 to 109% and the limit of quantification (LoQ) was 32.5 pg m(-3) for chlorpyrifos, 13.5 pg m(-3) for fenhexamid, imazalil and prochloraz, and 6.5 pg m(-3) f…

Microwave-assisted tandem cross metathesis intramolecular Aza-Michael reaction: an easy entry to cyclic beta-amino carbonyl derivatives.

2007

Hoveyda−Grubbs catalyst in combination with BF3·OEt2 efficiently promotes tandem cross metathesis intramolecular aza-Michael reaction between enones and unsaturated carbamates resulting in the creation of β-amino carbonyl units. The use of microwave irradiation dramatically accelerates the process, enhancing the synthetic utility of this methodology for the preparation of these types of derivatives. When enantiomerically enriched α-branched amines were used as starting materials, the process was also very efficient, although with modest selectivity in the newly created stereocenter. The use of microwave irradiation led to an interesting effect, inverting the selectivity in the addition proc…

Layout influence on microwave performance of graphene field effect transistors

2018

The authors report on an in-depth statistical and parametrical investigation on the microwave performance of graphene FETs on sapphire substrate. The devices differ for the gate-drain/source distance and for the gate length, having kept instead the gate width constant. Microwave S -parameters have been measured for the different devices. Their results demonstrate that the cut-off frequency does not monotonically increase with the scaling of the device geometry and that it exists an optimal region in the gate-drain/source and gate-length space which maximises the microwave performance.

Graphene Field-Effect Transistors Employing Different Thin Oxide Films: A Comparative Study

2019

In this work, we report on a comparison among graphene field-effect transistors (GFETs) employing different dielectrics as gate layers to evaluate their microwave response. In particular, aluminum oxide (Al$_{2}$O$_{3}$), titanium oxide (TiO$_{2}$), and hafnium oxide (HfO$_{2}$) have been tested. GFETs have been fabricated on a single chip and a statistical analysis has been performed on a set of 24 devices for each type of oxide. Direct current and microwave measurements have been carried out on such GFETs and short circuit current gain and maximum available gain have been chosen as quality factors to evaluate their microwave performance. Our results show that all of the devices belonging …

Assessment and inter-comparison of recently developed/reprocessed microwave satellite soil moisture products using ISMN ground-based measurements

2019

Soil moisture (SM) is a key state variable in understanding the climate system through its control on the land surface energy, water budget partitioning, and the carbon cycle. Monitoring SM at regional scale has become possible thanks to microwave remote sensing. In the past two decades, several satellites were launched carrying on board either radiometer (passive) or radar (active) or both sensors in different frequency bands with various spatial and temporal resolutions. Soil moisture algorithms are in rapid development and their improvements/revisions are ongoing. The latest SM retrieval products and versions of products that have been recently released are not yet, to our knowledge, com…

Microwave-free magnetometry with nitrogen-vacancy centers in diamond

2016

We use magnetic-field-dependent features in the photoluminescence of negatively charged nitrogen-vacancy centers to measure magnetic fields without the use of microwaves. In particular, we present a magnetometer based on the level anti-crossing in the triplet ground state at 102.4 mT with a demonstrated noise floor of 6 nT/$\sqrt{\text{Hz}}$, limited by the intensity noise of the laser and the performance of the background-field power supply. The technique presented here can be useful in applications where the sensor is placed closed to conductive materials, e.g. magnetic induction tomography or magnetic field mapping, and in remote-sensing applications since principally no electrical acces…

Retrieval of characteristic parameters for water vapour transmittance in the development of ground based Sun-Sky radiometric measurements of columnar…

2014

Abstract. Sun–sky radiometers are instruments created for aerosol study, but they can measure in the water vapour absorption band allowing the estimation of columnar water vapour in clear sky simultaneously with aerosol characteristics, with high temporal resolution. A new methodology is presented for estimating calibration parameters (i.e. characteristic parameters of the atmospheric transmittance and solar calibration constant) directly from the sun–sky radiometer measurements. The methodology is based on the hypothesis that characteristic parameters of the atmospheric transmittance are dependent on vertical profiles of pressure, temperature and moisture occurring at each site of measurem…

Microwave assisted synthesis and solid-state characterization of lithocholyl amides of isomeric aminopyridines

2011

Microwave (MW) assisted synthesis and solid state structural characterizations of novel lithocholyl amides of 2-, 3-, and 4-aminopyridine are reported. It is shown that the MW technique is a proper method in the preparation of N-lithocholyl amides of isomeric aminopyridines. It offers many advantages compared to conventional heating. The molecular and crystal structures as well as the polymorphic and hydrated forms of prepared conjugates with their thermodynamic stabilities have been characterized by means of high resolution liquid- and solid-state NMR spectroscopy, single crystal and powder X-ray diffraction, and thermogravimetric analysis. Owing to the many biological functions of bile ac…