Search results for "NANOTUBES"

Electrical conductance of carbon nanotubes with misaligned ends

2013

During a manufacturing process, when a straight carbon nanotube is placed on a substrate, e.g., production of transistors, its two ends are often misaligned. In this study, we investigate the effects of multiwall carbon nanotubes’ (MWCNTs) outer diameter and chirality on the change in conductance due to misalignment of the two ends. The length of the studied MWCNTs was 120 nm, while the diameters ranged between 4 and 7 nm. A mixed finite element-tight-binding approach was carefully designed to realize reduction in computational time by orders of magnitude in calculating the deformation-induced changes in the electrical transport properties of the nanotubes. Numerical results suggest that ar…

Hybrid catalysts for CO 2 conversion into cyclic carbonates

2019

The conversion of carbon dioxide into valuable chemicals such as cyclic carbonates is an appealing topic for the scientific community due to the possibility of valorizing waste into an inexpensive, available, nontoxic, and renewable carbon feedstock. In this regard, last-generation heterogeneous catalysts are of great interest owing to their high catalytic activity, robustness, and easy recovery and recycling. In the present review, recent advances on CO 2 cycloaddition to epoxide mediated by hybrid catalysts through organometallic or organo-catalytic species supported onto silica-, nanocarbon-, and metal-organic framework (MOF)-based heterogeneous materials, are highlighted and discussed.

Plasmonic Nanosensors for the Label-Free Imaging of Dynamic Protein Patterns.

2020

We introduce a new approach to monitor the dynamics and spatial patterns of biological molecular assemblies. Our molecular imaging method relies on plasmonic gold nanoparticles as point-like detectors and requires no labeling of the molecules. We show spatial resolution of up to 5 μm and 30 ms temporal resolution, which is comparable to wide-field fluorescence microscopy, while requiring only readily available gold nanoparticles and a dark-field optical microscope. We demonstrate the method on MinDE proteins attaching to and detaching from lipid membranes of different composition for 24 h. We foresee our new imaging method as an indispensable tool in advanced molecular biology and biophysic…

Multifunctional Carrier Based on Halloysite/Laponite Hybrid Hydrogel for Kartogenin Delivery

2018

[Image: see text] A novel carrier system based on halloysite nanotubes (HNT), for the potential intraarticular delivery of kartogenin (KGN) by means laponite (Lap) hydrogel (HNT/KGN/Lap), is developed. The drug was first loaded into HNT, and the hybrid composite obtained was used as filler for laponite hydrogel. Both the filler and the hydrogel were thoroughly investigated by several techniques and the hydrogel morphology was imaged by transmission electron microscopy. Furthermore, the gelating ability of laponite in the presence of the filler and the rheological properties of the hybrid hydrogel were also investigated. The kinetic release of kartogenin from HNT and HNT/Lap hybrid hydrogel …

Bismuth-Catalyzed Growth of SnS2 Nanotubes and Their Stability

2009

Carbon nanotubes under electron irradiation: Stability of the tubes and their action as pipes for atom transport

2005

The production and migration of carbon interstitials in carbon nanotubes under electron irradiation is studied experimentally and theoretically. It is shown that the threshold for displacing carbon atoms and the defect production rate strongly depend on the diameter of the nanotubes. Multiwalled nanotubes shrink by a loss of atoms and by diffusion of interstitials through the inner hollow in the axial direction. Thus, experimental evidence is given that nanotubes can act as nanoscale pipes for the transport of atoms.

Photoelectrochemical characterization of Cu2O-nanowire arrays electrodeposited into anodic alumina membranes

2007

Perfectly aligned nanowire arrays of polycrystalline Cu2O were grown by template-pulsed electrodeposition from a cupric acetate-sodium acetate bath into anodic alumina membranes (AAM). The photoelectrochemical behavior of arrays with different nanowire lengths (0.5 mu m and 2 mu m) was investigated in neutral solution, and the results compared to those pertaining to Cu2O films grown with the same procedure. Although all samples displayed the same indirect bandgap (similar to 1.9 eV), differences were observed both in photocurrent intensity and sign. The latter changed with potential and wavelength in different ways for nanowires and films, revealing a different defect concentration in the t…

Modified nanocarbons as catalysts in organic processes

2019

The application of nanocarbons as useful scaffolds for the production of a wide range of catalytic systems is an ever-growing field as witnessed by the huge amount of research on this topic. Both covalent and non-covalent modifications of nanocarbons represent the main routes to gain access to hybrid nanostructured catalysts. In this chapter the attention will be focused on nanocarbons, namely, fullerene, nanotubes, and graphene, employed for catalytic purposes covering both organocatalytic and metal-based (metal nanoparticles, organometallic complexes) reactions, whereas simple physical mixtures of nanocarbons and metal nanoparticles as well as examples dealing with electrocatalysis or pho…

Graphene, Fullerenes, Carbon Nanotubes: Electronic Subsystem

2017

This chapter introduces the reader to the analysis of the structural and electronic system properties of various carbon allotropes (CNT, graphene) and several molecular derivatives. The genesis of the electronic system formation is investigated in detail. Non-regular defected nanocarbon systems are considered for possible applications in different fields, including energy storage; chemical, biochemical and electrochemical sensing; water purification; and catalysis.

New concepts and applications in macromolecular chemistry of fullerenes

2010

A new classification on the different types of fullerene-containing polymers is presented according to their different properties and applications they exhibit in a variety of fields. Because of their interest and novelty, water-soluble and biodegradable C(60)-polymers are discussed first, followed by polyfullerene-based membranes where unprecedented supramolecular structures are presented. Next are compounds that involve hybrid materials formed from fullerenes and other components such as silica, DNA, and carbon nanotubes (CNTs) where the most recent advances have been achieved. A most relevant topic is still that of C(60)-based donor-acceptor (D-A) polymers. Since their application in pho…