Search results for "Pill"
showing 10 items of 1870 documents
Quartz-capillary gas chromatography of chlorinated phenols and catechols
1983
The gas chromatography of all chlorinated phenols and catechols on a non-polar SE-30 quartz-capillary column has been studied. The relative retention times of the individual components are given and the elution order is discussed. All of the chlorophenols and chlorocatechols can be separated under appropriate operating conditions but simultaneous determination of all the compounds studied resulted in overlapping peaks. Theortho-effect in catechols is stronger than that in phenols. A different order of elution for the compounds studied to that of the corresponding acetate esters is found. Generally, longer retention times for the latter are observed.
ChemInform Abstract: Alkaloid Determination in Crude Extracts from Cortex Quebracho and Opium Applying Capillary Electrophoresis and Capillary Electr…
2010
The applicability of capillary electrophoresis with UV and electrospray ionisation (ESI)-mass spectrometric detection to the determination of alkaloids in crude extracts of Cortex Quebracho and opium has been investigated. The use of a buffer electrolyte consisting of aqueous ammonium acetate (pH 3.1) and acetonitrile resulted in a high performance of peak resolution. Most of the alkaloids have been identified according to the signal of the protonated molecular ion in the ESI mass spectrum
Ionic Liquids on Demand in Continuous Flow
2009
We report on the development of an alternative protocol for the facile, solvent-free synthesis of various novel imidazolium-based ionic liquids (ILs) that affords highly pure products without the necessity of subsequent purification steps. The continuous approach is based on the combination of HPLC pumps with a micromixer and a capillary residence tube. Our system provides a high degree of control over the alkylation reactions due to a high surface-to-volume ratio and superior heat and mass transport. Within the scope of our studies, we focused on ionic liquids containing differently substituted phenyl rings and characterized these compounds with respect to further use for direct applicatio…
ChemInform Abstract: Low-Loading Asymmetric Organocatalysis
2012
Asymmetric organocatalysis is now recognized as the third pillar of asymmetric synthesis. Recent years have witnessed increasing interest towards the use of highly active and stereoselective organocatalysts. This critical review documents the advances in the development of chiral organocatalysts which are systematically used in ≤3 mol% loading in all the sub-areas of the field, namely aminocatalysis, Bronsted acids and bases, Lewis acids and bases, hydrogen bond-mediated catalysis, phase transfer and N-heterocyclic carbene catalyses (194 references).
La capilla de la Virgen del Carmen y el arquitecto Vicente Gascó
2021
El presente trabajo revela parte del proceso constructivo y aspectos de culto de la capilla de la Virgen del Carmen (1774-1783), titular del antiguo convento carmelita de la ciudad de Valencia, constituyendo uno de los mejores ejemplos de arquitectura académica en la capital. En el año 1776, hallándose la capilla pendiente de proseguir la obra, tuvo lugar el informe para proceder al tallado, inspirado en la obra de Palladio, así como dos justiprecios de su coste. La investigación se completa con nuevas aportaciones a la biografía de su principal artífice, el arquitecto Vicente Gascó Masot (1734-1802). Entre ellas sobresale, dentro del inventario de bienes post mortem, su rica y variada bibl…
Ultrastructural comparative analysis on the adhesive papillae of the swimming larvae of three ascidian species
2009
This paper presents a preliminary report on the papillae of the swimming larvae of three ascidian species: Ascidia malaca, Phallusia mammillata and Ciona intestinalis. The investigations, carried out at ultrastructural level and at confocal laser microscope, have evidenced, in the adhesive papillae of the three studied species, three different cell-types: axial columnar cells, collocytes, sensory cells respectively. The adhesive papillae of A. malaca and P. mammillata show central axial columnar cells with long microvilli emerging from the apical edge and extending throughout the hyaline cap. Collocytes are elongated secreting cells, lying in middle-lateral side. Sensory cells have a cilium…
ANKRD26-RET - A novel gene fusion involving RET in papillary thyroid carcinoma
2018
Abstract Background Rearrangements of RET are drivers of oncogenesis, traceable in different cancer types as papillary thyroid carcinoma (PTC), non-small cell lung cancer, colorectal or breast cancer. Anchored multiplex PCR based next-generation sequencing (NGS) can detect RET rearrangements involving previously unknown partner genes. Methods A sample of PTC underwent NGS, following detection of RET rearrangement by fluorescence in situ hybridization. Expression analysis of ANKRD26 and RET was performed for the tumor harboring ANKRD26-RET, for corresponding normal thyroid tissue and PTC tumors with representative genetic alterations (BRAFV600E, CCDC6-RET), complemented by a comparative sear…
La construcción de bóvedas en la Sicilia del siglo XIV: las capillas palatinas
2013
Il saggio analizza la variegata gamma di soluzioni tecniche e formali riscontrabili nella costruzione di volte reali nella Sicilia del XIV secolo, attraverso la casistica osservabile nelle cappelle platine. Dall'esame dei casi studio selezionati emerge un panorama ricco e vario, indicativo di un intreccio di esperienze e modelli di diversa provenienza, a confutare la tradizionale visione storiografica di un'isola totalmente chiusa in se stessa nel Trecento.
Clubs de convergence et effets de débordements géographiques : une analyse spatiale sur données régionales européennes, 1980-1995
2007
Our article offers an econometric model of spatial interactions for the empirical analysis of growth in European regions over the period 1980-1995. The model detects spatial spillover effects and makes it possible to take account of the European economy’s strong polarization. More specifically, by factoring in both spatial autocorrelation and spatial heterogeneity, we characterize the economic polarization pattern in European regions, identify convergence clubs, and model them as spatial regimes. We estimate a two-regime model with spatially autocorrelated errors and show that the convergence process differs between the two regimes. We find a strongly significant spatial spillover effect : …
Estimation des effets de proximité dans le processus de convergence régionale : une approche par l'économétrie spatiale sur 92 régions européennes (1…
2002
L'objectif de cet article est d'examiner les conséquences de la dépendance spatiale sur la croissance régionale et le processus de convergence. Sur un échantillon de 92 régions européennes sur la période 1980-1995, nous montrons que le modèle de b-convergence absolue doit être re-spécifié en raison de la présence d'auto-corrélation spatiale. Les méthodes de l'économétrie spatiale nous orientent vers une spécification avec erreurs spatialement auto-corrélées qui nous permet de mettre en évidence un effet de débordement géographique. Nous montrons ainsi que le taux de croissance d'une région est influencé positivement par les taux de croissance des régions contiguës.