Search results for "TPH"
showing 10 items of 170 documents
Time spent on the smartphone does not relate to manual dexterity in young adults.
2021
Abstract Background The Grooved Pegboard Test (GPT) is widely adopted to evaluate manual dexterity, it presents normative data but the test is influenced by different factors. The influence of time spent on smartphones has not been considered before, for this reason, the objective of this study was to evaluate if smartphone use influences the time to complete the GPT. A total of 38 (21 women; 17 men) young adults 20.7 (1.5) years participated in the study. The time spent on the smartphones during the last seven days was recorded through the device itself and the GPT performance was measured. A correlation analysis between the time spent on the smartphone and GPT was performed while the t-te…
The extrabasinal elements in Lower Pennsylvanian floras of the Maritime Provinces, Canada: Description of Adiantites, Pseudadiantites and Rhacopterid…
2021
Adiantites adiantoide s (Lindley and Hutton) Kidston, Pseudadiantites sessilis (Roehl) Gothan and Pseudadiantites rhomboideus (Ettingshausen) comb. nov. are figured and described as well as Rhacopteridium speciosum (Ettingshausen) Hirmer, as part of a revision of lower Pennsylvanian floras of Nova Scotia. These species show a foliar branching structure which is described as "pseudopinnate" as against the fully planated pinnate structure of the Palaeozoic fern and pteridosperm fronds. Their systematic affinity is unknown. A discussion is presented of the genera A diantites, Pseudadiantites, Aneimites , Palaeopteridium , and Triphyllopteris , and the problematic nature of the history of Adian…
A Smartphone App to Promote Healthy Weight Gain, Diet, and Physical Activity During Pregnancy (HealthyMoms): Protocol for a Randomized Controlled Tri…
2019
BACKGROUND: Excessive gestational weight gain is common and associated with adverse outcomes both in the short and long term. Although traditional lifestyle-based interventions have shown to mitigate excess gestational weight gain, little is known about whether mobile Health (mHealth) apps can promote healthy weight gain, diet, and physical activity during pregnancy. OBJECTIVE: The primary aim of the HealthyMoms trial is to determine the effectiveness of a smartphone app (HealthyMoms) for mitigating excess gestational weight gain during pregnancy. Secondary aims are to determine the effectiveness of the app on dietary habits, physical activity, body fatness, and glycemia during pregnancy. M…
Séries charbonneuses dans des séquences rétrogradantes: cas du bassin houiller paralique westphalien de Jérada (Maroc)
1998
Abstract Several orders of stacked genetic sequences in the Westphalian C of the Jerada Basin are defined from detailed sedimentological data. Eight coal seams were formed in this paralic basin as distal facies passed laterally into proximal facies in retrogradational stages. These stages are related to base level rises that curtailed detrital influx and induced the development of swamps and the preservation of organic matter below anoxic water levels. The base level variations are related to active faulting along the basin margins and to sea level changes in the Palaeo-Tethys.
Parent of origin effects in attention/deficit hyperactivity disorder (ADHD): analysis of data from the international multicenter ADHD genetics (IMAGE…
2008
Contains fulltext : 71540.pdf (Publisher’s version ) (Closed access) There are conflicting reports suggesting that the parental origin of transmitted risk alleles may play a role in the etiology of attention deficit/hyperactivity disorder (ADHD). A recent report by Hawi and colleagues observed a generalized paternal over-transmission of alleles associated with ADHD. This was not replicated in more recent studies. Using data from a large multicenter study we examined the overall and gene-specific parent of origin effect in 554 independent SNPs across 47 genes. Transmission disequilibrium and explicit parent of origin test were performed using PLINK. Overall parent of origin effect was tested…
Organics versus clastics: conditions necessary for peat (coal) development
1990
Abstract The absence or lack of detrital influx into ancient peat-forming swamps is critical to the formation of low-ash coal. Modern and ancient coal-forming swamps of continental basins show a separation of peat and clastic sediments which is partially fault controlled. In the African rift valleys as well as in the Stephanian intermontane coal basins of France, thick peat free from clastic input may be the result of tectonic activity. In the paralic basins of Morocco (Westphalian B) and Nigeria (Late Cretaceous) coal occur landward of the shoreline turnaround and are related to a relative high stand of the sea, which curtailed detrital influx into the basins. Thus, peat formation occurred…
Peripheral halo-functionalization in [Cu(N^N)(P^P)]+ emitters: influence on the performances of light-emitting electrochemical cells
2016
A series of heteroleptic [Cu(N^N)(P^P)][PF6] complexes is described in which P^P = bis(2-(diphenylphosphino)phenyl)ether (POP) or 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (xantphos) and N^N = 4,4′-diphenyl-6,6′-dimethyl-2,2′-bipyridine substituted in the 4-position of the phenyl groups with atom X (N^N = 1 has X = F, 2 has X = Cl, 3 has X = Br, 4 has X = I; the benchmark N^N ligand with X = H is 5). These complexes have been characterized by multinuclear NMR spectroscopy, mass spectrometry, elemental analyses and cyclic voltammetry; representative single crystal structures are also reported. The solution absorption spectra are characterized by high energy bands (arising from ligand-c…
Photoluminescent Cu(i) vs. Ag(i) complexes: slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states.
2019
This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4'-(MeO)2-2,2'-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9'-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.
Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(iii) complexes bearing bisphosphine ligands
2016
EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and AKB acknowledge support from EPSRC (EP/J01771X). This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) MAT2014-55200. Herein we present a structure-property relationship study of thirteen cationic iridium (III) complexes of the form of [Ir(C^N)2(P^P)]PF6 in both solution and the solid state through systematic evaluation of six bisphosphine (P^P) ligands (xantphos, dpephos, dppe, Dppe, nixantphos and is…
σ-Hammett parameter: a strategy to enhance both photo- and electro-luminescence features of heteroleptic copper(i) complexes
2017
This work studies the effect of the σ-Hammett parameter (σp) – i.e., the σ-donation effect caused by substitution at the para position of a bipyridine ligand (4,4′-R2bipy, where R is MeO, Me, H, NO2) – on both the photo- and electro-luminescence features of a series of heteroleptic copper(I) complexes – i.e., [Cu(N^N)(P^P)]+ where N^N and P^P ligands are R2bipy and Xantphos, respectively. By virtue of a comprehensive photophysical, theoretical, and thin-film lighting device – i.e., light-emitting electrochemical cells (LECs) – investigation, we note a clear relationship between the σp and the photo- and electro-luminescence parameters, such as photoluminescence quantum yields, excited-state…