Search results for "purity"
showing 10 items of 356 documents
Plasmon excitations in chemically heterogeneous nanoarrays
2020
| openaire: EC/H2020/838996/EU//RealNanoPlasmon The capability of collective excitations, such as localized surface plasmon resonances, to produce a versatile spectrum of optical phenomena is governed by the interactions within the collective and single-particle responses in the finite system. In many practical instances, plasmonic metallic nanoparticles and arrays are either topologically or chemically heterogeneous, which affects both the constituent transitions and their interactions. Here, the formation of collective excitations in weakly Cu- and Pd-doped Au nanoarrays is described using time-dependent density functional theory. The additional impurity-induced modes in the optical respo…
Measurement of trace impurities in ultra pure hydrogen and deuterium at the parts-per-billion level using gas chromatography
2018
Abstract A series of muon experiments at the Paul Scherrer Institute in Switzerland deploy ultra-pure hydrogen active targets. A new gas impurity analysis technique was developed, based on conventional gas chromatography, with the capability to measure part-per-billion (ppb) traces of nitrogen and oxygen in hydrogen and deuterium. Key ingredients are a cryogenic admixture accumulation, a directly connected sampling system and a dedicated calibration setup. The dependence of the measured concentration on the sample volume was investigated, confirming that all impurities from the sample gas are collected in the accumulation column and measured with the gas chromatograph. The system was calibr…
Optical properties and spectrometric performance of TlBr detector crystals
2006
Abstract It is shown that preliminary TlBr crystals optical parameters testing can be used for detector crystal selection. Absorption in fundamental spectral region was used for the band gap width definition and determination of homological impurities presence. The luminescence was applied for impurity and defects content study. Radionuclide spectra 241Am were measured using the ionizing radiation detectors with planar electrodes made from TlBr crystals. The detector energy resolution for TlBr detectors produced from different row materials was summarized and the results of detector testing parameters and results of optical investigation were compared.
Optical investigations of TlBr detector crystals
2004
Shift of fundamental absorption edge, the position of main luminescence bands, the luminescence decay and transient absorption spectra in three TlBr crystals were studied. The γ-quanta detector made from TlBr crystals with similar transient absorption and luminescence parameters shows similar detector properties. The iodine impurity in TlBr was detected by optical methods. The role of impurities and crystal defects in γ-quanta detectors manufactured is discussed.
A purity monitoring system for liquid argon calorimeters
2005
Abstract For liquid argon calorimeters electronegative impurities dissolved in the medium degrade the detector response and deteriorate the energy resolution, especially at high energies. A concept for a purity monitoring system for liquid argon calorimeters has been developed and is presented here. Special combined monitors of 241 Am- and 207 Bi-cells are used to monitor the concentration of impurities. The working principle as well as results from test measurements are discussed.
Observation of scattering and absorption centers in lead fluoride crystals
2006
For the first time, lead fluoride is used as a fast and compact material in electromagnetic calorimetry. Excellent optical and mechanical properties of the pure Cherenkov crystals are necessary for the A4 collaboration to perform a measurement of the nucleon's strange form factors. Visible scattering and absorption centers as well as surface damages have been investigated to characterize the quality of more than one thousand crystals. Besides, transmittance measurements have been performed on all crystals to reveal absorption bands produced by intrinsic or impurity related point-structure defects. As a consequence, 89 crystals had to be replaced by the Chinese manufacturer SICCAS.
Theoretical study of resonant x-ray emission spectroscopy of Mn films on Ag.
2006
We report a theoretical study on resonant x-ray emission spectra (RXES) in the whole energy region of the Mn $L_{2,3}$ white lines for three prototypical Mn/Ag(001) systems: (i) a Mn impurity in Ag, (ii) an adsorbed Mn monolayer on Ag, and (iii) a thick Mn film. The calculated RXES spectra depend strongly on the excitation energy. At $L_3$ excitation, the spectra of all three systems are dominated by the elastic peak. For excitation energies around $L_2$, and between $L_3$ and $L_2$, however, most of the spectral weight comes from inelastic x-ray scattering. The line shape of these inelastic ``satellite'' structures changes considerably between the three considered Mn/Ag systems, a fact tha…
Elastic properties, structures and phase transitions in model colloids
2004
The nature of the melting transition for a system of hard discs with translational degrees of freedom in two spatial dimensions has been analysed by a combination of computer simulation methods and a finite size scaling technique. The behaviour of the system is consistent with the predictions of the Kosterlitz–Thouless–Halperin–Nelson–Young (KTHNY) theory. The structural and elastic properties of binary colloidal mixtures in two and three spatial dimensions are discussed as well as those of colloidal systems with quenched point impurities. Hard and soft discs in external periodic (light-) fields show rich phase diagrams including freezing and melting transitions when the density of the syst…
Statistical properties of the eigenvalue spectrum of the three-dimensional Anderson Hamiltonian
1993
A method to describe the metal-insulator transition (MIT) in disordered systems is presented. For this purpose the statistical properties of the eigenvalue spectrum of the Anderson Hamiltonian are considered. As the MIT corresponds to the transition between chaotic and nonchaotic behavior, it can be expected that the random matrix theory enables a qualitative description of the phase transition. We show that it is possible to determine the critical disorder in this way. In the thermodynamic limit the critical point behavior separates two different regimes: one for the metallic side and one for the insulating side.
Shape analysis of the level-spacing distribution around the metal-insulator transition in the three-dimensional Anderson model
1995
We present a new method for the numerical treatment of second order phase transitions using the level spacing distribution function $P(s)$. We show that the quantities introduced originally for the shape analysis of eigenvectors can be properly applied for the description of the eigenvalues as well. The position of the metal--insulator transition (MIT) of the three dimensional Anderson model and the critical exponent are evaluated. The shape analysis of $P(s)$ obtained numerically shows that near the MIT $P(s)$ is clearly different from both the Brody distribution and from Izrailev's formula, and the best description is of the form $P(s)=c_1\,s\exp(-c_2\,s^{1+\beta})$, with $\beta\approx 0.…