PULSED LASER DEPOSITION OF ND:YAG THIN FILMS

Space Charge and Carrier Trapping Effects on the Transient Photocurrents of Organic Materials Using the Time-of-Flight Technique

We apply the time-of-flight (TOF) technique to study space charge and carrier trapping effects in the organic materials N,N'-diphenyl-N,N'-bis(3- methylphenyl)-1,1-biphenyl-4,4'-diamine (TPD) and tris(8-hydroxyquinolato) aluminum (Alq3). This is carried out by changing the applied electric field, the laser pulse intensity, and the repetition rate together with environmental conditions in air or in vacuum. We report for the first time, to the best of our knowledge, a clearly nondispersive electron transport in TPD due to the absence of deep traps. Conversely, Alq3 exhibits a dispersive electron transport. However, this can be partially recovered by leaving the sample in high vacuum for sever…

Efficiency enhancement of organic light emitting diodes by NaOH surface treatment of the ITO anode

Abstract Organic light emitting diodes (OLEDs) based on tris-(8-idroxyquinoline)aluminum (Alq 3 ) with enhanced efficiency are reported here. This is obtained by improving the charge carrier balance, through a preliminary NaOH surface treatment of the indium tin oxide (ITO) anode, in order to decrease its work function and, consequently, reduce the hole injection. The obtained devices exhibit a 1.36% external quantum efficiency and a 1.2 lm/W power efficiency at a current density of 60 mA/cm 2 . These values are more than double as compared with those of identical reference devices fabricated without the preliminary NaOH surface treatment.

Blue Emitting Organic Light Emitting Diodes

Organic light emitting diodes (OLEDs) [1] can be fabricated on a range of materials such as glass, silicon or flexible plastic substrates. This can be exploited for the realization of integrated OLED-based fluorescence chemical sensors [2] and microfluidic systems [3] for application in areas such as biotechnology, life sciences, pharmaceuticals, public health and defense. These devices hold promises to be cost effective, ultra-compact (including the possibility to be fabricated into large bidimensional arrays), and capable to handle smaller sample volumes in order to achieve high throughput. Blue light is advantageous because it is strongly absorbed by most sensing molecules attached to bi…

Study of voltage decrease in organic light emitting diodes during the initial stage of lifetime

Abstract We report the results of lifetime DC testing at constant current of not-encapsulated organic light emitting diodes (OLEDs) based on Tris (8 idroxyquinoline) aluminum (Alq3) as emitting material. In particular, a voltage decrease during the initial stage of the lifetime test is observed. The cause of this behavior is also discussed, mainly linked to initial Joule self-heating of the device, rising its temperature above room temperature until thermal equilibrium is reached at steady state.

Investigation on Metal–Oxide Graphene Field-Effect Transistors With Clamped Geometries

In this work, we report on the design, fabrication and characterization of Metal-Oxide Graphene Field-effect Transistors (MOGFETs) exploiting novel clamped gate geometries aimed at enhancing the device transconductance. The fabricated devices employ clamped metal contacts also for source and drain, as well as an optimized graphene meandered pattern for source contacting, in order to reduce parasitic resistance. Our experimental results demonstrate that MOGFETs with the proposed structure show improved high frequency performance, in terms of maximum available gain and transition frequency values, as a consequence of the higher equivalent transconductance obtained.

Effect of driving method on the degradation of organic light emitting diodes

Abstract Lifetime testing results are reported for organic light emitting diodes (OLEDs) having the structure ITO (anode)/ N , N ′-diphenyl- N , N ′-bis(3-methylphenyl)-1,1′-diphenyl-4,4′-diamine (TPD)/tris-(8-hydroxyquinoline)aluminum (AlQ)/Al (cathode) and operated using dc and pulsed waveforms for comparison. In ambient atmosphere non-encapsulated devices show a lifetime of about 70 h in pulsed operation at an initial luminance of 500 cd/m 2 , almost four times longer than in dc operation. A fast initial decay of luminance is observed for dc operation. It is most probably due to a combination of Joule heating and mobile ionic impurities migration within the OLED structure under the conti…

Donor/Acceptor Heterojunction Organic Solar Cells

The operation and the design of organic solar cells with donor/acceptor heterojunction structure and exciton blocking layer is outlined and results of their initial development and assessment are reported. Under halogen lamp illumination with 100 mW/cm2 incident optical power density, the devices exhibits an open circuit voltage VOC = 0.45 V, a short circuit current density JSC between 2 and 2.5 mA/cm2 with a fill factor FF &asymp

An Example of Ti:LiNbO3 Device Fabrication: The Mach-Zehnder Electrooptical Modulator

Integrated optics on LiNbO3 has already reached a stage of maturity. Several manufacturers are producing standard and custom devices on LiNbO3 such as high speed (up to 20 GHz) phase and intensity modulators, switching matrices, hybrid optical gyroscopes, etc.1. Two techniques are commonly used to fabricate these devices: titanium indiffusion for 1.3 and 1.5 μm wavelength operation and annealed proton exchange (APE) at 0.8 μm, due to its higher power handling capacity.

Graded reflectivity micromirror arrays

A technique for fabricating arrays of graded reflectivity micromirrors with diameters as small as 25 microm is reported. It is based on laser-induced physical vapor deposition through microholes on a thin free-standing noncontact mask, and it is suitable for applications in micro-optics and solid-state laser technology.

Measurement of drift mobilities in amorphous organic films using the Time of Flight method

We apply the Time of Flight (TOF) technique to study carrier mobility in N, N’-diphenyl-N,N’-bis(3-methylphenyl) -1,1-biphenyl-4,4’-diamine (TPD) and tris(8-hydroxyquinolato) aluminium (Alq 3 ). These materials are two examples of, respectively, hole and electron transporting molecular materials. Measurements are performed in free air or under vacuum varying the experimental parameters such as laser pulse intensity and single shot irradiation. We observe a transition from dispersive to non dispersive transport changing the experimental conditions.