0000000001298922

AUTHOR

Marius Andruh

showing 98 related works from this author

Heterotrimetallic coordination polymers: {Cu(II)Ln(III)Fe(III)} chains and {Ni(II)Ln(III)Fe(III)} layers: synthesis, crystal structures, and magnetic…

2015

The use of the [Fe(III) (AA)(CN)4](-) complex anion as metalloligand towards the preformed [Cu(II) (valpn)Ln(III)](3+) or [Ni(II) (valpn)Ln(III) ](3+) heterometallic complex cations (AA=2,2'-bipyridine (bipy) and 1,10-phenathroline (phen); H2 valpn=1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol)) allowed the preparation of two families of heterotrimetallic complexes: three isostructural 1D coordination polymers of general formula {[Cu(II) (valpn)Ln(III) (H2O)3 (μ-NC)2 Fe(III) (phen)(CN)2 {(μ-NC)Fe(III) (phen)(CN)3}]NO3 ⋅7 H2O}n (Ln=Gd (1), Tb (2), and Dy (3)) and the trinuclear complex [Cu(II) (valpn)La(III) (OH2 )3 (O2 NO)(μ-NC)Fe(III) (phen)(CN)3 ]⋅NO3 ⋅H2O⋅CH3 CN (4) were obtained …

ChemistryLigandOrganic ChemistryInorganic chemistryGeneral ChemistryCrystal structureCatalysisMagnetizationchemistry.chemical_compoundBipyridineCrystallographyX-ray crystallographyMoleculeIsostructuralAcetonitrileChemistry (Weinheim an der Bergstrasse, Germany)
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Polynuclear copper(II) complexes with hexadentate Schiff base directed by the counter ion. Syntheses, crystal structures and magnetic properties

2018

Abstract Four new complexes, [Cu 9 L 6 ( µ 3 -ClO 4 ) 2 ](ClO 4 ) 4 ·4CHCl 3 1 , [Cu 3 L 2 (H 2 O) 2 ](ClO 4 ) 2 ·3H 2 O 2 , [Cu 6 L 4 (N 3 ) 2 ](ClO 4 ) 2 3 and [Cu 2 L(CH 3 COO) 2 ] 4 , where H 2 L stands for the Schiff base N , N ′-bis[(2-hydroxybenzilideneamino)-propyl]-piperazine, were obtained and structurally characterized. Compounds 1 , 2 and 3 contain the Cu 3 L 2 2+ entities in which L 2− acts in an unsymmetrical mode with N 3 O donor set wrapped around marginal copper(II) and with the remained NO sets bound to the central copper ion. The marginal copper(II) ions are in distorted square pyramidal environment, whereas that of the central one is square planar. In 1 , the peripheral …

Schiff base010405 organic chemistryChemistryLigandStereochemistryMetal ions in aqueous solutionchemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciencesCopperSquare pyramidal molecular geometry0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundPerchlorateMaterials ChemistryMoleculePhysical and Theoretical ChemistryInorganica Chimica Acta
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[Cr(phen)(ox)2]-: a versatile bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of …

2000

The new complexes of formula AsPh4[Cr(phen)(ox)2]·H2O (1), [NaCr(phen)(ox)2(H2O)]·2H2O (2) and {[Cr(phen)(ox)2]2[Mn2(bpy)2(H2O)2(ox)]}·6H2O (3) (AsPh4=tetraphenylarsonium cation; phen=1,10-phenanthroline; ox=oxalate dianion; bpy=2,2′-bipyridine) have been prepared and characterized by single-crystal X-ray diffraction. The structure of 1 consists of discrete [Cr(phen)(ox)2]− anions, tetraphenylarsonium cations and uncoordinated water molecules. The chromium environment in 1 is distorted octahedral with Cr–O bond distances between 1.959(3) and 1.947(3) A and Cr–N bonds of 2.083(4) and 2.072(4) A. The angles subtended at the chromium atom by the two oxalates are 83.6(2) and 83.3(1)° whereas th…

DenticityLigandInorganic chemistrychemistry.chemical_elementGeneral ChemistryCrystal structureManganeseCatalysisOxalatechemistry.chemical_compoundCrystallographyChromiumOctahedronchemistryOctahedral molecular geometryMaterials ChemistryNew Journal of Chemistry
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[Cr(dpa)(ox)2]–: a new bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of PPh4[Cr…

2001

[EN] The new complexes of formulae PPh4[Cr(dpa)(ox)(2)] (1), AsPh4[Cr(dpa)(OX)(2)] (2), Hdpa[Cr(dpa)(ox)(2)]-4H(2)O (3), Rad[Cr(dpa)(ox)(2)] . H2O (4) and Sr[Cr(dpa)(ox)(2)](2) . 8H(2)O (5) [PPh4 = tetraphenylphosphonium cation; AsPh4 = tetraphenylarsoniurn cation; dpa = 2,T-dipyridylamine; ox = oxalate dianion; Rad = 2-(4-N-methylpyridinium)4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-a-oxyl-3-N-oxide] have been prepared and characterised by single-crystal X-ray diffraction. The structures of 1-4 consist of discrete [Cr(dpa)(ox)(2)](-) anions, tetraphenylphosphonium. (1), tetraphenylarsonium (2), monoprotonated Hdpa (3) and univalent radical (4) cations and uncoordinated water molecules (2-…

Metal ions in aqueous solutionInorganic chemistryLinear trichromium complexeschemistry.chemical_elementNitronyl nitroxide radicalsCrystal structureChlorideCatalysisOxalateElectronic-Propertieschemistry.chemical_compoundChromiumMaterials ChemistryMoleculeCr contactsMonohydrateMolecular-StructureChemistryLigandGeneral ChemistryAtoms LiCrystallographyGaussian-Basis setsOctahedronFISICA APLICADACopper(II) complexesChirality (chemistry)New Journal of Chemistry
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Three different types of bridging ligands in a 3d-3d'-3d'' heterotrimetallic chain.

2017

A one-pot synthesis of a 3d–3d′–3d′′ heterotrimetallic coordination polymer with double diphenoxido, single cyanido and bis-bidentate oxalate as alternating bridges which exhibits an overall antiferromagnetic behaviour has been developed.

Inorganic Chemistrychemistry.chemical_compoundCrystallographyBridging (networking)chemistry010405 organic chemistryCoordination polymer010402 general chemistry01 natural sciencesOxalate0104 chemical sciencesDalton transactions (Cambridge, England : 2003)
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[Cr(bpym)(C2O4)2]− in designing heterometallic complexes. Crystal structures and magnetic properties of PPh4[Cr(bpym)(C2O4)2]·H2O and [Ag(bpym)][Cr(C…

2002

Abstract The preparation, crystal structure and magnetic properties of PPh 4 [Cr(bpym)(C 2 O 4 ) 2 ]·H 2 O ( 1 ) and [Ag(bpym)][Cr(C 2 O 4 ) 2 (H 2 O) 2 ]·2H 2 O ( 2 ) (C 2 O 4  2− =oxalate dianion, bpym=2,2′-bipyrimidine and PPh 4  + =tetraphenylphosphonium cation) are described. The structure of 1 is made up of discrete (2,2′-bipyrimidine)bis(oxalato)chromate(III) anions, teraphenylphosphonium cations and uncoordinated water molecules. The structure of 2 consists chains of univalent silver cations bridged by bis-chelating 2,2′-bypyrimidine, cis -diaquabis(oxalato)chromate(III) anions and crystallisation water molecules. The chromium atom in 1 and 2 has a slightly distorted octahedral geom…

DenticityStereochemistryCrystal structureMagnetic susceptibilityOxalateInorganic ChemistryBond lengthchemistry.chemical_compoundCrystallographychemistryOctahedral molecular geometryMaterials ChemistryMoleculeAntiferromagnetismPhysical and Theoretical ChemistryInorganica Chimica Acta
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A new mixed-valence hexanuclear cobalt complex, [Co4IICo2III(dea)2(Hdea)4)(piv)4](ClO4)2·H2O: Synthesis, crystal structure and magnetic properties

2010

A new Co II /Co III hexanuclear complex, [Co 4 II Co 2 III (dea) 2 (Hdea) 4 )(piv) 4 ](ClO 4 ) 2 ·H 2 O 1 , has been obtained by reacting cobalt(II) perchlorate, diethanolamine, and pivalic acid (H 2 dea = diethanolamine and piv = pivalato anion). The cobalt ions are held together by four μ 3 and four μ 2 alkoxo bridges as well as by four syn – syn carboxylato groups. The hexanuclear motif contains four Co(II) and two Co(III) ions. The {Co II 4 Co III 2 (μ 2 -O) 4 (μ 3 -O) 4 } core can be described as a four face-sharing monovacant and bivacant distorted heterocubane units. The cobalt(III) ions are hexacoordinated. Two of the cobalt(II) are hexacoordinated, while the two others are pentacoo…

DiethanolamineValence (chemistry)Pivalic acidchemistry.chemical_elementCrystal structureInorganic ChemistryPerchloratechemistry.chemical_compoundCrystallographyBipyramidchemistryMaterials ChemistrySinglet statePhysical and Theoretical ChemistryCobaltInorganica Chimica Acta
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Synthesis, crystal structure and magnetic properties of [Cu(bipy)2(CH3COO)][Cu(bipy)2(Cr(C2O4)3)]·∼10.5H2O, the first compound containing the [Cr(C2O…

2001

Abstract The reaction between copper(II) acetate with 2,2′-bipyridine and K3[Cr(C2O4)3] leads to the novel salt [Cu(bipy)2(CH3COO)][Cu(bipy)2(Cr(C2O4)3)]·∼10.5H2O, 1 (bipy=2,2′-bipyridine). The crystal structure of 1 consists of mononuclear cationic species [Cu(bipy)2(CH3COO)]+ and heterobinuclear anionic units, [Cu(bipy)2(Cr(C2O4)3)]−. The tris-oxalato-chromium entity behaves as a monodentate ligand toward the copper(II) ion within the complex anion. The distance between Cr(III) and Cu(II) across the bridging oxalato group is 5.056(2) A. The copper(II) ions exhibit a distorted trigonal bipyramidal surrounding in both cationic and anionic species. The π–π stacking interaction between bipy l…

DenticityChemistryInorganic chemistryStackingCationic polymerizationchemistry.chemical_elementCrystal structureMagnetic susceptibilityCopper22'-BipyridineInorganic Chemistrychemistry.chemical_compoundTrigonal bipyramidal molecular geometryCrystallographyMaterials ChemistryPhysical and Theoretical ChemistryInorganica Chimica Acta
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Heteropolymetallic Supramolecular Solid-State Architectures Constructed from [Cr(AA)(C2O4)2]- Tectons, and Sustained by Coordinative, Hydrogen Bond a…

2004

The paper reports on four novel solid-state architectures constructed by using tectons having the general formula:  [Cr(AA)(C2O4)2]- [AA = 2,2‘-bipyridine (bipy) and 1,10-phenanthroline (phen)]. These building blocks are involved in various intermolecular interactions:  coordinative, hydrogen bonds, and π−π contacts. Two new crystallohydrates in the Ba[Cr(AA)(C2O4)2]2·nH2O family have been characterized:  [BaCr2(bipy)2(C2O4)4(H2O)2]·4H2O (1) and [BaCr2(phen)2(C2O4)4(H2O)2] (2). Because of the different numbers of water molecules, their crystal structures are completely different from those of two others previously reported, [BaCr2(bipy)2(C2O4)4(H2O)]·H2O and [BaCr2(phen)2(C2O4)4(H2O)2]·4H2O…

DenticityChemistryHydrogen bondPhenanthrolineStackingSupramolecular chemistryGeneral ChemistryCrystal structureCondensed Matter Physics22'-Bipyridinechemistry.chemical_compoundCrystallographyMoleculeGeneral Materials ScienceCrystal Growth & Design
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A two-dimensional coordination polymer constructed from binuclear copper(II) metalloligands and manganese(II) ions: Synthesis, crystal structure and …

2016

Abstract The self-assembly process between the binuclear [Cu2(HL)(L)]− complex and the manganese(II) ion affords a two-dimensional coordination polymer of formula [Mn{Cu2(HL)(L)}2(H2O)2]n (1) (H3L = 3-hydroxyiminomethylsalicylic acid) where parallel ladder-like motifs of defective double cubanes of bis(phenoxo)dicopper(II) units as rods and anti-syn carboxylato bridges as rungs act as ligands towards tetraaqua-manganese(II) entities through the deprotonated oxime groups. The topology of 1 is compared with the one of another compound, [Mn{Cu2(HL)(L)}2(H2O)4]·4H2O·2DMF (1′) which was obtained in different conditions by Okawa et al. (J. Chem. Soc., Dalton Trans. (2001) 3119). Magnetic suscepti…

010405 organic chemistryStereochemistryCoordination polymerchemistry.chemical_elementCrystal structureManganese010402 general chemistryOxime01 natural sciencesMagnetic susceptibilityCopper0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographyDeprotonationchemistryMaterials ChemistryPhysical and Theoretical ChemistryInorganica Chimica Acta
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Synthesis, crystal structures and magnetic properties of cyanide- and phenolate-bridged [MIIINiII]2tetranuclear complexes (M = Fe and Cr)

2005

The binuclear complex NiII2L(H2O)2(ClO4)2 (1) and the neutral tetranuclear bimetallic compounds [{MIII(phen)(CN)4}2{NiII2L(H2O)2}]·2CH3CN with M = Fe (2) and Cr (3) [H2L = 11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]hexacosa-2,7,9,11,13(26),14,19,21(25),22,24-decaene-25,26-diol] have been synthesized and the structures of 2 and 3 determined by single crystal X-ray diffraction. 2 and 3 are isostructural compounds whose structure is made up of centrosymmetric binuclear cations [Ni2(L)(H2O)2]2+ and two peripheral [M(phen)(CN)4]− anions [M = Fe (2) and Cr (3)] acting as monodentate ligands towards the nickel atoms through one of their four cyanide nitrogen atoms. The environment of t…

Inorganic ChemistryCrystallographyNickelDenticityChemistryIntramolecular forceInorganic chemistryAntiferromagnetismMoleculechemistry.chemical_elementDensity functional theoryCrystal structureIsostructuralDalton Trans.
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Heterometallic CoII-CoIII-MII alkoxido-bridged heptanuclear motifs (M = Cu, Zn). Syntheses, crystal structures and magnetic properties

2018

Two new alkoxido-bridged heterometallic complexes of formula [CoIICoIII 3CuII 3(dea)6(CH3COO)3](ClO4)0.75(CH3COO)1.25 (1) and [CoII 2CoIII 2ZnII 3(tea)2(piv)6(CH3O)2(OH)2(CH3OH)2]·H2O 2 (H2dea=diethanolamine, H3tea=triethanolamine and Hpiv=pivalic acid) have been assembled using aminoalcohol ligands. The cationic core in 1 possesses a threefold crystallographic axis, and it exhibits a set of three copper(II), one cobalt(II) and three cobalt(III) ions arranged as a hexagon of alternating copper(II) and cobalt(III) ions around the central cobalt(II) ion. Each edge of the hexagon is defined by a double alkoxido bridge, the outer one being bis-monodentate with copper(II)-cobalt(III) pair wherea…

Denticity/dk/atira/pure/subjectarea/asjc/2500/2505Inorganic chemistrychemistry.chemical_elementCrystal structureZinc010402 general chemistry01 natural sciencesCobalt complexesIonInorganic ChemistryMagnetic propertiesZinc complexesMaterials ChemistryPhysical and Theoretical Chemistry/dk/atira/pure/subjectarea/asjc/1600/1606/dk/atira/pure/subjectarea/asjc/1600/1604010405 organic chemistryLigandCopper0104 chemical sciencesCrystallographychemistryIntramolecular forceMixed-valence clustersCobaltCopper complexesInorganica Chimica Acta
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[Mn2(bipym)(H2O)8]4+and [Fe(bipy)(CN)4]−as building blocks in designing novel bipym- and cyanide-bridged heterobimetallic complexes (bipym = 2,2′-bip…

2002

Two new cyano complexes, K[Fe(bipy)(CN)4]·H2O (1) and (μ-bipym)[Mn(H2O)3{Fe(bipy)(CN)4}]2[Fe(bipy)(CN)4]2·12H2O (2), have been synthesised and their structures determined by single-crystal X-ray diffraction. Complex 1 is made up of mononuclear [Fe(bipy)(CN)4]− anions, potassium cations and water molecules of crystallization. The iron(III) is six-coordinated, being surrounded by two nitrogen atoms of a chelating bipy and four carbon atoms of four cyanide groups [Fe–N and Fe–C 1.991(3)–1.990(3) and 1.958(5)–1.914(5) A, respectively]. Complex 2 consists of centrosymmetric tetranuclear (μ-bipym)[Fe(H2O)3{Fe(bipy)(CN)4}]22+ cations, [Fe(bipy)(CN)4]− anions and water molecules of crystallization.…

DenticityLigandCyanideInorganic chemistrychemistry.chemical_elementGeneral ChemistryManganese22'-BipyridineBond lengthCrystallographychemistry.chemical_compoundchemistryOctahedronMoleculeJ. Chem. Soc., Dalton Trans.
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Bis(oxalato)chromium(III) complexes: Versatile tectons in designing heterometallic coordination compounds

2011

Abstract The mononuclear oxalato-containing chromium(III) complexes of general formula [Cr(AA)(C2O4)2]− (AA = α-diimine type ligand) are able to produce a large variety of heterometallic complexes by acting as ligands towards either fully solvated metal ions or preformed cationic complexes with available coordination sites. This review focuses on the structural diversity of the polynuclear complexes (oligonuclear and coordination polymers) which are generated by the bis(oxalato)chromate(III) species, with a special emphasis to their magnetic properties.

chemistry.chemical_classificationChromate conversion coatingbiologyChemistryStereochemistryLigandMetal ions in aqueous solutionCationic polymerizationStructural diversitychemistry.chemical_elementASPHCoordination complexInorganic ChemistryChromiumPolymer chemistryMaterials Chemistrybiology.proteinPhysical and Theoretical ChemistryCoordination Chemistry Reviews
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New cyanide-bridged Mn(III)-M(III) heterometallic dinuclear complexes constructed from [M(III)(AA)(CN)4]- building blocks (M = Cr and Fe): synthesis,…

2011

Three Mn(III)-M(III) (M = Cr and Fe) dinuclear complexes have been obtained by assembling [Mn(III)(SB)(H(2)O)](+) and [M(III)(AA)(CN)(4)](-) ions, where SB is the dianion of the Schiff-base resulting from the condensation of 3-methoxysalicylaldehyde with ethylenediamine (3-MeOsalen(2-)) or 1,2-cyclohexanediamine (3-MeOsalcyen(2-)): [Mn(3-MeOsalen)(H(2)O)(µ-NC)Cr(bipy)(CN)(3)]·2H(2)O (1), [Mn(3-MeOsalen)(H(2)O)(µ-NC)Cr(ampy)(CN)(3)][Mn(3-MeOsalen)(H(2)O)(2)]ClO(4)·2H(2)O (2) and [Mn(3-MeOsalcyen)(H(2)O)(µ-NC)Fe(bpym)(CN)(3)]·3H(2)O (3) (bipy = 2,2'-bipyridine, ampy = 2-aminomethylpyridine and bpym = 2,2'-bipyrimidine). The [M(AA)(CN)(4)](-) unit in 1-3 acts as a monodentate ligand towards th…

DenticityChemistryHydrogen bondStereochemistryCyanidechemistry.chemical_elementEthylenediamineCrystal structureManganeseInorganic Chemistrychemistry.chemical_compoundCrystallographyOctahedronMoleculeDalton transactions (Cambridge, England : 2003)
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Two-Dimensional Coordination Polymers Constructed by [NiIILnIII] Nodes and [WIV(bpy)(CN)6]2– Spacers: A Network of [NiIIDyIII] Single Molecule Magnets

2013

Three isomorphous two-dimensional (2D) coordination polymers of general formula {[Ni(II)(valpn)Ln(III)(NO3)(H2O)(μ-NC)4W(IV)(bipy)(CN)2]·xH2O·yCH3CN}n have been synthesized by reacting Ph4P[W(V)(CN)6(bipy)] with the heterodinuclear [Ni(II)Ln(III)(valpn)(O2NO)3] complexes [H2valpn = 1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol), bipy = 2,2'-bipyridine, and Ln = Gd (1), Dy (2), and Tb (3) with x = 2 (1), 3.9 (2), and 3.35 (3) and y = 2.50 (1), 2 (2), and 1.8 (3)]. Their crystal structures consist of [Ni(II)Ln(III)] 3d-4f nodes which are connected by [W(IV)(bipy)(CN)6](2-) diamagnetic linkers resulting from the reduction of W(V) to W(IV) during the reaction process. The Ni(II) and Ln(I…

Inorganic Chemistrychemistry.chemical_classificationCrystallographyOxygen atomChemistryLigandStereochemistryMoleculePolymerCrystal structurePhysical and Theoretical ChemistryIonInorganic Chemistry
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Synthesis, crystal structure and magnetic properties of a new [ZnII6DyIII6] dodecanuclear motif

2013

Abstract A new dodecanuclear complex, [{(HL)(L)(dmf)ZnIIDyIII(dmf)(H2O)}6]·3dmf·4.2H2O has been assembled using a supramolecular compartmental ligand (H3L results from the condensation reaction of 3-formylsalicylic acid and hydroxylamine). The six DyIII ions describe an octahedron that is inscribed into the octahedron generated by the zinc(II) ions each DyIII ion from this motif behaving as a single ion magnet.

ChemistryStereochemistryLigandSupramolecular chemistrychemistry.chemical_elementCrystal structureZincCondensation reactionIonInorganic Chemistrychemistry.chemical_compoundCrystallographyHydroxylamineOctahedronMaterials ChemistryPhysical and Theoretical ChemistryPolyhedron
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An original 1D Cu–Co heterometallic compound: synthesis, structure and magnetic properties

2006

A novel heterobimetallic system, 1∞[LCuIICoII(NCS)2] (1), was obtained by reacting the neutral mononuclear complex [LCu] with cobalt(II) acetate in the presence of potassium thiocyanate (L is the dianion of the Schiff base resulting from the 2 ∶ 1 condensation of 3-methoxysalicylaldehyde with 1,3-propanediamine). The crystallographic investigation of 1 reveals a one-dimensional alternating zig-zag chain-like structure, made of dinuclear {LCuCo} units linked by thiocyanate bridges. The copper(II) ion is pentacoordinate to the N2O2 donor set of the Schiff base ligand in the basal plane, with the apical position occupied by the sulfur atom. The cobalt ion displays a strongly distorted (4 + 2) …

Schiff baseThiocyanateChemistryLigandExchange interactionInorganic chemistrychemistry.chemical_elementGeneral ChemistryCatalysischemistry.chemical_compoundCrystallographyPotassium thiocyanateOctahedral molecular geometryMaterials ChemistryAntiferromagnetismCobaltNew Journal of Chemistry
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Chromium(III) complexes with 2-(2′-pyridyl)imidazole: Synthesis, crystal structure and magnetic properties

2011

Abstract The preparation, crystal structure and variable temperature-magnetic investigation of three 2-(2′-pyridyl)imidazole-containing chromium(III) complexes of formula PPh4[Cr(pyim)(C2O4)2]·H2O (1), AsPh4[Cr(pyim)(C2O4)2]·H2O (2) and [Cr2(pyim)2(C2O4)2(OH2)2]·2pyim · 6H2O (3) [pyim = 2-(2′-pyridyl)imidazole, C 2 O 4 2 - = dianion of oxalic acid , PPh 4 + = tetraphenylphosphonium cation and AsPh 4 + = tetraphenylarsonium cation ] are reported herein. The isomorphous compounds are made up of discrete [Cr(pyim)(C2O4)2]− anions, XPh 4 + cations [X = P (1) and As (2)] and uncoordinated water molecules. The chromium environment in 1 and 2 is distorted octahedral with Cr–N and Cr–O bond distanc…

Hydrogen bondStereochemistrychemistry.chemical_elementCrystal structureMagnetic susceptibilityOxalateInorganic Chemistrychemistry.chemical_compoundChromiumCrystallographychemistryIntramolecular forceMaterials ChemistryImidazoleMoleculePhysical and Theoretical ChemistryInorganica Chimica Acta
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A novel octacyanido dicobalt(iii) building block for the construction of heterometallic compounds

2019

The first bimetallic octacyanido complex of CoIII, (PPh4)2[Co2(μ-2,5-dpp)(CN)8] (1), was synthesized and used as a metalloligand with [Mn(MAC)(H2O)2]Cl2·4H2O to give a new {CoIIIMnII} heterometallic chain of formula [MnII(MAC)(μ-NC)2Co2III(μ-2,5-dpp)(CN)6]n·7nH2O (2) (PPh4+ = tetraphenylphosphonium cation; 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene). Both compounds were characterized by single-crystal X-ray diffraction. Compound 1 contains a diamagnetic 2,5-dpp-bridged dicobalt(III) unit with four peripheral cyanide ligands at each cobalt center achieving a six-coordinate surrounding, the electroneutral…

PyrazineCyanidechemistry.chemical_element02 engineering and technologyGeneral ChemistryManganeseAtmospheric temperature range010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCatalysis0104 chemical sciencesIonCrystallographychemistry.chemical_compoundPentagonal bipyramidal molecular geometrychemistryMaterials Chemistry0210 nano-technologyCobaltBimetallic stripNew Journal of Chemistry
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Mononuclear Fe(III) and tetranuclear [Fe(III)Gd(III)]2 complexes with a Schiff-base ligand derived from the o-vanillin: Synthesis, crystal structures…

2011

The mononuclear high-spin iron(III) complexes [Fe(3-MeOsalpn)Cl(H 2 O)] ( 1 ) and [Fe(3-MeOsalpn)(NCS)(H 2 O)]·0.5CH 3 CN ( 2 ) and the tetranuclear oxo-bridged compound [{Fe(3-MeOsalpn)Gd(NO 3 ) 3 } 2 (μ-O)]·CH 3 CN ( 3 ) [3-MeOsalpn 2−  =  N , N ′-propylenebis(3-methoxysalicylideneiminate)] have been prepared and magneto-structurally characterised. The iron(III) ion in 1 and 2 is six-coordinated in a somewhat distorted octahedral surrounding with the two phenolate-oxygens and two imine-nitrogens from the Schiff-base building the equatorial plane and a water ( 1 and 2 ) and a chloro ( 1 )/thiocyanate-nitrogen ( 2 ) in the axial positions. The neutral mononuclear units of 1 and 2 are assemb…

Schiff baseHydrogen bondSupramolecular chemistryCrystal structureInorganic Chemistrychemistry.chemical_compoundCrystallographyOctahedronchemistryIntramolecular forceMaterials ChemistryMoleculeAntiferromagnetismPhysical and Theoretical ChemistryPolyhedron
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Aggregation of [Ln(12)(III)] clusters by the dianion of 3-formylsalicylic acid. Synthesis, crystal structures, magnetic and luminescence properties

2019

Three isostrucutral dodecanuclear clusters with the general formula [Ln(12)(fsa)(12)(mu f(3)-OH)(12)(DMF)(12)]center dot nDMF (fsa(2-) is the dianion of 3-formylsalicylic acid; Ln = Eu 1, Gd 2, Dy 3) have been obtained from the reaction of fromylsalicyclic acid (H(2)fsa), tetrabutylammonium hydroxide and Ln(NO3)(3)center dot 6H(2)O in methanol/DMF. Their structure consists of four vertex-sharing heterocubanes. Each heterocubane unit is assembled from four Ln(III) ions, three mu(3)-OH groups and one mu(3)-oxygen atom arising from the fsa(2-) carboxylato group. The photophysical properties of the europium derivative investigated at both 300 and 80 K sustain a relative intense emission obtaine…

---Materials science010405 organic chemistryTetrabutylammonium hydroxidechemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryAtomDysprosiumMagnetic refrigerationEuropiumLuminescence
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Magnetism in Heterobimetallic and Heterotrimetallic Chains Based on the Use of [W V (bipy)(CN) 6 ] – as a Metalloligand

2018

Inorganic ChemistryCrystallography010405 organic chemistryChemistryMagnetismSelf-assembly010402 general chemistry01 natural sciences0104 chemical sciencesEuropean Journal of Inorganic Chemistry
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New alkoxo-bridged mixed-valence cobalt clusters: Synthesis, crystal structures and magnetic properties

2008

Two new Co II /Co III complexes, [{Co II Co III (mea) 3 } 2 (bpe) 3 ](ClO 4 ) 4  · 1.5CH 3 OH · 1.5H 2 O ( 1 ) and [ Co 4 II Co 3 III ( dea ) 6 ( CH 3 COO ) 3 ] ( ClO 4 ) 0.75 ( CH 3 COO ) 1.25 · 0.5 H 2 O ( 2 ) [Hmea = monoethanolamine H 2 dea = diethanolamine and bpe = 1,2-bis(4-pyridyl)ethane], have been obtained by reacting cobalt(II) perchlorate ( 1 and 2 ), Hmea ( 1 )/H 2 dea ( 2 ), bpe ( 1 ) and sodium acetate ( 2 ). The crystal structures of 1 and 2 have been solved by single crystal X-ray diffraction. Crystal 1 contains “Chinese lantern”-like shaped cations, resulting by connecting two {Co II Co III (mea) 3 } moieties with three flexible bpe ligands. The coordination sphere of the …

Valence (chemistry)Coordination sphereInorganic chemistrychemistry.chemical_elementCrystal structureInorganic ChemistryPerchloratechemistry.chemical_compoundCrystallographychemistryIntramolecular forceMaterials ChemistryAntiferromagnetismPhysical and Theoretical ChemistrySingle crystalCobaltInorganica Chimica Acta
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Magnetic Molecular Rectangles Constructed from Functionalized Nitronyl‐Nitroxide Ligands and Lanthanide(III) Ions

2020

Inorganic ChemistryLanthanideNitroxide mediated radical polymerizationChemistryPolymer chemistryIonEuropean Journal of Inorganic Chemistry
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A new ferromagnetically coupled μ-alkoxo–μ-acetato copper(II) trinuclear complex: [Cu3(H2tea)(Htea)(CH3COO)2](ClO4) (H3tea=triethanolamine)

2005

Abstract A μ-alkoxo–μ-acetato trinuclear copper(II) complex, [Cu3(H2tea)(Htea)(CH3COO)2](ClO4) 1, has been synthesized by reacting copper(II) perchlorate, triethanolamine and sodium acetate. The unit cell contains two centrosymmetric, crystallographically independent trinuclear Cu(II) complexes and two ClO 4 - ions. The crystallographically independent trinuclear Cu(II) complexes differ mainly in some of their geometry parameters. The coordination environment of the central copper atom is square-planar, in one trinuclear entity, and elongated octahedral in the other one (in this last case, the coordination number of the central copper atom increases through the semicoordination of an oxygen…

Coordination numberInorganic chemistrychemistry.chemical_elementCrystal structureCopperIonInorganic ChemistryCrystallographyPerchloratechemistry.chemical_compoundFerromagnetismchemistryOctahedronTriethanolamineMaterials ChemistrymedicinePhysical and Theoretical Chemistrymedicine.drugInorganica Chimica Acta
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An original 3D coordination polymer constructed from trinuclear nodes and tetracarboxylato spacers

2021

A novel 3D coordination polymer, ∞3[{Cu3(felden)}4(btec)3]·17H2O, has been assembled using cationic trigonal nodes, [CuII3(felden)]3+, generated by a tricompartmental ligand, H3felden, which results from the Schiff condensation reaction between 2,4,6-triformylphloroglucinol and N,N-dimethylethylenediamine. The tetraanion of the 1,2,4,5-benzenetetracaboxylic acid (H4btec) was employed as a spacer. The structure of 1 shows large icosahedral cavities and channels and the magnetic interaction between the copper(II) ions within the triangles is weak and antiferromagnetic.

Materials scienceLigandCoordination polymerIcosahedral symmetryCationic polymerizationchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsCondensation reactionCopperIonCrystallographychemistry.chemical_compoundchemistryAntiferromagnetismGeneral Materials ScienceCrystEngComm
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Synthesis, Crystal Structures, and Magnetic Properties of Two Novel Cyanido-Bridged Heterotrimetallic {CuIIMnIICrIII} Complexes

2017

The self-assembly process between the heteroleptic [CrIII(phen)(CN)4]− and [CrIII(ampy)(CN)4]− metalloligands and the heterobimetallic {CuII(valpn)MnII}2+ tecton afforded two heterotrimetallic complexes of formula [{CuII(valpn)MnII(μ-NC)2CrIII(phen)(CN)2}2{(μ-NC)CrIII(phen)(CN)3}2]·2CH3CN (1) and {[CuII(valpn)MnII(μ-NC)2CrIII(ampy)(CN)2]2·2CH3CN}n (2) [phen = 1,10-phenanthroline, ampy = 2-aminomethylpyridine, and H2valpn = 1,3-propanedyilbis(2-iminomethylene-6-methoxyphenol)]. The crystal structure of 1 consists of neutral CuII2MnII2CrIII4 octanuclear units, where two [Cr(phen)(CN)4]− anions act as bis-monodentate ligands through cyanide groups toward two manganese(II) ions from two [CuII(v…

010405 organic chemistryStereochemistryCoordination polymerCyanidechemistry.chemical_elementCrystal structureManganese010402 general chemistry01 natural sciencesCopper0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryPhysical and Theoretical ChemistryInorganic Chemistry
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Ferromagnetic coupling through spin polarization in the hexanuclear [MnII(3)CuII(3)] complex.

2004

A novel Cu(II)-Mn(II) hexanuclear complex of formula [[MnCuL](3)(tma)](ClO(4))(3).8H(2)O [H(2)L = macrocyclic Robson proligand; H(3)tma = trimesic acid] has been obtained by connecting three heterobinuclear [Cu(II)Mn(II)L](2+) cationic species through the trimesate anion. The complex exhibits a C(3) rotational symmetry, imposed by the geometry of the bridging ligand. The interaction within each Mn(II)-Cu(II) pair is antiferromagnetic (J = -16.7 cm(-1)). A weak ferromagnetic coupling among the three S = 2 resulting spins through the tricarboxylato bridge leads to a S = 6 ground spin state, for which the spin polarization mechanism is responsible.

Inorganic ChemistryCrystallographychemistry.chemical_compoundCoupling (physics)Spin polarizationFerromagnetismCondensed matter physicsChemistryTrimesic acidPhysical and Theoretical ChemistryInorganic chemistry
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Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d-4f clusters.

2015

Two types of oxalato-bridged heterometallic 3d–4f dodeca- and hexanuclear compounds have been obtained by connecting six bi- and, respectively, trinuclear moieties through oxalato bridges arising from the slow decomposition of the L-ascorbic acid.

Inorganic Chemistrychemistry.chemical_compoundchemistrySimple (abstract algebra)Inorganic chemistryAscorbic acidDecompositionOxalateIonDalton transactions (Cambridge, England : 2003)
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C3-symmetric trinuclear copper(ii) species as tectons in crystal engineering

2013

Three new complexes have been obtained using C3-symmetric trinuclear complexes as tectons; [Cu3(felden)(NCS)3(dmf)3] (1), [Cu3(felden)(mand)3]·(C2H5)2O (2), and [Cu3(felden)(dca)3(C2H5OH)]·2H2O (3) (H3felden is the Schiff base resulting from the condensation of 2,4,6-triformylphloroglucinol with N,N-dimethylethylenediamine, mand− is the anion of the R-mandelic acid and dca− is the dicyanamide anion). Compounds 1 and 2 are discrete trinuclear species, while compound 3 is a 2D coordination polymer, constructed from trinuclear nodes and dicyanamido spacers. The variable-temperature magnetic properties of 1–3 have been investigated and they reveal the occurrence of weak antiferromagnetic intera…

Schiff baseStereochemistryCoordination polymerchemistry.chemical_elementGeneral ChemistryChromophoreCondensed Matter PhysicsCrystal engineeringCopperchemistry.chemical_compoundCrystallographychemistryIntramolecular forceAntiferromagnetismGeneral Materials ScienceDicyanamideCrystEngComm
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Intramolecular versus intermolecular exchange pathways in the binuclear complex [Cu2(H2tea)2(4,4′-bipy)](ClO4)2·3H2O (H3tea=triethanolamine and 4,4′-…

2001

Abstract The binuclear copper(II) complex of formula [Cu2(H2tea)2(4,4′-bipy)](ClO4)2·3H2O (1) (H3tea=triethanolamine and 4,4′-bipy=4,4′-bipyridine) has been isolated and characterized by X-ray diffraction. Its structure consists of dinuclear [Cu2(H2tea)2(4,4′-bipy)]2+ cations, uncoordinated perchlorate anions and crystallization water molecules. Each copper atom exhibits a trigonal-bipyramidal environment with the three triethanolamine-oxygen atoms building the equatorial plane, and the triethanolamine-nitrogen and one of the 4,4′-bipy nitrogen atoms defining the three-fold axis. The 4,4′-bipy molecule acts as a bismonodentate bridging ligand, the copper–copper separation across it being 11…

StereochemistryIntermolecular forceBridging ligandCrystal structure44'-BipyridineInorganic ChemistryPerchloratechemistry.chemical_compoundCrystallographychemistryTriethanolamineIntramolecular forceMaterials ChemistrymedicineMoleculePhysical and Theoretical Chemistrymedicine.drugPolyhedron
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A new chiral dimanganese(iii) complex: synthesis, crystal structure, spectroscopic, magnetic, and catalytic properties

2016

Two enantiomeric complexes of formula [MnIII2(μ-OCH3)2(R-valBINAM)2]·1.75DMF (1) and [MnIII2(μ-OCH3)2(S-valBINAM)2]·2DMF (2) [valBINAM = 1,1′-binaphthalene-2,2′-bis(3-methoxysalicylideneiminate)] have been synthesized using as a ligand the chiral Schiff bases resulting from the condensation reactions between o-vanillin and the chiral 1,1′-binaphthyl-2,2′-diamine. The structures of 1 and 2 which have been solved by single crystal X-ray diffraction consist of neutral dimers, the manganese(III) ions being bridged by two methoxido anions, arising from the solvent, and by two valBINAM2− ligands. Their circular dichroism spectra at room temperature emphasize the occurrence of the exciton coupling…

010405 organic chemistryLigandGeneral Chemical EngineeringInorganic chemistrychemistry.chemical_elementGeneral ChemistryManganeseCrystal structure010402 general chemistryCondensation reaction01 natural sciences0104 chemical sciencesCatalysisSolventCrystallographychemistryEnantiomerSingle crystalRSC Advances
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New complexes of Ni(II) and Co(III) with a Schiff-base ligand derived from o -vanillin. Crystal structure, magnetic and catalytic properties of a dis…

2018

Abstract A binuclear complex, [Ni2L2(NO3)(H2O)(CH3CN)]ClO4·CH3CN (1), has been obtained using a Schiff-base ligand (HL) derived from o-vanillin and 4-(2-aminoethyl)morpholine. The crystal structure of 1 has been solved. Both Ni(II) ions are hexacoordinated, but they display different coordination spheres. The exchange interaction between the two nickel ions is antiferromagnetic (J = −7.9 ± 0.2 cm−1; H = −JS1S2), in line with the DFT calculations. Compound 1 has been tested as a catalyst in the epoxidation of various olefins. The reaction of the same ligand with a mixture of cobalt(II) perchlorate and nitrate affords a mononuclear Co(III) complex, [CoL2(H2O)]ClO4·CH3OH (2).

Schiff base010405 organic chemistryLigandchemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesCatalysisInorganic ChemistryPerchloratechemistry.chemical_compoundNickelCrystallographychemistryMorpholineMaterials ChemistryPhysical and Theoretical ChemistryCobaltPolyhedron
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Homo- and heterometallic complexes constructed from hexafluoroacetylacetonato and Schiff-base complexes as building-blocks

2018

Three new homo- and heterotrimetallic complexes have been synthesized and crystallographically characterized: [Cu2(saldmpn)2(μ-OCH3)2Cu2(hfac)2] (1), [Ni2(valaepy)2(hfac)2] (2), [Cu(saldmpn)Co(hfac)2] (3) [H2saldmpn is the Schiff-base resulting from condensation of salicylaldehyde with 2,2-dimethyl-1,3-diaminopropane and Hvalaepy results from the reaction of o-vanillin with 2-(2-aminoethyl)pyridine)]. The structure of 1 consists of a neutral tetranuclear species that can be viewed as resulting from mutual coordination of one {(hfac)Cu(μ-OCH3)2(Cu(hfac)} and two {Cu(saldmpn)} building blocks. Compound 2 is a binuclear complex that results from two {Ni(hfac)(valaepy} fragments, the nickel(II)…

Schiff base010405 organic chemistryCondensationchemistry.chemical_element010402 general chemistry01 natural sciences0104 chemical sciencesIonCrystallographychemistry.chemical_compoundNickelchemistryFerromagnetismSalicylaldehydePyridineMaterials ChemistryPhysical and Theoretical ChemistryCobaltJournal of Coordination Chemistry
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Two-Dimensional Coordination Polymers Constructed Using, Simultaneously, Linear and Angular Spacers and Cobalt(II) Nodes. New Examples of Networks of…

2014

Two novel bidimensional coordination polymers, [Co(azbbpy)(4,4'-bipy)0.5(DMF)(NCS)2]·MeOH (1) and [Co(azbbpy)(bpe)0.5(DMF)(NCS)2]·0.25H2O (2), resulted from the assembling of cobalt(II) ions by 1,3-bis(4-pyridyl)azulene, using either 4,4'-bipyridyl or 1,2-bis(4-pyridyl)ethylene as neutral spacers. The cobalt(II) nodes in 1 and 2 act as single-ion magnets (SIMs).

chemistry.chemical_classificationEthyleneSingle ionchemistry.chemical_elementPolymerAzuleneIonInorganic Chemistrychemistry.chemical_compoundchemistryMagnetOrganic chemistryPhysical chemistryPhysical and Theoretical ChemistryCobaltInorganic Chemistry
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[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes

2012

The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.

Inorganic ChemistryCrystallographyChemistryPhysical and Theoretical ChemistryInorganic Chemistry
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[Cr(AA)(C2O4)2]− and [Cu(bpca)]+ as building blocks in designing new oxalato-bridged CrIIICuII compounds [AA=2,2′-bipyridine and 1,10-phenanthroline…

2003

Abstract The monouclear complex PPh4[Cr(bipy)(ox)2]·H2O (1) and the heterodinuclear compounds [Cu(bpca)(H2O)Cr(bipy)(ox)2]·2.5H2O (2) and [Cu(bpca)(H2O)Cr(phen)(ox)2]·2H2O (3) [PPh4+=tetraphenylphosphonium cation, bpca=bis(2-pyridylcarbonyl)amide anion, ox=oxalate dianion, bipy=2,2′-bipyridine and phen=1,10-phenanthroline] have been synthesized and characterized by single-crystal X-ray diffraction. Discrete [Cr(bipy)(ox)2]− mononuclear anions and tetraphenylphosphonium cations are present in 1 whereas the structures of 2 and 3 are made up neutral oxalato-bridged bimetallic CrIIICuII units. The chromium environment is distorted octahedral in the three complexes: two nitrogen atoms from a bi…

DenticityStereochemistryLigandPhenanthrolineCrystal structure22'-BipyridineOxalateInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryOctahedronAmideMaterials ChemistryPhysical and Theoretical ChemistryInorganica Chimica Acta
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One-dimensional coordination polymers constructed from di- and trinuclear {3d–4f} tectons. A new useful spacer in crystal engineering: 1,3-bis(4-pyri…

2014

Four new heterometallic 3d–4f complexes have been obtained using bi- and trinuclear building blocks: 1∞[Ni(L1)Gd(NO3)3(azbbpy)]·CH3CN (1), [Zn(L1)Eu(NO3)3(azbbpy)]·H2O (2), 1∞[(CuL2)2Gd(NO3)2(dca)] 3 and 1∞[(NiL2)2Dy(H2O)4(oxy-bbz)]NO3·3H2O (4), [H2L1 = 1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol), H2L2 = 2,6-di(acetoacetyl)pyridine, azbbpy = 1,3-bis(4-pyridyl)azulene, dca− = dicyanamide anion, and oxy-bbz = the dianion of the 4,4′-oxy-bis(benzoic) acid]. 1 and 2 represent the first complexes containing 1,3-bis(4-pyridyl)azulene as a ligand. 1, 3, and 4 are one-dimensional coordination polymers constructed from heterometallic nodes connected by the exo-dentate ligands. Helical chai…

chemistry.chemical_classificationLigandStereochemistryStackingSupramolecular chemistryGeneral ChemistryPolymerAzuleneCondensed Matter PhysicsCrystal engineeringchemistry.chemical_compoundCrystallographychemistryPyridineGeneral Materials ScienceDicyanamideCrystEngComm
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Trinuclear Nickel(II) and Cobalt(II) Complexes Constructed from Mannich–Schiff‐Base Ligands: Synthesis, Crystal Structures, and Magnetic Properties

2019

Inorganic Chemistrychemistry.chemical_compoundNickelSchiff basechemistryPolymer chemistrychemistry.chemical_elementCrystal structureCobaltEuropean Journal of Inorganic Chemistry
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CCDC 995944: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallographyCrystal System(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-bis(mu-cyano)-bis(110-phenanthroline)-tetra-aqua-hexacyano-copper-di-iron-terbium nitrate heptahydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 995946: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallography(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-nitrato-tetra-aqua-copper-lanthanum (110-phenanthroline)-tetracyano-iron nitrate acetonitrile solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825561: Experimental Crystal Structure Determination

2019

Related Article: Alina S. Dinca, Alexei Mindru, Diana Dragancea, Carmen Tiseanu, Sergiu Shova, Samuele Cornia, Luca M. Carrella, Eva Rentschler, Marco Affronte, Marius Andruh|2019|Dalton Trans.|48|1700|doi:10.1039/C8DT04602F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdodecakis(mu-3-formyl-2-oxidobenzoato)-dodecakis(mu-hydroxo)-dodecakis(NN-dimethylformamide)-dodeca-gadolinium(iii) NN-dimethylformamide solvateExperimental 3D Coordinates
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CCDC 2044705: Experimental Crystal Structure Determination

2021

Related Article: Sergiu Calancea, Luca Carrella, Teodora Mocanu, Vladimir Sadohin, Mihai Raduca, Iacob Gutu, Julio C. Rocha, Maria G. F. Vaz, Eva Rentschler, Marius Andruh|2021|Eur.J.Inorg.Chem.|2021|567|doi:10.1002/ejic.202000954

bis(mu-4455-tetramethyl-3-oxo-2-(5-phenyl-1H-pyrazol-4-yl)-45-dihydro-1H-3-imidazol-1-oxyl)-hexakis(111555-hexafluoroacetylacetonato)-di-gadolinium(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1520091: Experimental Crystal Structure Determination

2017

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-hexakis(mu-cyano)-tetrakis(110-phenanthroline)-decacyano-diaqua-di-copper(ii)-tetra-chromium(iii)-di-manganese(ii) acetonitrile solvateExperimental 3D Coordinates
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CCDC 995943: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallographyCrystal SystemCrystal Structure(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-bis(mu-cyano)-bis(110-phenanthroline)-tetra-aqua-hexacyano-copper-di-iron-gadolinium nitrate heptahydrateCell ParametersExperimental 3D Coordinates
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CCDC 1482464: Experimental Crystal Structure Determination

2016

Related Article: Alina S. Dinca, Natalia Candu, Sergiu Shova, Francesc Lloret, Miguel Julve, Vasile I. Parvulescu, Marius Andruh|2016|RSC Advances|6|86569|doi:10.1039/C6RA18989J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-(S)-(2-(((2'-((2-oxy-3-methoxybenzylidene)amino)-11'-binaphthalen-2-yl)imino)methyl)-6-methoxyphenolato))-bis(mu-methoxo)-di-manganese(iii) NN-dimethylformamide solvateExperimental 3D Coordinates
researchProduct

CCDC 1520092: Experimental Crystal Structure Determination

2017

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966

Space GroupCrystallographycatena-((mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-tris(mu-cyano)-pentacyano-bis(1-(pyridin-2-yl)methanamine)-copper(ii)-di-chromium(iii)-manganese(ii) acetonitrile solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1049500: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

hexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-europium-hexa-zinc dimethylformamide solvate hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1049932: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

Space GroupCrystallographyhexakis(mu2-Acetato)-hexakis(mu2-oxalato)-hexakis(mu2-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexa-dysprosium-hexa-zinc methanol solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 995947: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(mu-cyano)-(110-phenanthroline)-dinitrato-aqua-cyano-iron-nickel-gadolinium acetonitrile solvate monohydrate]Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957553: Experimental Crystal Structure Determination

2019

Related Article: Mihaela I. Mocanu, Andrei A. Patrascu, Mihaela Hillebrand, Sergiu Shova, Francesc Lloret, Miguel Julve, and Marius Andruh|2019|Eur.J.Inorg.Chem.|2019|4773|doi:10.1002/ejic.201901076

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-azido)-dinitrato-tri-nickelExperimental 3D Coordinates
researchProduct

CCDC 2044634: Experimental Crystal Structure Determination

2020

Related Article: Alina S. Dinca, Andreea Dogaru, Adrian E. Ion, Simona Nica, Dan Dumitrescu, Sergiu Shova, Francesc Lloret, Miguel Julve, Marius Andruh|2021|CrystEngComm|23|1332|doi:10.1039/D0CE01667E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu-246-tris({[2-(dimethylamino)ethyl]imino}methyl)benzene-135-triolato)-tris(mu-benzene-1245-tetracarboxylato)-dodeca-copper(ii) unknown solvate]Experimental 3D Coordinates
researchProduct

CCDC 1550041: Experimental Crystal Structure Determination

2017

Related Article: Eliza Martin, Violeta Tudor, Augustin M. Madalan, Catalin Maxim, Floriana Tuna, Francesc Lloret, Miguel Julve, Marius Andruh|2017|Inorg.Chim.Acta|475|98|doi:10.1016/j.ica.2017.05.077

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-tris(2-oxyethyl)amine)-bis(mu-hydroxo)-bis(mu-methoxo)-tetrakis(mu-pivalato)-bis(methanol)-bis(pivalato)-di-cobalt(ii)-di-cobalt(iii)-tri-zinc(ii)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1049499: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

Space GroupCrystallographyhexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-copper-hexa-dysprosium pentahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957556: Experimental Crystal Structure Determination

2019

Related Article: Mihaela I. Mocanu, Andrei A. Patrascu, Mihaela Hillebrand, Sergiu Shova, Francesc Lloret, Miguel Julve, and Marius Andruh|2019|Eur.J.Inorg.Chem.|2019|4773|doi:10.1002/ejic.201901076

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-nitrato)-dinitrato-tri-cobalt acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1049501: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu3-11'-Pyridine-26-diylbis(3-oxobut-1-en-1-olato))-(mu2-oxalato)-octa-aqua-bis(oxalato)-tetra-nickel-di-gadolinium docosahydrateExperimental 3D Coordinates
researchProduct

CCDC 995948: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

catena-[(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(cyano)-(110-phenanthroline)-dinitrato-aqua-cyano-iron-nickel-terbium acetonitrile solvate monohydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1049546: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexakis(ethanol)-hexa-dysprosium-hexa-nickel acetonitrile solvate hydrateExperimental 3D Coordinates
researchProduct

CCDC 940301: Experimental Crystal Structure Determination

2013

Related Article: Alina S. Dinca, Julia Vallejo, Sergiu Shova, Francesc Lloret, Miguel Julve and Marius Andruh|2013|Polyhedron|65|238|doi:10.1016/j.poly.2013.08.049

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu~3~-3-[(Hydroxyimino)methyl]-2-oxidobenzoate)-hexakis(mu~3~-2-oxido-3-[(oxidoimino)methyl]benzoate)-dodecakis(NN-dimethylformamide)-(hexaaqua)-hexa-dysprosium-hexa-zinc NN-dimethylformamide solvate hydrateExperimental 3D Coordinates
researchProduct

CCDC 1892383: Experimental Crystal Structure Determination

2019

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bis(tetraphenylphosphonium) [mu-25-bis(pyridin-2-yl)pyrazine]-octacyano-di-cobalt dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 995949: Experimental Crystal Structure Determination

2015

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catena-[(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(mu-cyano)-(22'-bipyridine)-dinitrato-aqua-cyano-iron-nickel-dysprosium acetonitrile monohydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1558560: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-22'-{piperazine-14-diylbis[(propane-31-diyl)azanylylidenemethylylidene]}diphenolato)-bis(mu-perchlorato)-nona-copper(ii) tetrakis(perchlorate) chloroform solvate]Cell ParametersExperimental 3D Coordinates
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CCDC 953096: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-(22'-bipyridine)-aqua-(nitrato)-bis(cyano)-nickel-terbium-tungsten acetonitrile solvate hydrate]Cell ParametersExperimental 3D Coordinates
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CCDC 1574907: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-tetracyano-bis(2-(1H-imidazol-2-yl)pyridine)-(22'-bipyridine)-manganese(ii)-tungsten(v) (22'-bipyridine)-hexacyano-tungsten(v)]Experimental 3D Coordinates
researchProduct

CCDC 1825562: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systemdodecakis(mu-3-formyl-2-oxidobenzoato)-dodecakis(mu-hydroxo)-dodecakis(NN-dimethylformamide)-dodeca-dysprosium(iii) NN-dimethylformamide solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 949950: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographycatena-(bis(mu-44'-pyridine-26-diylbis(4-oxybut-3-en-2-one))-(mu-44'-oxydibenzoato)-tetraaqua-dysprosium-di-nickel nitrate trihydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1558856: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(acetato)-{mu-[2-{[(3-{4-[3-({[2-(hydroxy)phenyl]methylidene}amino)propyl]piperazin-1-yl}propyl)imino]methyl}phenolato]}-di-copper(ii)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1482465: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-(R)-(2-(((2'-((2-oxy-3-methoxybenzylidene)amino)-11'-binaphthalen-2-yl)imino)methyl)-6-methoxyphenolato))-bis(mu-methoxo)-di-manganese(iii) NN-dimethylformamide solvateExperimental 3D Coordinates
researchProduct

CCDC 1957555: Experimental Crystal Structure Determination

2019

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Space GroupCrystallography(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-isothiocyanato)-dinitrato-tri-cobalt acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1826839: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal System(mu-2-methoxy-6-[{[2-(morpholin-4-yl)ethyl]imino}methyl]phenolato)-(mu-nitrato)-(2-methoxy-6-[{[2-(morpholin-4-yl)ethyl]imino}methyl]phenolato)-acetonitrile-aqua-di-nickel(ii) perchlorate acetonitrile solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2010168: Experimental Crystal Structure Determination

2022

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 953097: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal Systemcatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-(22'-bipyridine)-nitrato-aqua-dicyano-dysprosium-nickel-tungsten acetonitrile solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 949949: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographycatena-(bis(mu-44'-pyridine-26-diylbis(4-oxybut-3-en-2-one))-(mu-dicyanamide)-bis(nitrato)-gadolinium-di-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1029369: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-44'-Azulene-13-diyldipyridine)-bis(mu2-44'-bipyridine)-bis(NN-dimethylformamide)-tetrakis(isothiocyanato)-di-cobalt methanol solvate dihydrate]Experimental 3D Coordinates
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CCDC 1558855: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(mu-22'-{piperazine-14-diylbis[(propane-31-diyl)azanylylidenemethylylidene]}diphenolato)-bis(mu-azido)-hexa-copper(ii) bis(perchlorate)
researchProduct

CCDC 949948: Experimental Crystal Structure Determination

2013

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Space GroupCrystallography(44'-Azulene-13-diyldipyridine)-(22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(nitrato)-europium(iii)-zinc(ii) monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1580964: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[(22-dimethylpropane-13-diyl)bis(azanylylidenemethylylidene)]diphenolato)-bis(111555-hexafluoroacetylacetonato)-copper(ii)-cobalt(ii)Experimental 3D Coordinates
researchProduct

CCDC 1049497: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systemhexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-copper-hexa-europium dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1029370: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-44'-Azulene-13-diyldipyridine)-bis(mu2-44'-ethene-12-diyldipyridine)-bis(NN-dimethylformamide)-tetrakis(isothiocyanato)-di-cobalt hydrate]Experimental 3D Coordinates
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CCDC 2044706: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-4455-tetramethyl-3-oxo-2-(5-phenyl-1H-pyrazol-4-yl)-45-dihydro-1H-3-imidazol-1-oxyl)-hexakis(111555-hexafluoroacetylacetonato)-di-terbium(iii)Experimental 3D Coordinates
researchProduct

CCDC 1550042: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal Systemhexakis(mu-bis(2-oxyethyl)amine)-tris(acetato)-cobalt(ii)-tri-cobalt(iii)-tri-copper(ii) acetate perchlorateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957554: Experimental Crystal Structure Determination

2019

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Space GroupCrystallography(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-azido)-dinitrato-tri-cobaltCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1582340: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(hexakis(mu-cyano)-(mu-oxalato)-tetrakis(mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-tetra-aqua-hexacyano-di-chromium-tetra-copper-tetra-manganese hexahydrate)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1558561: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-22'-{piperazine-14-diylbis[(propane-31-diyl)azanylylidenemethylylidene]}diphenolato)-diaqua-tri-copper(ii) bis(perchlorate) trihydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1839534: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systemaqua-bis[2-methoxy-6-({[2-(morpholin-4-yl)ethyl]imino}methyl)phenolato]-cobalt(iii) perchlorate methanol solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1049498: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal Structurehexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-copper-hexa-gadolinium dimethylformamide solvate nonahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1892384: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu-cyano)-(mu-25-bis(pyridin-2-yl)pyrazine)-hexacyano-(213-dimethyl-3691218-penta-azabicyclo[12.3.1]octadeca-1(18)2121416-pentaene)-di-cobalt-manganese heptahydrate)Experimental 3D Coordinates
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CCDC 2010169: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-4455-tetramethyl-3-oxo-2-(5-phenyl-1H-pyrazol-4-yl)-45-dihydro-1H-3-imidazol-1-oxyl)-hexakis(111555-hexafluoroacetylacetonato)-di-thulium(iii)Experimental 3D Coordinates
researchProduct

CCDC 953098: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-aqua-(22'-bipyridine)-(nitrato)-bis(cyano)-nickel-gadolinium-tungsten acetonitrile solvate dihydrate]Experimental 3D Coordinates
researchProduct

CCDC 1574908: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systemcatena-[tris(mu-cyano)-(mu-1024-dimethyl-36141720-pentaazatricyclo[20.3.1.1812]heptacosa-1(26)268(27)91113202224-decaene-2627-diolato)-(22'-bipyridine)-tricyano-copper(ii)-manganese(ii)-tungsten(v) (22'-bipyridine)-hexacyano-tungsten(v) acetonitrile solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 949947: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographycatena-[(mu~2~- 44'-Azulene-13-diyldipyridine)-(22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(nitrato)-gadolinium-nickel acetonitrile solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2044707: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(mu-4455-tetramethyl-3-oxo-2-(5-phenyl-1H-pyrazol-4-yl)-45-dihydro-1H-3-imidazol-1-oxyl)-hexakis(111555-hexafluoroacetylacetonato)-di-dysprosium(iii)
researchProduct

CCDC 995945: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-bis(mu-cyano)-bis(110-phenanthroline)-tetra-aqua-hexacyano-copper-di-iron-dysprosium nitrate heptahydrateExperimental 3D Coordinates
researchProduct

CCDC 1580963: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systembis(mu-2-methoxy-6-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato)-bis(111555-hexafluoroacetylacetonato)-di-nickel(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957552: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-nitrato)-dinitrato-tri-nickel acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1580965: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-22'-[(22-dimethylpropane-13-diyl)bis(iminomethyl)]diphenolato)-bis(mu-methoxo)-bis(111555-hexafluoroacetylacetonato)-tetra-copper(ii)Experimental 3D Coordinates
researchProduct

CCDC 1825560: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal Structuredodecakis(mu-3-formyl-2-oxidobenzoato)-dodecakis(mu-hydroxo)-dodecakis(NN-dimethylformamide)-dodeca-europium(iii) NN-dimethylformamide solvateCell ParametersExperimental 3D Coordinates
researchProduct