Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour

A binary reversible switch between low-temperature multi-step spin crossover (SCO), through the evolution of the population γHS(T) with high-spin (HS)-low-spin (LS) sequence: HS1LS0 (state 1) ↔ HS2/3LS1/3 (state 2) ↔ HS1/2LS1/2 (state 3) ↔ HS1/3LS2/3 (state 4) ↔ HS0LS1 (state 5), and complete one step hysteretic spin transition featuring 20 K wide thermal hysteresis centred at 290 K occurs in the three-dimensional (3D) Hofmann-type porous coordination polymer {FeII(3,8phen)[Au(CN)2]2}·xPhNO2 (3,8phen = 3,8-phenanthroline, PhNO2 = nitrobenzene), made up of two identical interpenetrated pcu-type frameworks. The included PhNO2 guest (x = 1, 1·PhNO2) acts as a molecular wedge between the interp…

[Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate

In the binuclear title complex, [Cu2(ClO4)1.5(NO3)1.5(C18H16N6Se)(H2O)5]NO3·H2O, both CuII ions are hexacoordinated by O and N atoms, thus forming axially elongated CuO4N2 octahedra. The equatorial plane of each octahedron is formed by one chelating pyrazole–pyridine fragment of the organic ligand and two water molecules. The axial positions in one octahedron are occupied by a water molecule and a monodentately coordinated perchlorate anion, while those in the other are occupied by a nitrate anion and a disordered perchlorate/nitrate anion with equal site occupancy. The pyrazole–pyridine units of the organic selenide are trans-oriented to each other with a C—Se—…

One-Dimensional Iron(II) Compounds Exhibiting Spin Crossover and Liquid Crystalline Properties in the Room Temperature Region

A novel series of 1D Fe(II) metallomesogens have been synthesized using the ligand 5-bis(alkoxy)- N-(4 H-1,2,4-triazol-4-yl)benzamide (C n -tba) and the Fe(X) 2. sH 2O salts. The polymers obey the general formula [Fe(C n -tba) 3](X) 2. sH 2O [X = CF 3SO 3 (-), BF 4 (-); n = 4, 6, 8, 10, 12]. The derivatives with n = 4, 6 exhibit spin transition behavior like in crystalline compounds, whereas those with n = 8, 10, 12 present a spin transition coexisting with the mesomorphic behavior in the room-temperature region. A columnar mesophase has been found for the majority of the metallomesogens, but also a columnar lamellar mesophase was observed for other derivatives. [Fe(C 12-tba) 3](CF 3SO 3) 2…

Pressure and Thermally Induced Spin Crossover in a 2D Iron(II) Coordination Polymer {Fe[bipy(ttr)2]}n

Using magnetic measurements and UV -visible spectroscopy we have studied the pressure influence on the spin crossover (SCO) properties of the 2D Fe (II) coordination polymer formulated {Fe[bipy(ttr) 2 ]} n . At variable temperature and fixed pressure, we have measured the magnetic property of this compound. Under different pressures and at room temperature, the visible spectroscopy has been observed. The magnetic experiment displays a two-step spin crossover behavior under pressure. The visible spectroscopic measurements at room temperature show a spin crossover with an asymmetric hysteresis at 0.4GPa.

Imparting hysteretic behavior to spin transition in neutral mononuclear complexes

A series of spin transition neutral compounds [FeL(NCS)2] has been synthesized and characterized by means of magnetic susceptibility studies, X-ray diffraction, IR and Mossbauer spectroscopic, and calorimetric measurements (L = N,N-bis((3-alkoxypyridin-2-yl)methylene)-propane-1,3-diamine, number of carbon atoms in chains (n) = 4, 12, 14, 16, 18, 20). The shortest chain compound is crystalline and displays a gradual spin transition above ambient temperature. Growing the aliphatic substituent up to n = 12 and 14 leads to loss of crystalline order and deterioration of magnetic properties. At the critical chain length n = 16 and above, the compounds undergo a phase transition reflected by a spi…

Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

[EN] A multistable spin crossover (SCO) molecular alloy system [Fe1-xMx(nBu-im)(3)(tren)](P1-yAsyF6)(2) (M = Zn-II, Ni-II; (nBu-im)(3)(tren) = tris(n-butyl-imidazol(2-ethylamino))amine) has been synthesized and characterized. By controlling the composition of this isomorphous series, two cooperative thermally induced SCO events featuring distinct critical temperatures (T-c) and hysteresis widths (Delta T-c, memory) can be selected at will. The pristine derivative 100As (x = 0, y = 1) displays a strong cooperative two-step SCO and two reversible structural phase transitions (PTs). The low temperature PTLT and the SCO occur synchronously involving conformational changes of the ligand's n-buty…

Spin crossover in metallomesogens

Abstract In this review article are illustrated the strategies developed in order to achieve interplay/synergy between spin transition and liquid crystal transition. The synthesised Fe(II) metallomesogens exhibit different types of interplay between both phase transitions. A classification according to the analysis of the magnetic and structural data has led to the separation of three types of interplay, namely: type i systems with coupled phase transitions, subdivided into three groups a , b and c (in a the structural changes associated with the Cr ↔ LC drive the spin transition while in b these structural changes influence the spin state of the metallic centers but they are not the drivin…

[Aquabis(nitrato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua(nitrato-κO)copper(II)] nitrate monohydrate

In the title binuclear complex, [Cu2(NO3)3(C18H16N6Se)(H2O)3]NO3·H2O, the CuII ions are pentacoordinated in a tetragonal–pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water molecule and a nitrate O atom, whereas the apical positions are occupied by a water molecule for one CuII ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C–Se–C plane. Numerous intermolecular O—H...O and N—H...O hydrogen bonds between the coordinating and lattice water molecules, nitrate anions and pyrazole groups are observed. &amp…

Bis(3,5-dimethyl-1H-pyrazolyl)selenide--a new bidentate bent connector for preparation of 1D and 2D co-ordination polymers.

The synthesis and description of eight polymeric complexes formed by transition metals with the bifurcated ligand bis(3,5-dimethyl-1H-pyrazolyl)selenide are discussed together with X-ray crystal analysis as well as variable temperature magnetic susceptibility and characterization by Mossbauer spectroscopy. Preferable types of binding patterns of the ligand were determined, which include a variation of the bridging modes (cis- and trans-) and of the separation length, where the latter parameter together with bending of the ligand molecule were found to be dependent on the type of co-ordination geometry of the central atom and the nature of the anion. A strategy for increasing the structure d…

[Aquabis(nitrato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua(nitrato-κO)copper(II)] nitrate monohydrate

In the title binuclear complex, [Cu2(NO3)3(C18H16N6Se)(H2O)3]NO3·H2O, the Cu(II) ions are penta-coordinated in a tetra-gonal-pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water mol-ecule and a nitrate O atom, whereas the apical positions are occupied by a water mol-ecule for one Cu(II) ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C-Se-C plane. Numerous inter-molecular O-H⋯O and N-H⋯O hydrogen bonds between the coordinating and lattice water mol-ecules, nitrate anions and pyrazole groups are observed. π-π stacking inter-actions between the pyridine rings [av…

The Effect of Pressure on the Cooperative Spin Transition in the 2D Coordination Polymer {Fe(phpy) 2 [Ni(CN) 4 ]}

The effect of pressure on the spin-transition properties of the 2D coordination polymer {Fe(phpy)2[Ni(CN)4]} is reported. The study has been carried out by means of variable-temperature (10–310 K) magnetic susceptibility measurements at applied pressures of 105 Pa to 1.0 GPa and spectroscopic studies in the visible region at room temperature (105 Pa–3.0 GPa). As the pressure is increased, the characteristic temperature of the spin transition is displaced to higher temperatures and the thermal hysteresis loop disappears. A cooperative first-order spin transition characterized by a piezo-hysteresis loop about 0.3 GPa wide was observed at 293 K.

Does the solid-liquid crystal phase transition provoke the spin-state change in spin-crossover metallomesogens?

Three types of interplay/synergy between spin-crossover (SCO) and liquid crystalline (LC) phase transitions can be predicted: (i) systems with coupled phase transitions, where the structural changes associated to the Cr LC phase transition drives the spin-state transition, (ii) systems where both transitions coexist in the same temperature region but are not coupled, and (iii) systems with uncoupled phase transitions. Here we present a new family of Fe(II) metallomesogens based on the ligand tris[3-aza-4-((5-C(n))(6-R)(2-pyridyl))but-3-enyl]amine, with C(n) = hexyloxy, dodecyloxy, hexadecyloxy, octadecyloxy, eicosyloxy, R = hydrogen or methyl (C(n)-trenH or C(n)-trenMe), which affords examp…

Thermal- and light-induced spin crossover in novel 2D Fe(II) metalorganic frameworks {Fe(4-PhPy)(2)[M(II)(CN)(x)](y)}.sH(2)O: spectroscopic, structural, and magnetic studies.

Five novel two-dimensional coordination polymers {Fe(4PhPy)(2)[M(II)(CN)(4)]}.sH(2)O (4PhyPy = 4-phenylpyridine; 1: M(II) = Pd, s = 0; 2: M(II) = Ni, s = 0; 3: M(II) = Pt, s = 1) and {Fe(4PhPy)(2)[M(I)(CN)(2)](2)}.sH(2)O (4: M(I) = Ag, s = 1; 5: M(I) = Au, s = 0.5) exhibiting spin-crossover properties have been synthesized. They were characterized at various temperatures using X-ray absorption spectroscopy (XAS), powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), and magnetic susceptibility measurements. The occurrence of a cooperative thermal spin transition detected by the magnetic method is located at critical temperatures T(c)( downward arrow)/T(c)( upward arrow) …

Spin-Crossover and Liquid Crystal Properties in 2D Cyanide-Bridged FeII−MI/II Metalorganic Frameworks

Novel two-dimensional heterometallic Fe(II)-M(Ni(II), Pd(II), Pt(II), Ag(I), and Au(I)) cyanide-bridged metalorganic frameworks exhibiting spin-crossover and liquid crystal properties, formulated as {FeL(2)[M(I/II)(CN)(x)](y)}·sH(2)O, where L are the ligands 4-(4-alkoxyphenyl)pyridine, 4-(3,4-dialkoxyphenyl)pyridine, and 4-(3,4,5-trisalkoxyphenyl)pyridine, have been synthesized and characterized. The physical characterization has been carried out by means of EXAFS, X-ray powder diffraction, magnetic susceptibility, differential scanning measurements, and Mössbauer spectroscopy. The 2D Fe(II) metallomesogens undergo incomplete and continuous thermally induced spin transition at T(1/2) ≈ 170 …

Spin crossover in soft matter

Abstract This review article is devoted to the study of the spin crossover phenomenon in soft matter. Spin crossover compounds, though known for decades, bear the potential for practical applications in switching, sensing and display devices. Having arrived at a reasonable understanding of the spin transition process in solid and liquid states, one trend in this research field is to extend the knowledge into soft matter. The review begins with a brief description of Langmuir–Blodgett thin films based on FeII coordination compounds since it represents the first study of the spin crossover phenomenon in soft matter. The following section illustrates the FeII, FeIII and CoII complexes reported…

Homoleptic iron(II) complexes with the ionogenic ligand 6,6′-Bis(1H-tetrazol-5-yl)-2,2′-bipyridine: spin crossover behavior in a singular 2D spin crossover coordination polymer

Deprotonation of the ionogenic tetradentate ligand 6,6′-bis(1H-tetrazol-5-yl)-2,2′-bipyridine [H2bipy(ttr)2] in the presence of FeII in solution has afforded an anionic mononuclear complex and a neutral two-dimensional coordination polymer formulated as, respectively, NEt3H{Fe[bipy(ttr)2][Hbipy(ttr)2]}·3MeOH (1) and {Fe[bipy(ttr)2]}n (2). The anions [Hbipy(ttr)2]− and [bipy(ttr)2]2– embrace the FeII centers defining discrete molecular units 1 with the FeII ion lying in a distorted bisdisphenoid dodecahedron, a rare example of octacoordination in the coordination environment of this cation. The magnetic behavior of 1 shows that the FeII is high-spin, and its Mössbauer spectrum is characteriz…

Meltable Spin Transition Molecular Materials with Tunable Tc and Hysteresis Loop Width.

Herein, we report a way to achieve abrupt high-spin to low-spin transition with controllable transition temperature and hysteresis width, relying not on solid-state cooperative interactions, but utilizing coherency between phase and spin transitions in neutral FeII meltable complexes

Control of the spin state by charge and ligand substitution: two-step spin crossover behaviour in a novel neutral iron(II) complex

The influence of the charge and steric hindrance on the spin state of a series of four monomeric Fe-II complexes derived from the tridentate tigands 2-(1H-benzoimidazol-2-yl)-1,10-phenanthroline (Hphenbi) and 2-(1H-benzoimidazol-2-yl-9-methyl-1,10-phenanthroline (Hmphenbi) and their deprotonated forms (phenbi(-), mphenbi(-)) are investigated. The crystal structure and magnetic properties show that [Fe(Hphenbi)(2)](BF4)(2)center dot 1.5C(6)H(5)NO(2)center dot H2O (1) and its neutral form [Fe(phenbi)(2)]center dot 2CHCl(3)center dot H2O (2) are low-spin complexes at 400 K due to the strong ligand field imparted by the terpyridine-like tigand. In contrast, the steric hindrance induced by the m…

catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N]

The molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeIIatoms. The Fe—N(py) bond length (py is pyridine) is 2.2700 (15) Å, Fe—N(cyanide) is 2.1185 (16) Å and the Fe—O distance is 2.1275 (14) Å. The water molecules are hydrogen bonded to either bpb ligands or cyanide groups of the planar [Pt(CN)4]2−anion of adjacent polymeric chains. These O—H...N hydrogen bonds, in conjunction with offset and tilted π–π stacking interactions between bpb ligands and cyan…

Magnetism and Molecular Nonlinear Optical Second-Order Response Meet in a Spin Crossover Complex

International audience; The quadratic hyperpolarizability of two inorganic Schiff base metal complexes which differ from each other by the nature of the central metal ion (FeII or ZnII) is estimated using hyper-Rayleigh light-scattering (HRS) measurements. The investigated FeII microcrystals exhibit a thermal spin-crossover (SCO) from a diamagnetic to a paramagnetic state centered at T1/2 = 233 K that can be reproduced by the HRS signal whose modest intensity is mainly due to their centrosymmetric packing structure. Diamagnetic ZnII microcrystals even lead to much weaker (∼400 times) HRS intensities which are in addition temperature-independent. These observations allow us to ascribe the ch…

Cover Feature: Cyanido‐Bridged Fe II –M I Dimetallic Hofmann‐Like Spin‐Crossover Coordination Polymers Based on 2,6‐Naphthyridine (Eur. J. Inorg. Chem. 3‐4/2018)

Variable Cooperative Interactions in the Pressure and Thermally Induced Multistep Spin Transition in a Two-Dimensional Iron(II) Coordination Polymer

Two types of experiments conducted to investigate the effect of pressure on the spin crossover (SCO) properties of the 2D Fe(II) coordination polymer formulated {Fe[bipy(ttr)2]}n are reported, namely, (1) magnetic measurements performed at variable temperature and at fixed pressure and (2) visible spectroscopy at variable pressure and fixed temperature. The magnetic experiments carried out under a hydrostatic pressure constraint of 0.04, 0.08, and 0.8 GPa reveal a two-step spin transition behavior. The characteristic critical temperatures of the spin transition are shifted upward in temperature as pressure increases. The slope of the straight-line of the Tc vs P plot, dTc/dP, is 775 K/GPa a…

Spin crossover in iron(II) complexes: Recent advances

In this review article, several representative multifunctional SCO materials exhibiting interplay/synergy between the spin transition and magnetic coupling or liquid crystalline properties together with the present pioneering works on nano-structuration of SCO materials are illustrated. As the Mossbauer spectroscopy has been decisive in the study of the physical properties of these multifunctional materials, special attention is given to their corresponding Mossbauer investigations.

Mononuclear Complexes of Iron(II) Based on Symmetrical Tripodand Ligands: Novel Parent Systems for the Development of New Spin Crossover Metallomesogens

The synthesis and characterization of a series of mononuclear tripodand-based FeII complexes by means of Mossbauer andUV/Vis spectroscopic as well as magnetic methods is reported. The complexes were obtained from the reactions of FeII salt with heterocyclic aldehydes (imd = imidazole-4(5)-carboxaldehyde, py = picolinaldehyde, or 6-Mepy = 6-methylpicolinaldehyde) and a symmetric triamine [tren = tris(2-aminoethyl)amine, tame = 2,2,2-tris(aminomethyl)ethane, or tach = 1,3,5-cis,cis-cyclohexanetriamin]. Because of extreme rigidity of the capping triamine tach, the molecular structure of {Fe[tach(imd)3](BF4)2} (1) features an unprecedented tapered trigonal prismatic FeN6 polyhedron. The molecul…

Cyanido-Bridged FeII-MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine

[EN] Two new 3D spin-crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1; 2,6-naphthy = 2,6-naphthyridine) and {Fe(2,6-naphthy)- [Au(CN)2]2}·0.5PhNO2 (2) were synthesized and characterized. Both derivatives are made up of infinite stacks of {Fe[Ag(CN)2]2- [Ag2(CN)3]}n and {Fe[Au(CN)2]2}n layered grids connected by pillars of 2,6-naphthy ligands coordinated to the axial positions of the FeII centers of alternate layers.

Thermochromic Meltable Materials with Reverse Spin Transition Controlled by Chemical Design

International audience; We report a series of meltable FeII complexes, which, depending on the length of aliphatic chains, display abrupt forward low‐spin to high‐spin transition or unprecedented melting‐triggered reverse high‐spin to low‐spin transition on temperature rise. The reverse spin transition is perfectly reproducible on thermal cycling and the obtained materials are easily processable in the form of thin film owing to their soft‐matter nature. We found that the discovered approach represents a potentially generalizable new avenue to control both the location in temperature and the direction of the spin transition in meltable compounds.

CCDC 1972870: Experimental Crystal Structure Determination

Related Article: Lucía Piñero-López, Maksym Seredyuk, M. Carmen Muñoz, Jose Antonio Real|2020|Eur.J.Inorg.Chem.|2020|764|doi:10.1002/ejic.201901347

CCDC 1007129: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K

CCDC 971025: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1550080: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 1417214: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Maksym Seredyuk, Carmen Muñoz, Jose A. Real|2015|Angew.Chem.,Int.Ed.|54|14777|doi:10.1002/anie.201507620

CCDC 2016312: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1572177: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1572180: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1879899: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1879896: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 971023: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1572183: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1572184: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1565402: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 1879901: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1572181: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1418191: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk , Lucía Piñeiro-López , M. Carmen Muñoz , Francisco J. Martínez-Casado , Gábor Molnár , José Alberto Rodriguez-Velamazán , Azzedine Bousseksou , José Antonio Real|2015|Inorg.Chem.|54|7424|doi:10.1021/acs.inorgchem.5b01001

CCDC 1417215: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Maksym Seredyuk, Carmen Muñoz, Jose A. Real|2015|Angew.Chem.,Int.Ed.|54|14777|doi:10.1002/anie.201507620

CCDC 1418192: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk , Lucía Piñeiro-López , M. Carmen Muñoz , Francisco J. Martínez-Casado , Gábor Molnár , José Alberto Rodriguez-Velamazán , Azzedine Bousseksou , José Antonio Real|2015|Inorg.Chem.|54|7424|doi:10.1021/acs.inorgchem.5b01001

CCDC 1879898: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 2010363: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1994888: Experimental Crystal Structure Determination

Related Article: Francisco‐Javier Valverde‐Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Gábor Molnár, Yurii S. Bibik, José Antonio Real|2020|Angew.Chem.,Int.Ed.|59|18632|doi:10.1002/anie.202006453

CCDC 1455020: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna Znovjyak, M. Carmen Muñoz, Yurii Galyametdinov, Igor O. Fritsky, Jose A. Real|2016|RSC Advances|6|39627|doi:10.1039/C6RA05342D

CCDC 1007130: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K

CCDC 1455021: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna Znovjyak, M. Carmen Muñoz, Yurii Galyametdinov, Igor O. Fritsky, Jose A. Real|2016|RSC Advances|6|39627|doi:10.1039/C6RA05342D

CCDC 1007126: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K

CCDC 1418190: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk , Lucía Piñeiro-López , M. Carmen Muñoz , Francisco J. Martínez-Casado , Gábor Molnár , José Alberto Rodriguez-Velamazán , Azzedine Bousseksou , José Antonio Real|2015|Inorg.Chem.|54|7424|doi:10.1021/acs.inorgchem.5b01001

CCDC 915257: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Munoz, Miguel Castro, Tania Romero-Morcillo, Ana B. Gaspar,Jose Antonio Real|2013|Chem.-Eur.J.|19|6591|doi:10.1002/chem.201300394

CCDC 1572182: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 975036: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Muñoz, Vadim Ksenofontov, Philipp Gütlich, Yury Galyametdinov, and Jose A. Real|2014|Inorg.Chem.|53|8442|doi:10.1021/ic5010159

CCDC 975041: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Muñoz, Vadim Ksenofontov, Philipp Gütlich, Yury Galyametdinov, and Jose A. Real|2014|Inorg.Chem.|53|8442|doi:10.1021/ic5010159

CCDC 915259: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Munoz, Miguel Castro, Tania Romero-Morcillo, Ana B. Gaspar,Jose Antonio Real|2013|Chem.-Eur.J.|19|6591|doi:10.1002/chem.201300394

CCDC 1848631: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

CCDC 2010365: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1879900: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1550075: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 971022: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1565404: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 971024: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 975039: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Muñoz, Vadim Ksenofontov, Philipp Gütlich, Yury Galyametdinov, and Jose A. Real|2014|Inorg.Chem.|53|8442|doi:10.1021/ic5010159

CCDC 1550084: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 2010361: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1972869: Experimental Crystal Structure Determination

Related Article: Lucía Piñero-López, Maksym Seredyuk, M. Carmen Muñoz, Jose Antonio Real|2020|Eur.J.Inorg.Chem.|2020|764|doi:10.1002/ejic.201901347

CCDC 1848628: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

CCDC 1892385: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1565403: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 2010360: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1417216: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Maksym Seredyuk, Carmen Muñoz, Jose A. Real|2015|Angew.Chem.,Int.Ed.|54|14777|doi:10.1002/anie.201507620

CCDC 1007125: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K

CCDC 1550083: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 2010362: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 975037: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Muñoz, Vadim Ksenofontov, Philipp Gütlich, Yury Galyametdinov, and Jose A. Real|2014|Inorg.Chem.|53|8442|doi:10.1021/ic5010159

CCDC 2010366: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1007128: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K

CCDC 1550074: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 1572179: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 915258: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Munoz, Miguel Castro, Tania Romero-Morcillo, Ana B. Gaspar,Jose Antonio Real|2013|Chem.-Eur.J.|19|6591|doi:10.1002/chem.201300394

CCDC 1572178: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1857201: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

CCDC 1007127: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Muñoz, Jose Antonio Real|2014|Dalton Trans.|43|16387|doi:10.1039/C4DT01885K

CCDC 1550078: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 971021: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1550076: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 1550081: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 975038: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Muñoz, Vadim Ksenofontov, Philipp Gütlich, Yury Galyametdinov, and Jose A. Real|2014|Inorg.Chem.|53|8442|doi:10.1021/ic5010159

CCDC 1848626: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

CCDC 975040: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk, M. Carmen Muñoz, Vadim Ksenofontov, Philipp Gütlich, Yury Galyametdinov, and Jose A. Real|2014|Inorg.Chem.|53|8442|doi:10.1021/ic5010159

CCDC 2010364: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1550073: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 1879897: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1848629: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

CCDC 1972871: Experimental Crystal Structure Determination

Related Article: Lucía Piñero-López, Maksym Seredyuk, M. Carmen Muñoz, Jose Antonio Real|2020|Eur.J.Inorg.Chem.|2020|764|doi:10.1002/ejic.201901347

CCDC 1550077: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 1848627: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

CCDC 1550079: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639

CCDC 1550082: Experimental Crystal Structure Determination

Related Article: Lucı́a Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Matti Haukka, and José Antonio Real|2017|Inorg.Chem.|56|7038|doi:10.1021/acs.inorgchem.7b00639