0000000001302023
AUTHOR
Oscar Fabelo
showing 98 related works from this author
Low-Dimensional 3d–4f Complexes Assembled by Low-Spin [FeIII(phen)(CN)4]− Anions
2013
The synthesis, crystal structure, and magnetic properties of four new mixed 3d-4f complexes with formulas [{FeIII(phen)(CN)4} 4Gd2 III(bpym)(NO3) 2(H2O)4]·2CH3CN· 2H2O}n (1), [{FeIII(phen)(CN)4} 4Tb2 III(bpym)(H2O) 8]·(NO3)2·2CH3CN} n (2), [{FeIII(phen)(CN)4}4Sm III(bpym)(NO3)2(H2O) 5]·2CH3CN}n (3), and [{Fe III(phen)(CN)4}2Pr2 III(bpym)(NO3)4(H2O) 2]n (4) (phen = 1,10-phenanthroline and bpym = 2,2′-bipyrimidine) are discussed here. Compounds 1-3 are isomorphous and their structure consists of neutral ladder-like motifs where the rungs are made up by bpym-bridged dilanthanide(III) cations and the rods are defined by [Fe(phen)(CN)4]- units adopting a bis-monodentate coordination mode through…
Self-assembly of a chiral three-dimensional manganese(II)-copper(II) coordination polymer with a double helical architecture
2013
The use of the anionic dicopper(ii) complex, [CuII(mpba) 2]4- [mpba = N,N′-1,3-phenylenebis(oxamate)], as tetrakis(bidentate) metalloligand toward MnII ions in the presence of oxalate and the chiral (S)-trimethyl-(1-phenylethyl)ammonium cation affords the first example of a mixed oxalato/oxamato-based chiral 3D metal-organic polymer. © 2013 The Royal Society of Chemistry.
All-cis-1,2,3,4,5,6-cyclohexanehexacarboxylate two-dimensional gadolinium(III) complexes: Synthesis, X-ray crystal structure and magnetic properties
2010
Abstract The first gadolinium(III) complexes with the trideprotonated form of the 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H3clhex3−) of formulae [Gd(H3clhex)(H2O)4]n·3nH2O (1) and [Gd(H3clhex)(H2O)4]n·6nH2O (2) have been prepared through the gel technique and their structures determined by single crystal X-ray diffraction. The structure of 1 is made up of 63 honey-comb layers which are generated by [Gd(H2O)4]3+ cations and H3clhex3− anions acting as three-fold nodes and three-fold connectors, respectively. The structure of 2 consists of a [44,62] two-dimensional network extended in the ac plane where the H3clhex−3 groups act as four-fold connectors and the [Gd(H2O)4]3+ units as four-fol…
Copper(II)-methylmalonate complexes with unidentate N-donor ligands: Syntheses, structural characterization and magnetic properties
2009
Abstract Two new methylmalonate-bridged copper(II) complexes with the formulas [Cu(3-Ipy)(Memal)(H 2 O)] ( 1 ) and [Cu(2,4′-bpy)(Memal)(H 2 O)] · 3H 2 O ( 2 ) [Memal = methylmalonate dianion, 3-Ipy = 3-iodopyridine, 2,4′-bpy = 2,4′-bipyridine] have been synthesized and characterized by X-ray diffraction. Both compounds crystallize in the monoclinic space group P 2 1 / n and Z = 4, with unit cell parameters a = 8.5874(13) A, b = 7.1738(14) A, c = 19.093(5) A, β = 99.509(15)° in 1 and a = 17.375(4) A, b = 7.3305(14) A, c = 14.247(3) A, β = 111.409(15)° in 2 . The structures of 1 and 2 consist of zigzag chains of anti-syn carboxylate-bridged copper(II) ions running along the b directi…
[Fe(phen)(CN)4]−: a suitable metalloligand unit to build 3d–4f heterobimetallic complexes with mixed bpym-cyano bridges (phen = 1,10-phenantroline, b…
2010
The synthesis, crystal structure and magnetic properties of a new series of mixed 3d–4f complexes with the formula [{FeIII(phen)(CN)3(μ-CN)}4Ln2III(NO3)2(H2O)6(μ-bpym)]·nH2O [Ln = Eu (1), Gd (2), Dy (3) and Ho (4); n = 8 (1, 3 and 4) and 11 (2); phen = 1,10-phenantroline; bpym = 2,2′-bipyrimidine] are discussed here. Compounds 1–4 are centrosymmetric hexanuclear species whose structure is made up of two cyano-bridged {Fe2IIILnIII} heterobimetallic moieties which are connected through a bis-bidentate bpym molecule between the two rare-earth centers. The values of the iron–lanthanide distance across the single cyano-bridge are Fe(1)⋯Eu(1) = 5.5587(8) and Fe(2)⋯Eu(1) = 5.4908(8) A (1), Fe(1)⋯G…
Crystal growth and structural remarks on malonate-based lanthanide coordination polymers
2016
The synthesis, structural characterization and thermal study of new coordination polymers (CPs) of formula [Ln2(mal)3(H2O)5]·2H2O [Ln = Ho (1·2H2O), Tb (1a), Dy (1b), Er (1c) and Yb (1d); mal = malonate], [Ln2(mal)3(H2O)6] [Ln = Sm (2) and Ce (2a)], [Ce2(mal)3(H2O)6]·2H2O (3·2H2O) and [Ce2(mal)3(H2O)3]·2H2O (4·2H2O) are presented. Complexes 1–4 have been also characterized by single crystal X-ray diffraction. The structure of 2 was previously reported (Elsegood, M. R. J., Husain, S., Private Communication, 2014) and it is very close to that of 3. In the light of these results and those previously reported in the literature for malonate-containing lanthanide(III) complexes, a detailed overvi…
Novel malonate-containing coordination compounds with ligands having N-And NO-donors: Synthesis, structures, and magnetic properties
2012
In our efforts to tune the structures of mixed-ligands malonate-containing coordination compounds, four copper(II) and two high-spin cobalt(II) complexes of formulas [Cu(mal)(H 2O)(dpo)] n (1), [Cu 2(mal) 2(H 2O) 2(dpp)] n · 7nH 2O (2), [Cu 2(mal) 2(H 2O) 2-(bpe)] n · 2nH 2O (3), {[Cu(mal) 2(H 2O) 2][Cu(dien)]} n · 4nH 2O (4)[Co 2(mal) 2(H 2O) 6(dpo)] ·2H 2O(5) and [Co(mal)(H 2O)(phen)] n · 2nH 2O (6) [H 2mal = malonic acid, dpo =4,4'-bipyridine-N,N'-dioxide, dpp = 2,3-bis(pyridyl)pyrazine, bpe =1,2-bis(4-pyridyl)ethylene, dien = diethylenetriamine and phen = 1,10-phenanthroline] have been synthesized and structurally characterized by X-ray diffraction on single crystals. Complexes 1, 2, 4,…
Intramolecular ferro- and antiferromagnetic interactions in oxo-carboxylate bridged digadolinium(iii) complexes
2010
Two new digadolinium(III) complexes with monocarboxylate ligands, [Gd2(pac)6(H2O)4] (1) and [Gd2(tpac)6(H2O)4] (2) (Hpac = pentanoic acid and Htpac = 3-thiopheneacetic acid), have been prepared and their structures determined by X-ray diffraction on single crystals. Their structures consist of neutral and isolated digadolinium(III) units, containing six monocarboxylate ligands and four coordinated water molecules, the bridging skeleton being built by a muO(1):kappa2O(1)O(2) framework. This structural pattern has already been observed in the parent acetate-containing compound [Gd2(ac)6(H2O)4] x 4 H2O (3) whose structure and magnetic properties were reported elsewhere (L. Cañadillas-Delgado, …
A step further in the comprehension of the magnetic coupling in gadolinium(III)-based carboxylate complexes
2013
Three new gadolinium(III) complexes of formula [Gd4(bta) 3(H2O)16]n·12nH2O (1), [Gd4(bta)3(H2O)12] n·18nH2O (2) and [Gd2(H 2bta)(bta)(H2O)2]n·4nH 2O (3) (H4bta = 1,2,4,5-benzenetetracarboxylic acid) have been synthesized and their structures determined by X-ray diffraction. 1 and 3 are three-dimensional compounds whereas 2 exhibits a two-dimensional structure. The ability of the bta4- to adopt different coordination modes accounts for these high dimensionalities although it precludes a rational structural design. The structures of 1-3 have in common the double oxo-carboxylate bridge between gadolinium(III) ions (μ-O: κ2O,O′) either as a discrete units (1 and 2) or as a chain (3) and one (3)…
Multielectron oxidation in a ferromagnetically coupled dinickel(ii) triple mesocate.
2015
Triple-stranded dinuclear nickel(ii) complexes of the meso-helicate type have been obtained from the new N,N'-1,3-phenylenebis(pyrazine-2-carboxamidate) ligand; they possess a multielectron redox behaviour featuring up to four stepwise, one-electron oxidation reactions of the two ferromagnetically coupled Ni(II) ions to afford the putative high-valent dinickel(iii) and dinickel(iv) species, as supported by theoretical calculations.
Neutron diffraction studies of the molecular compound [Co 2(bta)]n (H4bta =1,2,4,5-benzenetetracarboxylic acid): In the quest of canted ferromagnetism
2013
The exchange mechanism and magnetic structure of the organic-inorganic layered molecule-based magnet [Co2(bta)]n (1) (H 4bta =1,2,4,5-benzenetetracarboxylic acid) have been investigated through variable-temperature magnetic susceptibility measurements and supported with a series of neutron diffraction experiments. Cryomagnetic studies have shown an antiferromagnetic ordering at a transition temperature of 16 K that is followed by the appearance of a weak ferromagnetism below 11 K. The weak antiferromagnetic interlayer interaction plays an important role in this system in spite of the long interlayer separation. A ferromagnetic ordering is induced by applied magnetic fields greater than 1800…
Effect of linker distribution in the photocatalytic activity of multivariate mesoporous crystals
2021
The use of Metal-Organic Frameworks as crystalline matrices for the synthesis of multiple component or multivariate solids by the combination of different linkers into a single material has emerged as a versatile route to tailor the properties of single-component phases or even access new functions. This approach is particularly relevant for Zr6-MOFs due to the synthetic flexibility of this inorganic node. However, the majority of materials are isolated as polycrystalline solids, which are not ideal to decipher the spatial arrangement of parent and exchanged linkers for the formation of homogeneous structures or heterogeneous domains across the solid. Here we use high-throughput methodologi…
[Cu3(Hmesox)3]3−: a Precursor for the Rational Design of Chiral Molecule-Based Magnets (H4mesox = 2-dihydroxymalonic acid)
2010
Two new compounds K(3)[Cu(3)(Hmesox)(3)(H(2)O)] x 4 H(2)O (1) and {(PPh(4))(2)[CoCu(3)(Hmesox)(3)Cl]} (2) [H(4)mesox = mesoxalic acid (2-dihydroxymalonic acid) and PPh(4)(+) = tetraphenylphosphonium cation] have been prepared and magneto-structurally characterized. Compound 1 contains the [Cu(3)(Hmesox)(3)](3-) entity which can be considered as a new precursor for molecular magnetism. In 1 the triangular arrangement of three copper(II) ions bridged by alkoxo groups are further connected to a symmetry-related tricopper(II) unit through a double oxo(carboxylate) bridge. The resulting hexacopper(II) entities are joined further through anti-syn carboxylate groups into an anionic three-dimension…
Well-resolved unusual alternating cyclic water tetramers embedded in a crystal host
2008
Infinite network involving two hydrogen-bonded tetrameric water rings (S4 and D2h) in a (4,4)-square grid crystal host
Study of the influence of the bridge on the magnetic coupling in cobalt(II) complexes.
2009
Two new cobalt(II) complexes of formula [Co(2)(bta)(H(2)O)(6)](n) x 2nH(2)O (1) and [Co(phda)(H(2)O)](n) x nH(2)O (2) [H(4)bta = 1,2,4,5-benzenetetracarboxylic acid, H(2)phda = 1,4-phenylenediacetic acid] have been characterized by single crystal X-ray diffraction. Compound 1 is a one-dimensional compound where the bta(4-) ligand acts as 2-fold connector between the cobalt(II) ions through two carboxylate groups in para-conformation. Triply bridged dicobalt(II) units occur within each chain, a water molecule, a carboxylate group in the syn-syn conformation, and an oxo-carboxylate with the mu(2)O(1);kappa(2)O(1),O(2) coordination mode acting as bridges. Compound 2 is a three-dimensional comp…
The Role of Order-Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron (II)…
2012
Neutron diffraction studies have been carried out to shed light on the unprecedented order-disorder phase transition (ca. 155 K) observed in the mixed-valence iron(II)-iron(III) formate framework compound [NH 2(CH3)2]n[FeIIIFe II(HCOO)6]n. The crystal structure at 220 K was first determined from Laue diffraction data, then a second refinement at 175 K and the crystal structure determination in the low temperature phase at 45 K were done with data from the monochromatic high resolution single crystal diffractometer D19. The 45 K nuclear structure reveals that the phase transition is associated with the order-disorder of the dimethylammonium counterion that is weakly anchored in the cavities …
Metal-organic coordination frameworks based on mixed methylmalonate and 4,4′-bipiridine ligands: synthesis, crystal structure and magnetic properties
2010
Five new complexes of formulae [M2(4,4′-bpy)(Memal)2X2]n [M = Fe(III) (2), Mn(II) (3), Co(II) (4), Ni(II) (5) and Zn(II) (6), and X = Cl−/OH− (2) and H2O (3–6); 4,4′-bpy = 4,4′-bipyridine and Memal = methylmalonate dianion] have been synthesized by following the previously reported procedure for [Cu2(4,4′-bpy)(Memal)2(H2O)2]n (1). Moreover, two new phases of the Cu(II)/Memal/4,4′-bpy system, namely {[Cu(4,4′-bpy)2][Cu(4,4′-bpy)2(Memal)(NO3)(H2O)]}n·nNO3·3.5nH2O (7) and [Cu(4,4′-bpy)2(Memal)(H2O)]n·nH2O (8), were obtained by varying the synthetic conditions. They were all structurally characterized by single crystal X-ray diffraction, and the magnetic properties of 2–5, 7 and 8 were investig…
Metallosupramolecular compounds based on Cu(ii)/oxalate/twisted NSSN ligands showing a new in situ S–C bond cleavage
2013
Four new complexes, [Cu2(C2O4) 2(SCS)]·3H2O (1), [Cu2(C 2O4)3(SCSH)2]·H2O (2), [Cu(C2O4)(SS)2]·3H2O (3) and [Cu(C2O4)(SS)]·6H2O (4) [where SCS = bis(4-pyridylthio)methane and SS = 4,4′-dipyridyldisulfide], have been synthesized by the reaction of the SS and SCS ligands with the corresponding copper(ii) oxalate salt. The different synthetic conditions allowed control of the preparation of a 3D open metal-organic framework in 1, a dinuclear zwitterionic molecular compound in 2 and one- and two-dimensional (1D and 2D) coordination polymers in 3 and 4, respectively. Compound 4 was also obtained by in situ transformation of the dithioether ligand (SCS) to the disulfide ligand (SS) under hydrothe…
Topological control of the spin coupling in dinuclear copper(II) complexes with meta- and para-phenylenediamine bridging ligands
2010
Abstract A novel series of copper(II) complexes of formula [Cu(tren)(mpda)](ClO4)2 · 1/2H2O (1), [Cu2(tren)2(mpda)](ClO4)4 · 2H2O (2), and [Cu2(tren)2(ppda)](ClO4)4 · 2H2O (3) containing the tetradentate tris(2-aminoethyl)amine (tren) terminal ligand and the potentially bridging 1,n-phenylenediamine [n = 3 (mpda) and 4 (ppda)] ligand have been prepared and spectroscopically characterized. X-ray diffraction on single crystals of 1 and 3 show the presence of mono- (1) and dinuclear (3) copper(II) units where the mpda (1) and ppda (3) ligands adopt terminal monodentate (1) and bridging bis(monodentate) (3) coordination modes toward [Cu(tren)]2+ cations with an overall non-planar, orthogonal di…
Self-assembly, metal binding ability, and magnetic properties of dinickel(II) and dicobalt(II) triple mesocates
2012
Two metallacyclic complexes of general formula Na-8[(M2L3)-L-II]center dot xH(2)O [M = Ni (4) and Co (5) with x = 15 (4) and 17 (5)] have been self-assembled in aqueous solution from N,N'-1,3-phenylenebis(oxamic acid) (H4L) and M2+ ions in a ligand/metal molar ratio of 3 : 2 in the presence of NaOH acting as base. X-Ray structural analyses of 4 and 5 show triple-stranded, dinuclear anions of the meso-helicate-type (so-called mesocates) with C-3h molecular symmetry. The two octahedral metal-tris(oxamate) moieties of opposite chiralities (Delta, Lambda form) are connected by three m-phenylene spacers at intermetallic distances of 6.822(2) (4) and 6.868(2) angstrom (5) to give a metallacryptan…
Dinuclear and two- and three-dimensional gadolinium(III) complexes with mono- and dicarboxylate ligands: synthesis, structure and magnetic properties
2009
Three new gadolinium(III) complexes with carboxylate ligands of formula [Gd2(ac)6(H2O)4]·2H2O (1), [Gd2(ac)2(fum)2(H2O)4]n (2) and [Gd2(ox)(fum)2(H2O)4]n·4nH2O (3) (ac = acetate, fum = fumarate and ox = oxalate) have been prepared and their structures determined by X-ray diffraction on single crystals. The structure of 1 is made up of discrete centrosymmetric di-µ-oxo(carboxylate acetate)digadolinium(III) units with an intramolecular Gd⋯Gd separation of 4.1589(3) A. Each gadolinium atom in 1 is nine-coordinated with two water molecules and seven carboxylate-oxygen atoms from four acetate ligands building a monocapped square antiprism environment. Compound 2 exhibits a sheet-like structure, …
Influence of the presence of divalent first-row transition metal ions on the structure of sodium(i) salts of 1,2,3,4-benzenetetracarboxylic acid (H4b…
2006
Three different sodium(I)-containing salts of 1,2,4,5-benzenetetracarboxylic (H4bta) of formula [Na4(bta)(H2O)12] (1), [Na2M(H2bta)2(H2O)8]·2H2O] [M = Mn (2) and Ni (3)] were synthesized and their structures were solved by single crystal X-ray diffraction methods. Compound 1 crystallises in orthorhombic system, space group Pc21b with a = 6.9997(4) A, b = 16.4260(9) A, c = 20.3312(18) A, V = 476.30(15) A3 and Z = 4. Compounds 2 and 3 crystallize in the monoclinic system, space group C2/m with a = 7.3778(4) A, b = 20.1493(6) A, c = 10.4963(4) A, β = 103.466(8)°, V = 1517.5(11) A3 and Z = 2 for 1 and a = 7.2862(4) A, b = 20.1165(7) A, c = 10.4032(3) A, β = 103.366(9)°, V = 1483.52(11) A3 and Z…
Synthesis, structural analysis, and magnetic properties of ethylmalonate-manganese(II) complexes
2011
12 páginas, 10 figuras, 6 tablas.-- et al.
Synthesis, crystal structure, and magnetic characterization of the three-dimensional compound [Co2(cbut)(H2O) 3]n (H4cbut = 1,2,3,4- cyclobutanetetra…
2014
A novel cobalt(II) complex of formula [Co2(cbut)(H 2O)3]n (1) (H4cbut = 1,2,3,4-cyclobutanetetracarboxylic acid) has been synthesized under hydrothermal conditions and its crystal structure has been determined by means of synchrotron radiation and neutron powder diffraction. The crystal structure of 1 consists of layers of cobalt(II) ions extending in the bc-plane which are pillared along the crystallographic a-axis through the skeleton of the cbut 4- ligand. Three crystallographically independent cobalt(II) ions [Co(1), Co(2), and Co(3)] occur in 1. They are all six-coordinate with four carboxylate-oxygens [Co(1)-Co(3)] and two cis-[Co(1)] or trans-water molecules [Co(2) and Co(3)] buildin…
High proton conduction in a chiral ferromagnetic metal-organic quartz-like framework.
2011
A complex-as-ligand strategy to get a multifunctional molecular material led to a metal-organic framework with the formula (NH(4))(4)[MnCr(2)(ox)(6)]·4H(2)O. Single-crystal X-ray diffraction revealed that the anionic bimetallic coordination network adopts a chiral three-dimensional quartz-like architecture. It hosts ammonium cations and water molecules in functionalized channels. In addition to ferromagnetic ordering below T(C) = 3.0 K related to the host network, the material exhibits a very high proton conductivity of 1.1 × 10(-3) S cm(-1) at room temperature due to the guest molecules.
Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(iii) complexes with 2,3-quinoxalinediolate ligands
2012
The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(iii) ions in basic media in air affords a new family of carbonato-bridged M 2 III compounds (M = Pr, Gd and Dy), the Dy 2 III analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets. This journal is © 2012 The Royal Society of Chemistry.
New 3d–4f supramolecular systems constructed by [Fe(bipy)(CN)4]− and partially blocked lanthanide cations
2009
Abstract The reaction of acetonitrile (1–5) and mixed acetonitrile/water 1:1 (6–9) solutions containing the cyanide-bearing [Fe(bipy)(CN)4]− building block (bipy = 2,2′-bipyridine) and the partially blocked [Ln(bpym)]3+ cation (Ln = lanthanide trivalent cation and bpym = 2,2′-bipyrimidine) has afforded two new families of 3d–4f supramolecular assemblies of formula [Ln(bpym)(NO3)2(H2O)3][Fe(bipy)(CN)4] · H2O · CH3CN [Ln = Sm (1), Gd (2), Tb (3), Dy (4) and Ho (5)] and [Ln(bpym)(NO3)2(H2O)4][Fe(bipy)(CN)4] [Ln = Pr (6), Nd (7), Sm (8), Gd (9)]. They crystallize in the P21/c (1–5) and P2/c (6–9) space groups and their structures are made up of [Fe(bipy)(CN)4]− anions (1–9) and [Ln(bpym)(NO3)2(…
Structural versatility in cobalt(ii) complexes with 1,2,4,5-benzenetetracarboxylic acid (H4bta) and 4,4′-bipyridine-N,N′-dioxide (dpo)
2007
Four new high-spin cobalt(II) complexes of formula [Co(H2O)6](H2bta)·dpo·4H2O (1), [{Co(H2O)4(dpo)}2(bta)]·4H2O·(2), [Co(H2O)2)(dpo)2(H2bta)]n (3) and [Co(H2O)3(dpo)(bta)1/2]n (4) (H4bta = 1,2,4,5-benzenetetracarboxylic acid and dpo = 4,4′-bipyridine-N,N′-dioxide) have been synthesized and their structures solved by single crystal X-ray diffraction methods. Compound 1 is an ionic salt whose structure is made up of [Co(H2O)6]2+ cations, H2bta2− anions, uncoordinated dpo groups and crystallization water molecules, which are linked by extensive hydrogen bonds to afford a three-dimensional network. The structure of 2 consists of bta-bridged dinuclear cobalt(II) complexes where four coordinated …
A three-dimensional copper(ii) 12-metallacrown-4 complex with malonomonohydroxamic acid (H3mmh) as a ligand
2011
Slow diffusion of an ethanolic solution of copper(ii) into an aqueous solution of partially deprotonated malonodihydroxamic acid (H4mdh) affords the pentanuclear complex of formula {[K(H2O) 2]2[Cu5(mmh)4]}n (1) (H3mmh = malonomonohydroxamic acid) which is formed by 12-MC-4 metallacrown units with the fifth copper(ii) ion being placed at the center of the square metallacrown unit. The dianionic pentacopper(ii) planar entity interacts with diaquapotassium(i) counterions through the carboxylate-oxygen atoms resulting in a neutral three-dimensional structure. Magnetic susceptibility measurements in the temperature range 1.9-300 K for 1 show the occurrence of relatively strong antiferromagnetic …
Postsynthetic Improvement of the Physical Properties in a Metal-Organic Framework through a Single Crystal to Single Crystal Transmetallation
2015
As ingle crystal to single crystal transmetallation process takes place in the three-dimensional (3D) metal- organic framework (MOF) of formula Mg II 2{Mg II 4(Cu II 2- (Me3mpba)2)3}·45 H2 O( 1 ;M e 3mpba 4¢ = N,N'-2,4,6-trimethyl- 1,3-phenylenebis(oxamate)). After complete replacement of the Mg II ions within the coordination network and those hosted in the channels by either Co II or Ni II ions, 1 is transmetallated to yield two novel MOFs of formulae Co2 II {Co II 4(Cu II 2(Me3- mpba)2)3}·56 H2 O( 2 )a nd Ni2 II {Ni II 4(Cu II 2(Me3mpba)2)3}· 54 H2 O( 3). This unique postsynthetic metal substitution affords materials with higher structural stability leading to enhanced gas sorption and m…
Cobalt(II) Sheet-Like Systems Based on Diacetic Ligands: from Subtle Structural Variances to Different Magnetic Behaviors
2009
The preparation, X-ray crystallography, and magnetic investigation of the compounds [Co(H(2)O)(2)(phda)](n) (1), [Co(phda)](n) (2), and [Co(chda)](n) (3) [H(2)phda = 1,4-phenylenediacetic acid and H(2)chda = 1,1-cyclohexanediacetic acid] are described herein. The cobalt atoms in this series are six- (1) and four-coordinated (2 and 3) in distorted octahedral (CoO(6)) and tetrahedral (CoO(4)) environments. The structures of 1-3 consists of rectangular-grids which are built up by sheets of cobalt atoms linked through anti-syn carboxylate bridges, giving rise to either a three-dimensional structure across the phenyl ring (1 and 2) or to regularly stacked layers with the cyclohexyl groups acting…
Syntheses, crystal structures and magnetic properties of five new manganese(ii) complexes: Influence of the conformation of different alkyl/aryl subs…
2014
et al.
Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.
2021
Following the synthesis of hydroxamate titanium–organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium–organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g–1.
Unprecedented coexistence of cyano-bridged Mn4(III)Cr(III) and Mn2(III)Cr(III) heterobimetallic complexes in one single crystal.
2008
The penta-[{MnIII(4-MeO-salen)(H2O)(micro-CN)}4CrIII(CN)2]+ and trinuclear [{MnIII(4-MeO-salen)(H2O)(micro-CN)}2CrIII(CN)4](-) units coexist in 1 with weak antiferromagnetic interactions which are overcome by a dc magnetic field of 2.5 T.
A novel oxalate-based three-dimensional coordination polymer showing magnetic ordering and high proton conductivity
2017
A novel three-dimensional (3D) coordination polymer with the formula (C3N2H5)4[MnCr2(ox)6]·5H2O (2), where ox = oxalate and C3N2H5 = imidazolium cation, is reported. Single crystal X-ray diffraction reveals that this porous coordination polymer adopts a chiral three-dimensional quartz-like architecture, with the guest imidazolium cations and water molecules being hosted in its pores. This novel multifunctional material exhibits both a ferromagnetic ordering at TC = 3.0 K, related to the host MnCr2 network, and high proton conductivity [1.86 × 10−3 S cm−1 at 295 K and 88% relative humidity (RH)] due to the presence of the acidic imidazolium cations and free water molecules. The similarity of…
Synthesis, crystal structure and magnetic characterization of a series of CuII-LnIII heterometallic [Ln = La, Ce, Pr, Nd and Sm) metal-organic compou…
2013
The synthesis and structural characterization of five Cu(II)-Ln(III) heteronuclear metal-organic frameworks of formula {[Ln4Cu 4(H2O)26(bta)5]·mH 2O}n and {[Ln4Cu4(H 2O)24(bta)5]·pH2O} n [Ln = LaIII (1A/1B), CeIII (2A/2B), Pr III (3A/3B), NdIII (4A/4B) and SmIII (5A/5B) with m/p = 20 (1A)/16 (1B), 18 (2A)/16 (2B), 14 (3A)/16 (3B), 22 (4A)/16 (4B) and 21 (5A)/14 (5B); H4bta =1,2,4,5-benzenetetracarboxylic acid (1-5)] have been performed. These compounds present a single-crystal to single-crystal phase transition from expanded A phases toward the B shrinking networks, which is triggered only in the presence of a dry environment. This phase transition is accompanied by a compression of the cry…
Synthesis, crystal structure and magnetic properties of the cyclic tetranuclear compound [Cu4(pz)4(hppa)2(H2O)4] [pz = pyrazolate; hppa = R,S-2-hydro…
2019
Abstract The synthesis, X-ray structure and magnetic properties of the neutral tetranuclear copper(II) complex of formula [Cu4(pz)4(hppa)2(H2O)4] (1) [Hpz = pyrazole and hppa = R,S-2-hydroxo-2-phenyl-2-(1-pyrazolyl)acetate] are reported. Remarkably, the structure of 1 reveals the presence of the S- and R-forms of the new hppa ligand which is formed in situ in the complex reaction between copper(II), pyrazole and phenylmalonate in water:methanol solvent mixture under ambient conditions. The two crystallographically independent copper(II) ions [Cu(1)/Cu(2)] are five-coordinate in square pyramidal surroundings. Three nitrogen atoms, from two pz groups and one hppa ligand and one oxygen atom of…
[MIII(bpym)(CN)4]−: a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym = 2,2′-bypyrimidine)
2008
Two cyano-bridged M(III)Mn(III) [M = Fe () and Cr ()] ferrimagnetic chains are reported; exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the overcoming by the applied dc field of the inter- and intrachain magnetic interactions, respectively.
Influence of the coligand in the magnetic properties of a series of copper(ii)–phenylmalonate complexes
2014
This work presents a series of layered systems based on phenylmalonate-containing copper(II) complexes and different coligands. Eight compounds [Cu(L)(Phmal)]n where L = pyrimidine (pym, 1) pyrazine (pyz, 2), 3-cyanopyridine (3-CNpy, 3), 4-cyanopyridine (4-CNpy, 4), 3-fluoropyridine (3-Fpy, 5), 3-chloropyridine (3-Clpy, 6), 3-bromopyridine (3-Brpy, 7) and 3-iodopyridine (3-Ipy, 8), have been synthesized and magneto-structurally characterized. The coligands selected not only modify the coordination environment of the metal ion, blocking or extending the polymerization, but also interact with the phenyl ring of the phenylmalonate ligand and dramatically affect the crystal packing through weak…
Tuning the Spin Ground State in Heterononanuclear Nickel(II)−Copper(II) Cylinders with a Triangular Metallacyclophane Core
2010
3 páginas, 2 figuras, 1 gráfico.-- et al.
Synthesis, structural analysis, and thermal and spectroscopic studies of methylmalonate-containing zinc(II) complexes
2012
The synthesis, crystal structure, thermal analysis and spectroscopic studies of five zinc(II) complexes of formulae [Zn(Memal)(H2O)]n (1) and [Zn2(L)(Memal)2(H2O)2]n (2-5) [H2Memal = methylmalonic acid, and L = 4,4′-bipyridine (4,4′-bpy) (2), 1,2-bis(4-pyridyl)ethylene (bpe) (3), 1,2-bis(4-pyridyl)ethane (bpa) (4) and 4,4′-azobispyridine (azpy) (5)] are presented here. The crystal structure of 1 is a three-dimensional arrangement of zinc(II) cations interconnected by methylmalonate groups adopting the μ3-κ2O:κO’:κO”:κO”’ coordination mode to afford a rare (10,3)-d utp-network. The structures of the compounds 2-5 are also three-dimensional and they consist of corrugated square layers of meth…
Novel cobalt(II) coordination polymers based on 1,2,4,5-benzenetetracarboxylic acid and extended bis-monodentate ligands
2009
Four new high-spin cobalt(II) complexes of formulae [Co2(bta)(4,4′-bpy)2(H2O)2]n (1), {Hbpe[Co(Hbta)(bpe)(H2O)2]}n (2), {[Co(H2bta)(azpy)(H2O)2]·azpy}n (3) and {[Co2(bta)(bpa)2(H2O)4]·8H2O}n (4) with H4bta = 1,2,4,5-benzenetetracarboxylic acid, 4,4′-bpy = 4,4′-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethene, azpy = 4,4′-azobispyridine and bpa = trans-1,2-bis(4-pyridyl)ethane, have been prepared and characterized by single crystal X-ray diffraction. Compounds 1–4 exhibit two-dimensional networks where the fully (1 and 4) or partially (2 and 3) deprotonated tetracarboxylic ligand connects two (2 and 3) or four (1 and 4) cobalt(II) ions through two trans-carboxylate (1–3) or all the carboxyla…
Magnetic coupling in discrete cyano-bridged Mn(III)-Fe(III) motifs: synthesis, crystal structure, magnetic properties and theoretical study.
2010
The preparation, crystal structures and magnetic properties of the heterobimetallic complexes of formula [Mn(III)(n-MeOsalen)(H(2)O)(mu-CN)Fe(III)(bpym)(CN)(3)]·mH(2)O with n = m = 3 (1) and n = 4 and m = 2 (2) [n-MeOsalen(2-) = N,N'-ethylenebis(n-methoxysalicylideneiminate) dianion and bpym = 2,2'-bipyrimidine] are reported. 1 and 2 are dinuclear neutral species where the cyano-bearing low-spin unit [Fe(III)(bpym)(CN)(4)](-) acts as a monodentate ligand towards the [Mn(III)(SB)(solv)(x)](+) entity (SB = tetradentate Schiff-base) through one of its four cyano groups. Adjacent heterobimetallic units are interlinked through hydrogen bonds involving the coordinated water molecule of one dinucl…
Long-distance magnetic coupling in dinuclear copper(II) complexes with oligo-para-phenylenediamine bridging ligands
2010
Abstract Two novel dinuclear copper(II) complexes of formulae [Cu2(tren)2(bpda)](ClO4)4 (2) and [Cu2(tren)2(tpda)](ClO4)4 (3) containing the tripodal tris(2-aminoethyl)amine (tren) terminal ligand and the 4,4′-biphenylenediamine (bpda) and 4,4″-p-terphenylenediamine (tpda) bridging ligands have been synthesized and structurally, spectroscopically, and magnetically characterized. Their experimentally available electronic spectroscopic and magnetic properties have been reasonably reproduced by DFT and TDDFT calculations. Single crystal X-ray diffraction analysis of 2 shows the presence of dicopper(II) cations where the bpda bridging ligand adopts a bismonodentate coordination mode toward two …
Two-Dimensional 3d–4f Heterometallic Coordination Polymers: Syntheses, Crystal Structures, and Magnetic Properties of Six New Co(II)–Ln(III) Compounds
2014
Six new heterometallic cobalt(II)-lanthanide(III) complexes of formulas [Ln(bta)(H2O)2]2[Co(H2O) 6]·10H2O [Ln = Nd(III) (1) and Eu(III) (2)] and [Ln2Co(bta)2(H2O)8] n·6nH2O [Ln = Eu(III) (3), Sm(III) (4), Gd(III) (5), and Tb(III) (6)] (H4bta = 1,2,4,5-benzenetretracaboxylic acid) have been synthesized and characterized via single-crystal X-ray diffraction. 1 and 2 are isostructural compounds with a structure composed of anionic layers of [Ln(bta)(H2O)2]n n- sandwiching mononuclear [Co(H2O)6]2+ cations plus crystallization water molecules, which are interlinked by electrostatic forces and hydrogen bonds, leading to a supramolecular three-dimensional network. 3-6 are also isostructural compou…
Synthesis, crystal structure and magnetic properties of a new cyanide-bridged mixed-valence copper(I)/copper(II) clathrate
2013
A unique cyanide-bridge mixed-valence CuI/CuII clathrate of formula [CuI2(CN)3][{CuII(tren)}2(μ-CN)](CF3SO3)2 [tren = tris(2-aminoethyl)amine] containing cyanide-bridged [{CuII(tren)}2(μ-CN)]3 + binuclear cations stacked between anionic honeycomb layered copper(I) cyanide networks, was synthesized and structurally characterized by single crystal X-ray diffraction. Variable-temperature magnetic susceptibility studies showed that the cyanide bridge mediates a strong antiferromagnetic interaction between the copper(II) centers (J = − 160 cm− 1, the spin Hamiltonian being defined as H = − JSA⋅SB).
Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal-organic frameworks (M = Ca, Sr and Ba)
2012
The use of the mononuclear copper(ii) complex, [Cu II(Me 2pma) 2] 2- (Me 2pma = N-2,6-dimethylphenyloxamate), as a bis(bidentate) metalloligand toward solvated alkaline earth metal cations affords a new series of oxamato-bridged heterobimetallic two-dimensional compounds with mixed square-octagonal [Ca II 2Cu II 3] or square [M II 2Cu II 3] (M = Sr and Ba) layered structures of (4·82) and (44·62) net topologies, respectively. © 2012 The Royal Society of Chemistry.
The construction of open GdIII metal–organic frameworks based on methanetriacetic acid: New objects with an old ligand
2010
11 páginas, 11 figuras, 2 esquemas.-- et al.
CCDC 1030505: Experimental Crystal Structure Determination
2015
Related Article: Thais Grancha, Jesús Ferrando-Soria, Hong-Cai Zhou, Jorge Gascon, Beatriz Seoane, Jorge Pasán, Oscar Fabelo, Miguel Julve and Emilio Pardo|2015|Angew.Chem.,Int.Ed.|54|6521|doi:10.1002/anie.201501691
CCDC 294297: Experimental Crystal Structure Determination
2016
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CCDC 983489: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado, Juan Rodríguez-Carvajal, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|5674|doi:10.1021/ic500443t
CCDC 941373: Experimental Crystal Structure Determination
2013
Related Article: Thais Grancha, Clarisse Tourbillon, Jesús Ferrando-Soria, Miguel Julve, Francesc Lloret, Jorge Pasán, Catalina Ruiz-Pérez, Oscar Fabelo, Emilio Pardo|2013|CrystEngComm|15|9312|doi:10.1039/C3CE41022F
CCDC 294298: Experimental Crystal Structure Determination
2016
Related Article: Fernando S. Delgado, Pablo Lorenzo-Luís, Jorge Pasán, Laura Cañadillas-Delgado, Oscar Fabelo, María Hernández-Molina, Antonio D. Lozano-Gorrín, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2016|CrystEngComm|18|7831|doi:10.1039/C6CE01360K
CCDC 1555659: Experimental Crystal Structure Determination
2017
Related Article: Marta Mon, Julia Vallejo, Jorge Pasán, Oscar Fabelo, Cyrille Train, Michel Verdaguer, Shin-ichi Ohkoshi, Hiroko Tokoro, Kosuke Nakagawa, Emilio Pardo|2017|Dalton Trans.|46|15130|doi:10.1039/C7DT03415F
CCDC 919615: Experimental Crystal Structure Determination
2013
Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B
CCDC 958829: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 958833: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 2106824: Experimental Crystal Structure Determination
2021
Related Article: Bele��n Lerma-Berlanga, Javier Castells-Gil, Carolina R. Ganivet, Neyvis Almora-Barrios, Javier Gonza��lez-Platas, Oscar Fabelo, Natalia M. Padial, Carlos Marti��-Gastaldo|2021|J.Am.Chem.Soc.|143|21195|doi:10.1021/jacs.1c09278
CCDC 984262: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582
CCDC 1030506: Experimental Crystal Structure Determination
2015
Related Article: Thais Grancha, Jesús Ferrando-Soria, Hong-Cai Zhou, Jorge Gascon, Beatriz Seoane, Jorge Pasán, Oscar Fabelo, Miguel Julve and Emilio Pardo|2015|Angew.Chem.,Int.Ed.|54|6521|doi:10.1002/anie.201501691
CCDC 958838: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 2106822: Experimental Crystal Structure Determination
2021
Related Article: Bele��n Lerma-Berlanga, Javier Castells-Gil, Carolina R. Ganivet, Neyvis Almora-Barrios, Javier Gonza��lez-Platas, Oscar Fabelo, Natalia M. Padial, Carlos Marti��-Gastaldo|2021|J.Am.Chem.Soc.|143|21195|doi:10.1021/jacs.1c09278
CCDC 937587: Experimental Crystal Structure Determination
2014
Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H
CCDC 984263: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582
CCDC 919613: Experimental Crystal Structure Determination
2013
Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B
CCDC 945084: Experimental Crystal Structure Determination
2013
Related Article: Laura Cañadillas-Delgado , Oscar Fabelo , J. Alberto Rodríguez-Velamazán , Marie-Hélène Lemée-Cailleau , Sax A. Mason , Emilio Pardo , Francesc Lloret , Jiong-Peng Zhao , Xian-He Bu , Virginie Simonet , Claire V. Colin , and Juan Rodríguez-Carvajal|2012|J.Am.Chem.Soc.|134|19772|doi:10.1021/ja3082457
CCDC 937589: Experimental Crystal Structure Determination
2014
Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H
CCDC 1045153: Experimental Crystal Structure Determination
2015
Related Article: Jesús Ferrando-Soria, Oscar Fabelo, María Castellano, Joan Cano, Stephen Fordham, Hong-Cai Zhou|2015|Chem.Commun.|51|13381|doi:10.1039/C5CC03544A
CCDC 984264: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582
CCDC 958834: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 937590: Experimental Crystal Structure Determination
2014
Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H
CCDC 958835: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 1030504: Experimental Crystal Structure Determination
2015
Related Article: Thais Grancha, Jesús Ferrando-Soria, Hong-Cai Zhou, Jorge Gascon, Beatriz Seoane, Jorge Pasán, Oscar Fabelo, Miguel Julve and Emilio Pardo|2015|Angew.Chem.,Int.Ed.|54|6521|doi:10.1002/anie.201501691
CCDC 2023345: Experimental Crystal Structure Determination
2021
Related Article: Belén Lerma-Berlanga, Carolina R. Ganivet, Neyvis Almora-Barrios, Sergio Tatay, Yong Peng, Josep Albero, Oscar Fabelo, Javier González-Platas, Hermenegildo García, Natalia M. Padial, Carlos Martí-Gastaldo|2021|J.Am.Chem.Soc.|143|1798|doi:10.1021/jacs.0c09015
CCDC 919614: Experimental Crystal Structure Determination
2013
Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B
CCDC 1475076: Experimental Crystal Structure Determination
2016
Related Article: Fernando S. Delgado, Pablo Lorenzo-Luís, Jorge Pasán, Laura Cañadillas-Delgado, Oscar Fabelo, María Hernández-Molina, Antonio D. Lozano-Gorrín, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2016|CrystEngComm|18|7831|doi:10.1039/C6CE01360K
CCDC 937591: Experimental Crystal Structure Determination
2014
Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H
CCDC 958832: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 945083: Experimental Crystal Structure Determination
2013
Related Article: Laura Cañadillas-Delgado , Oscar Fabelo , J. Alberto Rodríguez-Velamazán , Marie-Hélène Lemée-Cailleau , Sax A. Mason , Emilio Pardo , Francesc Lloret , Jiong-Peng Zhao , Xian-He Bu , Virginie Simonet , Claire V. Colin , and Juan Rodríguez-Carvajal|2012|J.Am.Chem.Soc.|134|19772|doi:10.1021/ja3082457
CCDC 937588: Experimental Crystal Structure Determination
2014
Related Article: Mariadel Déniz, Irene Hernández-Rodríguez, Jorge Pasán, Oscar Fabelo, Laura Cañadillas-Delgado, Julia Vallejo, Miguel Julve, Francesc Lloret, Catalina Ruiz-Pérez|2014|CrystEngComm|16|2766|doi:10.1039/C3CE42086H
CCDC 294299: Experimental Crystal Structure Determination
2016
Related Article: Fernando S. Delgado, Pablo Lorenzo-Luís, Jorge Pasán, Laura Cañadillas-Delgado, Oscar Fabelo, María Hernández-Molina, Antonio D. Lozano-Gorrín, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2016|CrystEngComm|18|7831|doi:10.1039/C6CE01360K
CCDC 958831: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 984260: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582
CCDC 903521: Experimental Crystal Structure Determination
2013
Related Article: Diana Visinescu, Luminita Marilena Toma, Oscar Fabelo, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve|2013|Inorg.Chem.|52|1525|doi:10.1021/ic302278q
CCDC 958836: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 903522: Experimental Crystal Structure Determination
2013
Related Article: Diana Visinescu, Luminita Marilena Toma, Oscar Fabelo, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve|2013|Inorg.Chem.|52|1525|doi:10.1021/ic302278q
CCDC 2106823: Experimental Crystal Structure Determination
2021
Related Article: Bele��n Lerma-Berlanga, Javier Castells-Gil, Carolina R. Ganivet, Neyvis Almora-Barrios, Javier Gonza��lez-Platas, Oscar Fabelo, Natalia M. Padial, Carlos Marti��-Gastaldo|2021|J.Am.Chem.Soc.|143|21195|doi:10.1021/jacs.1c09278
CCDC 952343: Experimental Crystal Structure Determination
2013
Related Article: Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Pau Díaz-Gallifa, Catalina Ruiz-Pérez, Francesc Lloret, Miguel Julve, Inés Puente Orench, Javier Campo, and Juan Rodríguez-Carvajal|2013|Inorg.Chem.|52|12818|doi:10.1021/ic402186p
CCDC 903520: Experimental Crystal Structure Determination
2013
Related Article: Diana Visinescu, Luminita Marilena Toma, Oscar Fabelo, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve|2013|Inorg.Chem.|52|1525|doi:10.1021/ic302278q
CCDC 1555658: Experimental Crystal Structure Determination
2017
Related Article: Marta Mon, Julia Vallejo, Jorge Pasán, Oscar Fabelo, Cyrille Train, Michel Verdaguer, Shin-ichi Ohkoshi, Hiroko Tokoro, Kosuke Nakagawa, Emilio Pardo|2017|Dalton Trans.|46|15130|doi:10.1039/C7DT03415F
CCDC 984265: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582
CCDC 903519: Experimental Crystal Structure Determination
2013
Related Article: Diana Visinescu, Luminita Marilena Toma, Oscar Fabelo, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve|2013|Inorg.Chem.|52|1525|doi:10.1021/ic302278q
CCDC 2023346: Experimental Crystal Structure Determination
2021
Related Article: Bel��n Lerma-Berlanga, Carolina R. Ganivet, Neyvis Almora-Barrios, Sergio Tatay, Yong Peng, Josep Albero, Oscar Fabelo, Javier Gonz��lez-Platas, Hermenegildo Garc��a, Natalia M. Padial, Carlos Mart��-Gastaldo|2021|J.Am.Chem.Soc.|143|1798|doi:10.1021/jacs.0c09015
CCDC 958837: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 945082: Experimental Crystal Structure Determination
2013
Related Article: Laura Cañadillas-Delgado , Oscar Fabelo , J. Alberto Rodríguez-Velamazán , Marie-Hélène Lemée-Cailleau , Sax A. Mason , Emilio Pardo , Francesc Lloret , Jiong-Peng Zhao , Xian-He Bu , Virginie Simonet , Claire V. Colin , and Juan Rodríguez-Carvajal|2012|J.Am.Chem.Soc.|134|19772|doi:10.1021/ja3082457
CCDC 984261: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado , Francesc Lloret , Miguel Julve , and Catalina Ruiz-Pérez|2014|Inorg.Chem.|53|6299|doi:10.1021/ic5008582
CCDC 958830: Experimental Crystal Structure Determination
2014
Related Article: Pau Díaz-Gallifa, Oscar Fabelo, Laura Cañadillas-Delgado, Jorge Pasán, Ana Labrador, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez|2013|Cryst.Growth Des.|13|4735|doi:10.1021/cg4008679
CCDC 919612: Experimental Crystal Structure Determination
2013
Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B