6533b7d5fe1ef96bd1263f0e

RESEARCH PRODUCT

Separation of atomic and molecular ions by ion mobility with an RF carpet

Paul ConstantinEmma HaettnerHans GeisselTimo DickelChristine HornungJulian BergmannSamuel Ayet San AndrésJ. EbertS. PurushothamanAnn-kathrin RinkMoritz P. ReiterMoritz P. ReiterWayne LippertIsrael MardorWolfgang R. PlaßHelmut WeickFlorian GreinerIain MooreChristoph ScheidenbergerIvan Miskun

subject

low-energy RIBPhysics - Instrumentation and DetectorsOrders of magnitude (temperature)beam purificationFOS: Physical sciences010402 general chemistrynucl-ex01 natural sciences530Ionmenetelmätion mobilityIonizationMoleculeddc:530Physical and Theoretical ChemistryfysiikkaNuclear Experiment (nucl-ex)Nuclear ExperimentInstrumentationphysics.ins-detSpectroscopyIon transporterRange (particle radiation)ionitChemistry010401 analytical chemistryExtraction (chemistry)gas cellpuhdistusInstrumentation and Detectors (physics.ins-det)Condensed Matter Physics0104 chemical sciencesmolecular contaminationBeamlinespace chargeAtomic physicserottaminen (tekniikka)epäpuhtaudet

description

Gas-filled stopping cells are used at accelerator laboratories for the thermalization of high-energy radioactive ion beams. Common challenges of many stopping cells are a high molecular background of extracted ions and limitations of extraction efficiency due to space-charge effects. At the FRS Ion Catcher at GSI, a new technique for removal of ionized molecules prior to their extraction out of the stopping cell has been developed. This technique utilizes the RF carpet for the separation of atomic ions from molecular contaminant ions through their difference in ion mobility. Results from the successful implementation and test during an experiment with a 600~MeV/u $^{124}$Xe primary beam are presented. Suppression of molecular contaminants by three orders of magnitude has been demonstrated. Essentially background-free measurement conditions with less than $1~\%$ of background events within a mass-to-charge range of 25 u/e have been achieved. The technique can also be used to reduce the space-charge effects at the extraction nozzle and in the downstream beamline, thus ensuring high efficiency of ion transport and highly-accurate measurements under space-charge-free conditions.

10.1016/j.ijms.2020.116450https://www.pure.ed.ac.uk/ws/files/178567374/2007.14467v2.pdf