6533b82bfe1ef96bd128d629

RESEARCH PRODUCT

Production of negative osmium ions by laser desorption and ionization.

Volker SonnenscheinSebastian RaederDaniel Rodriguez RodriguezKlaus WendtAntonio M. LallenaKlaus BlaumHans-jürgen KlugeMichael Block

subject

Matrix-assisted laser desorption electrospray ionizationMaterials scienceThermal ionizationMass spectrometryIon sourceSoft laser desorptionlaw.inventionAtmospheric-pressure laser ionizationPhysics::Plasma PhysicsReflectronlawPhysics::Atomic and Molecular ClustersPhysics::Atomic PhysicsAtomic physicsInstrumentationAmbient ionization

description

The interest to produce negative osmium ions is manifold in the realm of high-accuracy ion trap experiments: high-resolution nearly Doppler-free laser spectroscopy, antihydrogen formation in its ground state, and contributions to neutrino mass spectrometry. Production of these ions is generally accomplished by sputtering an Os sample with Cs(+) ions at tens of keV. Though this is a well-established method commonly used at accelerators, these kind of sources are quite demanding and tricky to operate. Therefore, the development of a more straightforward and cost effective production scheme will be of benefit for ion trap and other experiments. Such a scheme makes use of desorption and ionization with pulsed lasers and identification of the ions by time-of-flight mass spectrometry. First investigations of negative osmium ion production using a pulsed laser for desorption and ionization and a commercial matrix-assisted laser desorption/ionization time-of-flight system for identification has demonstrated the suitability of this technique. More than 10(3) negative osmium ions per shot were registered after bombarding pure osmium powder with a 5 ns pulse width Nd:yttrium aluminum garnet laser. The limitation in the ion number was imposed by the detection limit of the microchannel plate detector.

10.1063/1.3276685https://pubmed.ncbi.nlm.nih.gov/20113087