Entropy and institutional theory

2022

PurposeOnce introduced and conceptualized as a factor that causes erosion and decay of social institutions and subsequent deinstitutionalization, the notion of entropy is at odds with predictions of institutional isomorphism and seems to directly contradict the tendency toward ever-increasing institutionalization. The purpose of this paper is to offer a resolution of this theoretical inconsistency by revisiting the meaning of entropy and reconceptualizing institutionalization from an information-theoretic point of view.Design/methodology/approachIt is a theoretical paper that offers an information perspective on institutionalization.FindingsA mistaken understanding of the nature and role of…

Possible paths to increase detection of child sexual abuse in child and adolescent psychiatry: a meta-synthesis of survivors’ and health professional…

2022

Background: Efforts are directed both towards prevention and early detection of Child sexual abuse (CSA). Yet, only about 50% of CSA survivors disclose before adulthood, and health professionals rarely are the first disclosure recipients. Increasing the detection rate of CSA within the context of Child and Adolescent Psychiatry (CAP) therefore represents a significant secondary prevention strategy. However, facilitating CSA disclosure when the survivor is reluctant to tell is a highly complex and emotionally demanding clinical task. We therefore argue that efforts to increase detection rates of CSA within CAP need to rest on knowledge of how both survivors and health professionals experienc…

Resilience and prosocial behaviour in Spanish care professionals of dependent persons

2022

Professional residential care providers face several stressors due to the burden of caring for dependent people. This burden may affect the way in which care is carried out. Resilience, as personal strengths, may help them to be more effective in their workplace and in their interaction with patients, and this may be related to the development of participation skills and prosocial behaviours. A total of 125 professional's caregivers from Spain responded to the Connor-Davidson Resilience Scale Resilience Scale and the PB new Prosocial Conduct Scale over the years 2018 and 2019. We checked the predictive power of resilience as well as other predictors (sex, type of contract and total months w…

Novel de novo missense mutation in the interferon regulatory factor 6 gene in an Italian infant with IRF6-related disorder

2022

Abstract Background Congenital maxillomandibular syngnathia is a rare craniofacial anomaly leading to difficulties in feeding, breathing and ability to thrive. The fusion may consist of soft tissue union (synechiae) to hard tissue union. Isolated cases of maxillomandibular fusion are extremely rare, it is most often syndromic in etiology. Case presentation Clinical management of a female newborn with oromaxillofacial abnormities (synechiae, cleft palate, craniofacial dysmorphisms, dental anomaly) and extraoral malformations (skinfold overlying the nails of both halluces, syndactyly, abnormal external genitalia) is presented. The associated malformations addressed to molecular genetic invest…

Starting high school? On the origins of secondary education in Spain, 1857–1901

2022

AbstractThe development of modern educational systems radically altered the way knowledge and skills were transmitted. Yet, while elementary schooling rapidly expanded in late 19th and early twentieth centuries, secondary education struggled to find its way. This was also the case in Spain where, despite a growing demand, the provision of public secondary education during the second half of the 19th century was rather limited. As a result, private education, and especially that promoted by the Church, rushed to fill in the gap. Using a new database with municipal-level data, we examine what drove the expansion of private schools. As expected, demand-pull factors were critical. Still, the in…

Effects of Difficulty in Handling Emotions and Social Interactions on Nomophobia: Examining the Mediating Role of Feelings of Loneliness

2022

Abstract This study was addressed to assess nomophobia in an Italian sample (N = 456, 53.1% men, Mage = 31.8, SD = 11.1), also providing a deeper knowledge about how it is distributed across demographics, as well as identifying its best predictors. The main goal was to investigate the direct and indirect effects of difficulty in emotion regulation and social interaction anxiety on nomophobia through loneliness. Our findings indicated that loneliness explained the effect of the expressive suppression strategy (fully) and social interaction anxiety (partially) on nomophobia, whereas it was not a significant mediator when the cognitive reappraisal strategy was taken into account. Our study sug…

Frailty trajectories in community‐dwelling older adults during COVID ‐19 pandemic: The PRESTIGE study

2022

Background Frailty has been recognized as potential surrogate of biological age and relevant risk factor for COVID-19 severity. Thus, it is important to explore the frailty trajectories during COVID-19 pandemic and understand how COVID-19 directly and indirectly impacts on frailty condition. Methods We enrolled 217 community-dwelling older adults with available information on frailty condition as assessed by multidimensional frailty model both at baseline and at one-year follow-up using Multidimensional Prognostic Index (MPI) tools. Pre-frail/frail subjects were identified at baseline as those with MPI score >0.33 (MPI grades 2-3). Frailty worsening was defined by MPI difference between …

Modeling bismuth insertion in 1D hybrid lead halide TMSO(Pb x Bi y )I3 pseudo-perovskites

2022

Abstract The structures of the disordered 1D (pseudo-)perovskites of general TMSO(Pb x Bi y )I3 formulation [TMSO = (CH3)3SO+], obtained by doping the TMSOPbI3 species with Bi3+ ions, are investigated through the formulation of a statistical model of correlated disorder, which addresses the sequences of differently occupied BI6 face-sharing octahedra (B = Pb, Bi or vacant site) within ideally infinite [(BI3)−] n chains. The x-ray diffraction patterns simulated on the basis of the model are matched to the experimental traces, which show many broad peaks with awkward (nearly trapezoidal) shapes, under the assumption that the charge balance is fully accomplished within each chain. The analysis…

Effects of Mediterranean Diet Combined with CrossFit Training on Trained Adults’ Performance and Body Composition

2022

CrossFit is a high-intensity training discipline increasingly practiced in recent years. Specific nutritional approaches are usually recommended to maximize performance and improve body composition in high-intensity training regimens; notwithstanding, to date there are no targeted nutritional recommendations for CrossFit athletes. The Mediterranean Diet (MD) is a diet approach with a well-designed proportion of macronutrients, using only available/seasonal food of the Mediterranean area, whose health benefits are well demonstrated. No studies have evaluated this dietary strategy among CrossFit athletes and practitioners; for this reason, we tested the effects of 8 weeks of MD on CrossFit at…

Cognitive and Academic Outcomes of Fundamental Motor Skill and Physical Activity Interventions Designed for Children with Special Educational Needs: …

2022

This systematic review aimed to investigate the methodological quality and the effects of fundamental motor skills and physical activity interventions on cognitive and academic skills in 3- to 7-year-old children with special educational needs. The review was reported in accordance with the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA 2020) statement. A literature search was carried out in April 2020 (updated in January 2022) using seven electronic databases, including ERIC, Scopus, Web of Science, PsycINFO, CINAHL, PubMed, and SPORTDiscus. The methodological quality of the studies was assessed with Effective Public Health Practice Project (EPHPP) Quality Asses…

Hybrid biocomposites based on polylactic acid and natural fillers from Chamaerops humilis dwarf palm and Posidonia oceanica leaves

2022

AbstractPlatelet-like and fibrous lignocellulosic fillers were achieved from the leaves of Chamaerops humilis (CHL) and Posidonia oceanica (POL) and used as a hybrid reinforcement for a polylactic acid (PLA) matrix at three different loading levels (from 5 to 20%). The materials were fully characterized from a morphological, physicochemical, mechanical, and dynamic-thermomechanical point of view. When compared to their counterpart containing either CHL or POL only, the resulting hybrid biocomposites showed the highest mechanical properties, with strengthening and stiffening effects respectively up to 120% and 50% higher than those expected from the linear combination of the two, and higher …

Inhalable Formulation Based on Lipid–Polymer Hybrid Nanoparticles for the Macrophage Targeted Delivery of Roflumilast

2022

Here, novel lipid-polymer hybrid nanoparticles (LPHNPs), targeted to lung macrophages, were realized as potential carriers for Roflumilast administration in the management of chronic obstructive pulmonary disease (COPD). To achieve this, Roflumilast-loaded fluorescent polymeric nanoparticles, based on a polyaspartamide-polycaprolactone graft copolymer, and lipid vesicles, made from 1,2-dipalmitoyl-sn-glycero-3-phosphocholine and 1,2-distearoyl-sn-glycero-phosphoethanolamine-N-(polyethylene glycol)-mannose, were properly combined using a two-step method, successfully obtaining Roflumilast-loaded hybrid fluorescent nanoparticles (Man-LPHFNPs@Roflumilast). These exhibit colloidal size and a ne…

Digital Documenting Practices : Collaborative Writing in Workplace Training

2022

The present article examines collaborative writing in organizational consulting and training, where writing takes place as part of a group discussion assignment and is carried out by using digital writing technologies. In the training, the groups use digital tablets as their writing device in order to document their answers in the shared digital platform. Using multimodal conversation analysis as a method, the article illustrates the way writing is interactionally accomplished in this setting where digital writing intertwines with face-to-face interaction as the groups jointly formulate a documentable written entry for specific institutional purposes. The results show how writing is manage…

Letter to the Editor. Idiopathic normal pressure hydrocephalus: is 1-year follow-up enough?

2022

The rationality of rainy day savers: objective and subjective determinants of individual savings in Britain

2022

Using the largest and richest data on savings in Great Britain, six waves of the Wealth and Assets Survey from the Office for National Statistics, we compare standard life cycle models of saving with models using more 'subjective' measures, and the added dimension of longitudinal data. Whilst the life cycle model provides a benchmark, regular criticisms remain, particularly people's propensity to continue saving at older ages. Data on attitudes attenuate that issue, and panel data largely eliminate it. Our results confirm empirically, for Great Britain, the importance of some of the objective determinants of savings included in life cycle theory. When we look at more subjective ones, we sho…

Habitar en la palabra. Rose Ausländer y la poesía después de Auschwitz

2022

Hay palabras que entrañan misteriosamente un destino. En el caso de Rose Ausländer (Czernowitz, 1901-Düsseldorf, 1988), el apellido libremente asumido tras un breve matrimonio parece unir el fatum personal con el del pueblo judío, la inveterada extranjería (Ausländer significa en alemán extranjero) de quien nunca habitó una patria (Vaterland) a la que pudiera llamar suya con el exilio ancestral de los hijos de Judá. Obligada a dolorosos desarraigos, Rose es consciente desde muy pronto de que 'Dios nos dio / la palabra / y nosotros habitamos / en la palabra', y que ésta es, frente a las movedizas fronteras trazadas por la arbitrariedad del poder terreno, el único locus del ser humano, su paí…

FitAik: a package to calculate least-square fitted atomic transitions probabilities. Application to the Er+ lanthanide ion

2022

We present a new method implemented in our new package \textit{FitAik}, to perform least-squares fitting of calculated and experimental atomic transition probabilities, by using the mono-electronic transition integrals $\langle n\ell |r| n'\ell' \rangle$ (with $r$ the electronic radial coordinate) as adjustable quantities. \textit{FitAik} is interfaced to the Cowan suite of codes, for which it automatically writes input files and reads output files. We illustrate our procedure with the example of Er$^{+}$ ion, for which the agreement between calculated and experimental Einstein coefficients is found to be very good. The source code of \emph{FitAik} can be found on GitLab, and the calculated…

The pandemic within the pandemic: the surge of neuropsychological disorders in Italian children during the COVID-19 era

2022

Abstract Background Quarantine and isolation measures during COVID-19 pandemic may have caused additional stress and challenged the mental health of the youth. Aim of the study is to investigate the COVID-19 pandemic impact on neuropsychological disorders (NPD) of Italian children and adolescents to provide general pediatric recommendations. Material and methods A retrospective multicenter observational study was planned by the Italian Pediatric Society (SIP) to explore the impact of COVID-19 on the access of children to pediatric Emergency Departments (pED) for the evaluation of neuropsychological symptoms, collecting the classification codes of diagnoses between March 1, 2019 and March 2,…

Neurological vertigo in the emergency room in pediatric and adult age: systematic literature review and proposal for a diagnostic algorithm.

2022

AbstractNeurological vertigo is a common symptom in children and adults presenting to the emergency department (ED) and its evaluation may be challenging, requiring often the intervention of different medical specialties. When vertigo is associated with other specific symptoms or signs, a differential diagnosis may be easier. Conversely, if the patient exhibits isolated vertigo, the diagnostic approach becomes complex and only through a detailed history, a complete physical examination and specific tests the clinician can reach the correct diagnosis. Approach to vertigo in ED is considerably different in children and adults due to the differences in incidence and prevalence of the various c…

A New Correlation Coefficient for T-Spherical Fuzzy Sets and Its Application in Multicriteria Decision-Making and Pattern Recognition

2022

The goal of this paper is to design a new correlation coefficient for T -spherical fuzzy sets (TSFSs), which can accurately measure the nature of correlation (i.e., positive and negative) as well as the degree of relationship between TSFS. In order to formulate our proposed idea, we had taken inspiration from the statistical concept of the correlation coefficient. While doing so, we firstly introduce the variance and covariance of two TSFS and then constructed our scheme using these two newly defined notions. The numerical value of our proposed correlation coefficient lies within the interval − 1 , + 1 , as it should be from a statistical point of view, whereas the existing methods cannot m…

The two-photon decay of X(6900) from light-by-light scattering at the LHC

2022

The LHCb Collaboration has recently discovered a structure around 6.9 GeV in the double-$J/\psi$ mass distribution, possibly a first fully-charmed tetraquark state $X(6900)$. Based on vector-meson dominance (VMD) such a state should have a significant branching ratio for decaying into two photons. We show that the recorded LHC data for the light-by-light scattering may indeed accommodate for such a state, with a $\gamma \gamma$ branching ratio of order of $10^{-4}$, which is larger even than the value inferred by the VMD. The spin-parity assignment $0^{-+}$ is in better agreement with the VMD prediction than $0^{++}$, albeit not significantly at the current precision. Further light-by-light…

Effect of different packaging methods on the free amino acid profiles of the deep-water rose shrimp (Parapenaeus longirostris) during frozen storage

2022

The composition of free amino acids (FAAs) in seafood products contributes to characterizing their flavor, as well as freshness and quality during storage. Deep-water rose shrimps (Parapenaues longirostris, Lucas, 1846) (DWRS) are being increasingly harvested in the Mediterranean Sea, and the captured specimens are quickly frozen onboard fishing trawlers to preserve freshness and post-harvest quality. Here, we quantified the FAA profiles of DWRS packaged using five methods: (1) 100% N2; (2) vacuum; (3) 50% N2 + 50% CO2; (4) commercial anhydrous sodium sulfite; and (5) air (control). All samples were quickly frozen at −35°C and stored for 12 months at −18°C. Arginine (661 mg/100 g), proline …

Nonlinear Robust Control of a Quadratic Boost Converter in a Wide Operation Range, Based on Extended Linearization Method

2022

This paper proposes a control system for a quadratic boost DC/DC converter in a wide range of operations, based on an inner loop with a sliding mode controller, for reaching a desired equilibrium state, and an outer loop with integral-type controller, for assuring robustness against load and input voltage variations and converter parameter uncertainties. The sliding mode controller is designed with the extended linearization method and assures local asymptotic stability, whereas the integral controller is designed using classical frequency methods, and assures input–output stability. It is shown that the proposed controller also deals with the sudden changes in the nominal operating conditi…

MIS-C and co-infection with P. vivax and P. falciparum in a child: a clinical conundrum.

2022

Abstract Background The ongoing Coronavirus Disease 2019 (COVID-19) epidemic represents an unprecedented global health challenge. Many COVID-19 symptoms are similar to symptoms that can occur in other infections. Malaria should always be considered in patients with SARS-CoV-2 infection returning from endemic areas. Case presentation We present the first case of multisystem inflammatory syndrome (MIS-C) and Plasmodium vivax-falciparum and SARS-CoV2 coinfection in children. Despite clearance of parassitaemia and a negative COVID-19 nasopharyngeal PCR, the patient’s clinical conditions worsened. The World Health Organization (WHO) criteria were used to make the diagnosis of MIS-C. Treatment wi…

Photobleaching and Recovery Kinetics of a Palette of Carbon Nanodots Probed by In Situ Optical Spectroscopy

2022

Carbon dots (CDs) are a family of fluorescent nanoparticles displaying a wide range of interesting properties, which make them attractive for potential applications in different fields like bioimaging, photocatalysis, and many others. However, despite many years of dedicated studies, wide variations exist in the literature concerning the reported photostability of CDs, and even the photoluminescence mechanism is still unclear. Furthermore, an increasing number of recent studies have highlighted the photobleaching (PB) of CDs under intense UV or visible light beams. PB phenomena need to be fully addressed to optimize practical uses of CDs and can also provide information on the fundamental m…

Movement characteristics during customized exergames after total knee replacement in older adults

2022

Introduction: There is limited understanding of how older adults can reach kinematic goals in rehabilitation while performing exergames and conventional exercises, and how similar or different the kinematics during exergaming are when compared with conventional therapeutic exercise with similar movement. The aim of this study was to describe the movement characteristics performed during exercise in custom-designed exergames and conventional therapeutic exercises among patients who have undergone unilateral total knee replacement (TKR). In addition, the secondary aim was to assess the relation of these exercise methods, and to assess participants' perceived exertion and knee pain during exer…

Role of thyroid hormones in burning mouth syndrome. Systematic review

2022

Background: Burning mouth syndrome is an idiopathic condition characterized by burning pain in a normalappearing oral mucosa lasting at least four to six months. In the case of secondary burning mouth syndrome is associated with local or systemic factors (such as thyroid disorders) that can cause these symptoms. The aim of this review was to study the relationship between thyroid disorders and burning mouth syndrome. Material and Methods: The present study followed the PRISMA guidelines. An electronic search strategy was developed for PubMed/Medline, Scopus and Cochrane. The following combination of keywords and Boolean operators were used: Thyroid AND burning mouth; Thyroid AND burning mou…

Acetic Acid Mediated for One-Pot Synthesis of Novel Pyrazolyl s-Triazine Derivatives for the Targeted Therapy of Triple-Negative Breast Tumor Cells (…

2022

Here, we described the synthesis of novel pyrazole-s-triazine derivatives via an easy one-pot procedure for the reaction of β-dicarbonyl compounds (ethylacetoacetate, 5,5-dimethyl-1,3-cyclohexadione or 1,3-cyclohexadionone) with N,N-dimethylformamide dimethylacetal, followed by addition of 2-hydrazinyl-4,6-disubstituted-s-triazine either in ethanol-acetic acid or neat acetic acid to afford a novel pyrazole and pyrazole-fused cycloalkanone systems. The synthetic protocol proved to be efficient, with a shorter reaction time and high chemical yield with broad substrates. The new pyrazolyl-s-triazine derivatives were tested against the following cell lines: MCF-7 (breast cancer); MDA-MB-231 (tr…

Effects of overnight military training and acute battle stress on the cognitive performance of soldiers in simulated urban combat

2022

Understanding the effect of stress, fatigue, and sleep deprivation on the ability to maintain an alert and attentive state in an ecologically valid setting is of importance as lapsing attention can, in many safety-critical professions, have devastating consequences. Here we studied the effect of close-quarters battle (CQ battle) exercise combined with overnight military training with sleep deprivation on cognitive performance, namely sustained attention and response inhibition. In addition, the effect of the CQ battle and overnight training on cardiac activity [heart rate and root mean square of the successive differences (RMSSD)] during the cognitive testing and the relationship between ca…

Examining the generalizability of research findings from archival data

2022

This research project benefitted from Ministry of Education (Singapore) Tier 1 Grant R-313-000-131-115 (to A. Delios), National Science Foundation of China Grants 72002158 (to H.T.) and 71810107002 (to H.T.), grants from the Knut and Alice Wallenberg Foundation (to A. Dreber) and the Marianne and Marcus Wallenberg Foundation (through a Wallenberg Scholar grant; to A. Dreber), Austrian Science Fund (FWF) Grant SFB F63 (to A. Dreber), grants from the Jan Wallander and Tom Hedelius Foundation (Svenska Handelsbankens Forskningsstiftelser; to A. Dreber), and an Research & Development (R&D) research grant from Institut Européen d'Administration des Affaires (INSEAD) (to E.L.U.). Dmitrii Dubrov, o…

Eternal versus singular observers in interacting dark-energy-dark-matter models

2022

Interacting dark-energy-dark-matter models have been widely analyzed in the literature in an attempt to find traces of new physics beyond the usual cosmological (ΛCDM) models. Such a coupling between both dark components is usually introduced in a phenomenological way through a flux in the continuity equation. However, models with a Lagrangian formulation are also possible. A class of the latter assumes a conformal/disformal coupling that leads to a fifth force on the dark-matter component, which consequently does not follow the same geodesics as the other (baryonic, radiation, and dark-energy) matter sources. Here we analyze how the usual cosmological singularities of the standard matter f…

An immunologist's guide to immunosenescence and its treatment

2022

Abstract Introduction: Aging causes several changes in the immune system, although immune aging is strongly influenced by individual immunological history, as well as genetic and environmental factors leading to inter-individual variability. Areas covered: We focused on the biological and clinical meaning of immunosenescence. SARS-CoV-2 and Yellow Fever vaccine have demonstrated the clinical relevance of immunosenescence, while inconsistent results, obtained from longitudinal studies aimed at looking for immune risk phenotypes, have revealed that immunosenescence is highly context-dependent. Large projects allowed the delineation of the drivers of immune system variance, including genetic a…

Unveiling the Chemistry of Higher-Order Cycloaddition Reactions within the Molecular Electron Density Theory

2022

The higher-order cycloaddition (HOCA) reaction of tropone with cyclopentadiene (Cp) has been studied within the Molecular Electron Density Theory. The Electron Localization Function (ELF) analysis of the electronic structure of tropone and Cp characterizes the structural behaviors of the two conjugated unsaturated systems, while the conceptual DFT reactivity indices classify tropone as a strong electrophile and Cp as a strong nucleophile participating in polar cycloaddition reactions of reverse electron density flux. Eight competitive reaction paths have been characterized for this cycloaddition reaction. The most favorable one allowing the formation of the formal out [6 + 4] cycloadduct ha…

Deconstruyendo la “peer-to-peer sharing economy”: El desafío de la “economía colaborativa” a las cooperativas de plataforma en la era del pos-trabajo…

2022

La denominada economía colaborativa o economía p2p, concepto multifacético de creciente relevancia, constituye nuestro objeto de estudio como resultante de la traducción del vocablo anglosajón “sharing economy”. El presente artículo se plantea metodológicamente como una revisión crítica y una síntesis de las principales tendencias de la economía del siglo XXI del principio del nuevo fenómeno del neo-capitalismo de plataformas digitales. Desde el marco de la contradicción tradicional de trabajo y capital, se realiza un análisis pormenorizado del concepto de “colaboración” como traducción de “sharing”. Se realiza una revisión cronológica de la literatura, identificando los principales trabajo…

Russian speakers’ media engagement and acculturation in Finland and Latvia

2022

AbstractThis comparative study looks into Russian speakers’ acculturation in Finland and Latvia by contrasting their cultural involvement and cultural preference Carlson and Güler (J Int Migr Integr 19:625–647, 2018. 10.1007/s12134-018-0554-4) with their self-reported news media use. Drawing on survey data collected from both countries (N = 224), the findings show that participants in both countries scored closer to biculturalism than monoculturalism. Majority of the respondents report predominantly engaging with non-Russian news media sources. However, regardless of the societal context, respondents who were more engaged with Russian news media sources also scored higher on cultural prefer…

The crucial interactions between climate and soil

2022

Since the birth of soil science, climate has been recognized as a soil-forming factor, along with parent rock, time, topography, and organisms (from which humans were later kept distinct), often prevalent on the other factors on the very long term. But the climate is in turns affected by soils and their management. This paper describes the interrelationships between climate – and its current change – and soil, focusing on each single factor of its formation. Parent material governs, primarily through the particle size distribution, the capacity of soil to retain water and organic matter, which are two main soil-related drivers of the climate. Time is the only unmanageable soil-forming facto…