showing 36 of ~574560 from 574555 documents
Recovery of dissolved methane through a flat sheet module with PDMS, PP, and PVDF membranes
2022
Abstract A degassing contactor using a flat sheet membrane module (FM) was operated in sweep gas mode to study the performance of several commercial polymer membranes, both dense (polydimethylsiloxane, PDMS) and microporous (polypropylene, PP, and polyvinylidenefluoride, PVDF), for the recovery of dissolved methane from water. Non-steady state experiments were conducted at different liquid (QL, 3.5–40.5 L h-1) and gas flow rates (QN2, 0.05–15.00 L h-1). In the case of PDMS, PP, and when PVDF was operated at moderate high QL (≥ 21 L h-1), similar methane removal efficiencies (RE) were obtained. In the case of PVDF operated at relatively low QL (3.5 L h-1), a lower RE was observed. A model fo…
Selective Acrolein Hydrogenation over Ligand-Protected Gold Clusters : A Venus Flytrap Mechanism
2022
The catalytic partial hydrogenation of α,β-unsaturated aldehydes is an ideal reaction to understand the selectivity between two different functional groups Here the two functional groups are C═C and C═O, and the hydrogenation of C═O is preferentially desired due to the importance of the issuing products, unsaturated alcohols, in fine-chemical industries. Using density functional theory calculations, we investigate the catalytic competency toward this reaction of a Au nanocluster in the presence of protecting ligands that offer higher stability and the possibility for the uniform distribution of size-selected clusters in the catalytic system. meta-Mercaptobenzoic-acid-protected-protected Au …
The quest for precision oncology with immune checkpoint inhibitors for hepatocellular carcinoma
2022
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Recensione a: La competenza esperta. Tipologie e trasmissione, Gianfranco Marrone et Tiziana Migliore (a cura di), Milan, Meltemi, 2021
2022
Review to: Expert competence. Types and transmission, Gianfranco Marrone and Tiziana Migliore (edited by), Milan, Meltemi
Ferrocene-functionalized anilines as potent anticancer and antidiabetic agents: Synthesis, spectroscopic elucidation, and DFT calculations
2022
Abstract Ferrocene derivatives have attracted significant interest as potent biological agents and novel drug candidates. Hence, the present research work was focused on the synthesis and characterization of ferrocene-integrated anilines (FB1-FB4) through different spectroscopic techniques such as: FT-IR, multinuclear (1H and 13C) NMR, Raman, atomic absorption spectroscopy, elemental analysis, and single-crystal X-ray crystallography. The crystallographic analysis revealed a supramolecular structure mediated by secondary non-covalent interactions (π—H and π—π). These ferrocenyl derivatives demonstrated a quasi-reversible electrochemical behavior with one electron transfer from Fe(II) to Fe(…
Pharmacological Neuroenhancement, Perceived Stress, and Resilience in Spine Surgeons–A Cross-Sectional Survey
2022
Background Spine surgeons are usually exposed to high workload and demanding work conditions. Although the relationship between pharmacological neuroenhancement (PNE) and resilience (i.e., the ability to recover from stress), as well as perceived stress and resilience-enhancing factors, has been investigated in the general population, less is known about the impact of those factors in spine surgeons. This study aimed to close that gap by investigating the relationship between PNE use and resilience, perceived stress, or resilience-enhancing factors in spine surgeons. Methods We conducted a cross-sectional survey in a sample of 582 spine surgeons in German-speaking countries (Austria, German…
Adapting to the pandemic: longitudinal effects of social restrictions on time perception and boredom during the Covid-19 pandemic in Germany
2022
AbstractWith the Covid-19 pandemic, many governments introduced nationwide lockdowns that disrupted people’s daily routines and promoted social isolation. We applied a longitudinal online survey to investigate the mid-term effects of the mandated restrictions on the perceived passage of time (PPT) and boredom during and after a strict lockdown in Germany. One week after the beginning of the lockdown in March 2020, respondents reported a slower PPT and increased boredom compared to the pre-pandemic level. However, in the course of the lockdown, PPT accelerated and boredom decreased again until August 2020. Then, in October 2020, when incidence rates sharply rose and new restrictions were int…
Principio di non incriminazione della vittima di tratta autore di reato e obblighi di tutela ai sensi dell'art. 4 Cedu. Primi chiarimenti dalla Corte…
2022
Per la prima volta, la Corte europea dei diritti dell’uomo (Corte EDU) è chiamata a decidere se, ed entro quali limiti, un ordinamento che non rispetta il principio di non-incriminazione della vittima di tratta (VDT) per i reati da questa commessi violi o meno il divieto di schiavitù e di lavoro forzato stabilito dall’art. 4 della Convezione europea dei diritti dell’uomo (CEDU). Che il principio di non incriminazione abbia trovato tutela convenzionale soltanto sotto un profilo procedimentale, e non anche sostanziale, può a prima vista deludere le aspettative di chi ne auspica ormai da tempo un’ampia attuazione. Non può però escludersi che sia proprio sul piano della tutela procedimentale, d…
Assessing and modeling nitrite inhibition in microalgae-bacteria consortia for wastewater treatment by means of photo-respirometric and chlorophyll f…
2022
Abstract Total nitrite (TNO2 = HNO2 + NO−2) accumulation due to the activity of ammonia-oxidizing bacteria (AOB) was monitored in microalgae-bacteria consortia, and the inhibitory effect of nitrite/free nitrous acid (NO2-N/FNA) on microalgae photosynthesis and inhibition mechanism was studied. A culture of Scenedesmus was used to run two sets of batch reactors at different pH and TNO2 concentrations to evaluate the toxic potential of NO2-N and FNA. Photo-respirometric tests showed that NO2-N accumulation has a negative impact on net oxygen production rate (OPRNET). Chlorophyll a fluorescence analysis was used to examine the biochemical effects of NO2-N stress and the mechanism of NO2-N inhi…
An unusual conchorhynch from the upper Maastrichtian of the southeast Netherlands and the distinction between nautiloid and ammonoid conchorhynchs (M…
2022
Abstract A single, atypical conchorhynch (calcitic tip of a cephalopod lower jaw), recovered from the uppermost Meerssen Member (Maastricht Formation, upper Maastrichtian) at the former ENCI-HeidelbergCement Group quarry, south of Maastricht, is described as a new parataxon, Conchorhynchus illustris sp. nov. The specimen can be differentiated from all previous conchorhynch records on account of its large size, elongated shape and, in particular, of the structure of its apical part which is smooth and forwardly elongated. During the Late Cretaceous, conchorhynchs formed part of the jaw apparatus of nautilids and of two ammonoid suborders, Phylloceratina and Lytoceratina. Since conchorhynchs …
Potential of phosphonium-based ionic liquids to purify 1-propanol from water by liquid–liquid extraction at mild conditions
2022
Abstract In order to reduce the environmental of the separation of 1-propanol from water in a residual industry stream for its reuse, the capability as solvents of two different trihexyl(tetradecyl)phosphonium ionic liquids (ILs) – trihexyl(tetradecyl)phosphonium chloride ([TDTHP][Cl]) and trihexyl(tetradecyl)phosphonium bromide ([TDTHP][Br])-, was studied. The liquid–liquid equilibria data for both ternary systems, {water + 1-propanol + [TDTHP][Cl]} and {water + 1-propanol + [TDTHP][Br]} at different mild work temperatures, (283.2, 303.2 and 323.2) K, and atmospheric pressure were measured. The thermodynamic parameters for both ternary systems at different work conditions were obtained by …
Endoscopic training during fellowship: A nationwide French study
2022
ABSTRACT Background In France, it is mandatory that gastroenterology fellows have mastered the basic level of endoscopy by the end of training. The aim of this study was to assess improvement in the quality of fellows’ endoscopy training in France during the last four years. Methods All fellows in France in training were eligible for participation. A 21-item questionnaire was sent out. The primary outcome was the completion by fourth year fellows of all the number of procedures recommended. Results were compared with those of a 2016 survey. Results Two-hundred-and-sixty-five fellows responded to the survey. The participation rate was 47.0%. The mean age was 27.3 ± 1.0 years and 56.4% were f…
Stairway to organic heaven: The impact of social and temporal distance in print ads
2022
Abstract Multiple studies employ consumers’ intentions rather than actual purchases when assessing organic food consumption. These studies typically suggest a green bias in organic market share. Employing reactance and construal level theory, this research investigates the impact of one’s social distance to the character depicted in ads (animal vs. human) and the temporal distance (present vs. future) toward organic animal husbandry on consumers’ purchase responses directly; indirectly, as related to the portrayed character; and generally to organic foods. Three 2 (temporal distance: low, high) × 2 (social distance: low, high) between-subjects experiments demonstrate that low social distanc…
Corylus avellana: A Source of Diarylheptanoids With α-Glucosidase Inhibitory Activity Evaluated by in vitro and in silico Studies
2022
Corylus avellana hard shells, green leafy involucres, leaves, and male flowers have shown to be a source of diarylheptanoids, a class of natural products with promising biological activities. Cyclic diarylheptanoids, named giffonins, were isolated from the Italian cultivar “Tonda di Giffoni.” Even if many efforts have been made to establish the chemistry of these compounds, little is known about their biological properties. Herein, the inhibitory effects of diarylheptanoids isolated from C. avellana byproducts against α-glucosidase enzyme were evaluated. Molecular docking experiments disclosed the establishment of several key interactions between all the screened diarylheptanoids and the pr…
Design and simulation of QCA-based 3-bit binary to gray and vice versa code converter in reversible and non-reversible mode
2022
The current Very Large-Scale Integration (VLSI) technology has reached its peak due to the fundamental physical limits of Complementary Metal-Oxide-Semiconductor (CMOS). Quantum-dot Cellular Automata (QCA) is considered a proper alternative to CMOS technology in digital circuit design. QCA has features like low power, small area, and high speed in nanoscale digital circuit design. A code converter is a circuit that converts a determined code to another one. Code converters such as Binary to Gray, Gray to Binary, and Binary to BCD converters have a crucial role in fast signal processing in digital systems. Also, code converters are used as a base unit for data transmission into the Arithmeti…
Use of Sentinel-2 Satellite for Spatially Variable Rate Fertiliser Management in a Sicilian Vineyard
2022
Satellites can be used for producing maps of within-field crop and soil parameters and, consequentially, spatially variable rate crop input application maps. The plant vegetative vigour index (i.e., Normalised Difference Vegetation Index—NDVI) and the leaf water content index (i.e., Normalised Difference Water Index—NDWI) maps were used to study—through both time and space—the phenological phases of two plots, with Syrah and Nero d’Avola grapevine varieties, in a Sicilian vineyard farm, located in Naro (Agrigento, Sicily, Italy). The aim of this work is to produce spatially variable rate nitrogen fertiliser maps to be applied in the two vineyard plots under stu…
Quand conduire, c’est aussi habiter. Regard ethno-sociologique sur le rapport à l’automobile des jeunes générations
2022
International audience
Description of movement sensor dataset for dog behavior classification
2022
The description and results of the original investigation are found in: Dog behaviour classification with movement sensors placed on the harness and the collar, Kumpulainen, P., Valldeoriola Cardó, A., Somppi, S., Törnqvist, H., Väätäjä, H., Majaranta, P., Gizatdinova, Y., Antink, C. H., Surakka, V., V. Kujala, M., Vainio, O. & Vehkaoja, A., Aug 2021, In: Applied Animal Behaviour Science. 241, 7 p., 105393. Movement sensor data from seven static and dynamic dog behaviors (sitting, standing, lying down, trotting, walking, playing, and (treat) searching i.e. sniffing) was collected from 45 middle to large sized dogs with six degree-of-freedom movement sensors attached to the collar and the ha…
Rendering in corso...
2022
Introduzione al libro "Gaming" di Alexander R. Galloway Introduction to Alexander R. Galloway's "Gaming" book
Terroir peut-il être un terme en oenologie? Exploitation sémantique de données situées en contexte vini-viticole
2022
International audience; Ce chapitre interroge la place du lexème terroir dans les discours français sur le vin, en posant la question de son statut de terme. Il part de la constatation selon laquelle ces discours sont le plus souvent abordés à travers le prisme d’une conception réductrice de la terminologie aboutissant à une fétichisation naïve du mot, sorti de son contexte et de toute l’écologie du discours nécessaire à sa saisie véritablement pragma-sémantique. Après une mise en contexte intégrant les acquis de la recherche en communication-marketing sur cette question, le terme terroir est positionné à l’intersection entre les trois catégories que nous postulons pour le lexique œnologiqu…
Gender Equality and Maternal Burnout: A 40-Country Study
2022
International audience; In Western countries, recent decades have witnessed a revolution toward gender equality. Inequalities have been greatly reduced in areas such as education or employment. Because inequalities lead to distress, this development has largely benefited women. One notable exception is the realm of parenting, which has remained rife with inequalities even in the most egalitarian countries. We hypothesized that experiencing inequality in parenting when one holds egalitarian values and raising a child in a country characterized by a high level of gender equality in other areas, increases mothers’ psychological distress in the specific area of parenting. Multilevel modeling an…
Obbligo vaccinale e limiti: una recente decisione del Consiglio di Giustizia Amministrativa della Regione Siciliana
2022
This brief paper analyses the obligation of Covid-19 vaccine provided by Italian legislation for workers of the National Health Service. In the order n. 38 of 2022, the Council of Sicilian Administrative Justice decided to verify the possibility to impose mandatory Covid-19 vaccine in relation to Art. 32nd of the Italian Constitution, which provides freedom of self-determination in health choices. Moreover, this principle has to be connected to the general principle of solidarity , enshrined in the Art. 2nd of the Italian Constitution.
ZnO – Yb2O3 composite optical ceramics: Synthesis, structure and spectral-luminescent properties
2022
International audience; Zinc oxide optical ceramics containing 0 – 2 wt% ytterbium are prepared byuniaxial hot pressing of commercial oxides at 1150 and 1180 °C. The ceramics have themain crystalline phase of hexagonal wurtzite-type ZnO. Ytterbium ions do not enter theZnO crystals but form a cubic sesquioxide phase of Yb2O3 located at the ZnO grainboundaries. Yb acts as an inhibitor for the ZnO grain growth. The ceramics exhibittransmittance up to 60% in the visible. Their transmission in the infrared is determinedby the free charge carrier absorption. The Yb3+ ions are found in C2 and C3i sites in Yb2O3crystals. Under X-ray excitation, the ceramics exhibit intense luminescence bands in the…
Regio- and stereoselective synthesis of spiro-heterocycles bearing the pyrazole scaffold via [3+2] cycloaddition reaction
2022
Abstract Herein we reported the utility of one-pot multicomponent based [3+2] cycloaddition reaction transformation to prepare a new two hybrids of spirooxindoles engrafted with pyrazole skeleton. Upon treatment of the electron-deficient olefins based pyrazole motif with in situ the generated azomethine ylides (AY) of sarcosine with the 6-chloro-isatin afforded spiroadducts. To enlighten the regio- and diastereo-selectivity of these spiroheterocycles, single crystal X-ray diffraction analysis was presented. Using Hirshfeld calculations, many short distance contacts such as O…H, Cl…H, N…H, H…C, C…C and Cl…S have a great impact on the molecular packing and the crystal stability of 8a and 8b. …
Control points deployment in an Intelligent Transportation System for monitoring inter-urban network roadway
2022
Abstract The constant evolution of transportation systems and traffic in developing countries is nowadays confronted with a problem of road safety and therefore of a high accident rate, especially in the context of inter-urban road transport. In this work, we propose a communication architecture for an Intelligent Transport System (ITS) to provide surveillance in an inter-urban transport network in the context of developing countries. We introduce two types of control points: Relay Control Points (RCP) and Treatment Control Points (TrCP). We also designed two multi-objective models for the deployment of these points. In order to ensure good coverage, to minimize the cost of installation and…
Microbiological and physicochemical profile of sugar added ewe’s Ricotta during storage
2022
The microbiological and physicochemical traits of fresh ewe’s Ricotta made with (40% w/w) and without sucrose were investigated. Sugar added Ricotta (SAR) andcontrol Ricotta (CTR) were packaged and stored at 4°C for 90 d. Salmonella spp., Listeria monocytogenes,Escherichia coli, coagulase positive staphylococci, Enterobacteriaceae, total coliforms, Pseudomonas, yeasts, moulds and clostridia were undetectable during the entire monitoring. Total mesophilic and psychrotrophic microorganisms and mesophilic cocci lactic acid bacteria increased over time,but their development was limited in SAR production. The acidificationwas observed only for CTR. Water activity was consistently low(0.897 on av…
Patterns of domain-specific learning among medical undergraduate students in relation to confidence in their physiology knowledge : insights from a p…
2022
Research FocusThe promotion of domain-specific knowledge is a central goal of higher education and, in the field of medicine, it is particularly essential to promote global health. Domain-specific knowledge on its own is not exhaustive; confidence regarding the factual truth of this knowledge content is also required. An increase in both knowledge and confidence is considered a necessary prerequisite for making professional decisions in the clinical context. Especially the knowledge of human physiology is fundamental and simultaneously critical to medical decision-making. However, numerous studies have shown difficulties in understanding and misconceptions in this area of knowledge. Therefo…
Bodily Practices in Action Formation and Ascription in Multilingual Interaction: Introduction to the Special Issue.
2022
This special issue brings together empirical studies that investigate how bodily practices feature in action formation and action ascription in multilingual interaction (Schegloff, 2007; Levinson, 2013). Grounded in video-based conversation analysis and drawing on data from diverse sociomaterial settings, the articles investigate the contingent interactional processes through which speakers from different language backgrounds accomplish actions and achieve intersubjectivity. They demonstrate how specific constellations of linguistic resources, bodily conduct, spatial configurations, and material ecology are built into accomplishment of actions at different levels of interactional organizati…
Female audit team leaders and audit effort
2022
Abstract Auditing is a collective process conducted by a professional accounting team with a wide range of skills and experience. Audit work is labor-intensive, and audit team diversity, particularly gender diversity, is considered to have both auditing and economic effects. However, there is scant empirical research on the way that audit engagements are conducted and the role of audit team leaders (ATLs), specifically female ATLs, in the audit effort, because they and other audit team members mainly develop audit strategies in practice during the planification period. A hand-collected private data set was gathered from Spanish small and medium-sized audit firms from 2001 to 2015. After con…
(Bounded) Traveling combustion fronts with degenerate kinetics
2022
Abstract We consider the propagation of a flame front in a solid periodic medium. It is governed by an equation of Hamilton–Jacobi type, whose front’s velocity depends on the temperature via a nonlinear degenerate kinetic rate. The temperature solves a free boundary problem subject to boundary conditions depending on the front’s velocity itself. We show the existence of nonplanar traveling wave solutions which are bounded and global. Previous results by the same authors (cf. Alibaud and Namah, 2017) were obtained for essentially positively lower bounded kinetics or eventually which have some very weak degeneracy. Here we consider very general degenerate kinetics, including for the first tim…
Matroid optimization problems with monotone monomials in the objective
2022
Abstract In this paper we investigate non-linear matroid optimization problems with polynomial objective functions where the monomials satisfy certain monotonicity properties. Indeed, we study problems where the set of non-linear monomials consists of all non-linear monomials that can be built from a given subset of the variables. Linearizing all non-linear monomials we study the respective polytope. We present a complete description of this polytope. Apart from linearization constraints one needs appropriately strengthened rank inequalities. The separation problem for these inequalities reduces to a submodular function minimization problem. These polyhedral results give rise to a new hiera…
Do the current guidelines for heart failure diagnosis and treatment fit with clinical complexity?
2022
Heart failure (HF) is a clinical syndrome defined by specific symptoms and signs due to structural and/or functional heart abnormalities, which lead to inadequate cardiac output and/or increased intraventricular filling pressure. Importantly, HF becomes progressively a multisystemic disease. However, in August 2021, the European Society of Cardiology published the new Guidelines for the diagnosis and treatment of acute and chronic HF, according to which the left ventricular ejection fraction (LVEF) continues to represent the pivotal parameter for HF patients’ evaluation, risk stratification and therapeutic management despite its limitations are well known. Indeed, HF has a complex pathophys…
Immunological response against SARS-CoV-2 following full-dose administration of Comirnaty® COVID-19 vaccine in nursing home residents
2022
6 páginas, 2 figuras, 3 tablas. Se puede acceder al texto completo de este artículo desde PubMedCentral: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8490129 . Los datos de investigación utilizados en el mismo, se encuentran disponibles en: https://doi.org/10.1016/j.cmi.2021.09.031.
Management of Lemierre Syndrome.
2022
Lemierre Syndrome is a rare form of septic thrombophlebitis of the head and neck veins, most typically of the internal jugular vein, which affects otherwise healthy adolescents and young adults after an oropharyngitis or other local infection. It is characterized by multiple septic embolization. Despite treatment, Lemierre Syndrome displays a high rate of in-hospital complications that include thrombus progression and a new peripheral septic embolization; moreover, it can be fatal or cause disabling sequelae. The mainstay of the treatment is antibiotic therapy; anticoagulation is often used, but its role is controversial. Surgical treatment is often necessary in case of peripheral septic le…
Spanish Validation of the Multidimensional Existential Meaning Scale: Which Dimension of Meaning in Life Is More Associated With Psychopathology in P…
2022
BackgroundTo assess three dimensions of Meaning in Life (comprehension, purpose, and mattering) the Multidimensional Existential Meaning Scale (MEMS) was developed, however, the MEMS's factorial structure has not yet been confirmed in a Spanish-speaking sample. A question that remains unanswered is which of the three dimensions of MiL are associated with psychopathology in clinical samples.Aims(1) to analyze the psychometric properties of the MEMS in a Spanish non-clinical population, and (2) to identify which of the three dimensions of MiL shows the strongest relationship with depression, anxiety and positive affect in a clinical population.MethodThe non-clinical sample, consisted of N = 1…
“Castrazioni culturali”. Riflessioni sociologiche a partire dalla normativizzazione binaria del sesso e la medicalizzazione del corpo intersex
2022
The article aims to discuss how and when the social construct of sex as a binary concept was built and spread over the last two centuries and how it affected the condition of intersex people. It will also address the role played by the medical community in creating practices that reproduce sex anatomical st andards, thus the medical legitimization of some forms of violence and social marginalization by which bodies that go beyond the sex and gender binary are medicalized and treated. Guidelines adopted in Italy will be the case study. Current situation of int ersex people will be analyzed, considering the demands of the intersex international community and addressing whether the measures ta…