Search results for " ACTIVATION"

showing 10 items of 1535 documents

Características de los electrogramas auriculares registrados en las líneas de bloqueo producidas con radiofrecuencia en un modelo experimental

2000

Objetivos Analizar y cuantificar las modificaciones de los electrogramas auriculares tras la realizacion de lesiones lineales en la pared auricular utilizando procedimientos de ablacion con radiofrecuencia. Metodos En 12 preparaciones de corazon aislado de conejo segun la tecnica de Langendorff se ha utilizado un electrodo multiple epicardico (221 electrodos unipolares) para analizar la activacion auricular antes y despues de la realizacion de una lesion lineal en la pared auricular izquierda mediante aplicaciones sucesivas de radiofrecuencia. Tras comprobar la existencia de bloqueo de la conduccion en la zona lesionada mediante cartografia epicardica y analisis de los vectores de propagaci…

business.industryMedicineAtrial activationCardiology and Cardiovascular MedicinebusinessHumanitiesRevista Española de Cardiología
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Generation of an Eosinophilotactic Factor from Human PMNs by Various Mechanisms of Cell Activation

1979

It is well established that an increase in the number of eosinophils both in tissue and in the circulation is a feature of many clinical conditions based on delayed (1,2) and immediate type hypersensitivity reactions (3,4). Since eosinophils have been recognised to exert specific killer function on parasites (5) and to be prominent participants at sites of inflammation, the mechanisms of their chemo-attraction are of major importance. In immediate type hypersensitivity reactions, eosinophils have been demonstrated to counteract the mediators of inflammation such as histamine (6), the SRS-A (7) and the platelet aggregating factor (8).

business.industryPlatelet Aggregating FactorEnzyme releaseInflammationMast cellchemistry.chemical_compoundmedicine.anatomical_structurechemistryImmunologyMedicineArachidonic acidmedicine.symptombusinessCell activationHistamineFunction (biology)
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Alfavīrusu vektoru izstrāde makrofāgu aktvācijai vēža imunoterapijā

2016

Audzēju-iefiltrējošiem makrofāgiem piemīt gan spēja veicināt audzēja attīstību, gan inhibēt, attiecībā no to aktivācijas stāvokļa. In vitro pētījumos ir ticis parādīts, ka, iedarbojoties ar interferonu-g (IFN-γ) kopā ar Toll-like receptora (TLR) ligandu, tika ierosināts M1 makrofāgu fenotips, kas tiek asociēts ar audzēja iznīcināšanu. Audzēja imūnterapiju varētu nodrošināt M1 makrofāgu fenotipa inducēšana audzēju-iefiltrējošos makrofāgos. Šajā darbā mēs izvērtējām Semliki meža vīrusa (SFV) vektoru potenciālu makrofāgu aktivācijā pret vēzi. SFV tika izmantots, lai konstruētu replikācijas defektīvus konstruktus ar ieklonētiem peļu audzēja nekrozes faktora (mTNFα), peļu IFNγ un cilvēka IFNγ gē…

cancer immunotherapyrecombinant SFVmacrophage activationinterferon-γBioloģijasurvival
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A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification

2017

International audience; A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions.

catalytic applicationsPlanar chirality010402 general chemistryElectrochemistrycarbon-dioxide01 natural sciences[ CHIM ] Chemical SciencesCatalysisMaterials ChemistryOrganic chemistry[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryfree hydrogen activationaryl bromidesAlkylchemistry.chemical_classificationcomplexes010405 organic chemistryChemistryligandsdirect arylationMetals and AlloysGeneral ChemistrypalladiumCombinatorial chemistry0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialsfrustrated lewis pairsCeramics and Compositescoordination chemistry
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Biochemical characterization of two functional human liver acyl-CoA oxidase isoforms 1a and 1b encoded by a single gene

2007

Abstract Human acyl-CoA oxidase 1 (ACOX1) is a rate-limiting enzyme in peroxisomal fatty acids β-oxidation and its deficiency is associated with a lethal, autosomal recessive disease, called pseudoneonatal-adrenoleukodystrophy. Two mRNA variants, transcribed from a single gene encode ACOX1a or ACOX1b isoforms, respectively. Recently, a mutation in a splice site has been reported [H. Rosewich, H.R. Waterham, R.J. Wanders, S. Ferdinandusse, M. Henneke, D. Hunneman, J. Gartner, Pitfall in metabolic screening in a patient with fatal peroxisomal β-oxidation defect, Neuropediatrics 37 (2006) 95–98.], which results in the defective peroxisomal fatty acids β-oxidation. Here, we show that these mRNA…

chemistry.chemical_classificationGene isoformOxidase testBiophysicsCell BiologyBiologyPeroxisomeBiochemistryIsozymeMolecular biologyArticleEnzyme ActivationIsoenzymesMolecular WeightEnzymechemistryBiochemistryLiverEnzyme StabilityAcyl-CoA oxidaseACOX1HumansHeterologous expressionAcyl-CoA OxidaseMolecular Biology
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Chemistry and reactivity of mononuclear manganese oxamate complexes: Oxidative carbon-carbon bond cleavage of vic-diols by dioxygen and aldehydes cat…

2006

[EN] Two new mononuclear octahedral manganese(III) complexes with the tetradentate equatorial ligand o-phenylenebis(oxamate) (opba) and two aquo (1a) or two pyridine (1b) axial ligands have been synthesized and characterized structurally, magnetically, and electrochemically. The cyclovoltammogram of 1a in acetonitrile (25 degrees C, 0.1 M Bu4NPF6) shows an irreversible one-electron oxidation peak at a high anodic potential (E-ap = 1.03 V versus SCE), while that of 1b shows two well-separated one-electron oxidation peaks at moderate to high anodic potentials (E-ap = 0.92 and 1.27 V versus SCE), the first redox-wave being quasireversible in nature. The access to formally high-valent Mn-IV and…

chemistry.chemical_classificationO-O bond activationManganesePivalic acidLigandStereochemistryProcess Chemistry and Technologychemistry.chemical_elementManganeseC-C bond activationMedicinal chemistryAldehydeRedoxCatalysischemistry.chemical_compoundchemistryCarbon–carbon bondOxidationsFISICA APLICADAPyridinePhysical and Theoretical ChemistryBond cleavageRedox properties
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Polyunsaturated fatty acids in the modulation of T-cell signalling

2009

n-3 polyunsaturated fatty acids (PUFA) have been shown to modulate immune responses. These agents, being considered as adjuvant immunosuppressants, have been used in the treatment of various inflammatory and autoimmune diseases. However, the molecular mechanisms of action of n-3 PUFA-induced immunosuppressive effects are not well-understood. Since exogenous n-3 PUFA, under in vitro and in vivo conditions, are efficiently incorporated into T-cell plasma membranes, a number of recent studies have demonstrated that these agents may modulate T-cell signalling. In this review, the interactions of n-3 PUFA with the second messenger cascade initiated during early and late events of T-cell activati…

chemistry.chemical_classificationPhospholipase DT-LymphocytesClinical BiochemistryCell BiologyBiologyLymphocyte ActivationModels BiologicalDiglyceridesMembrane MicrodomainsBiochemistrychemistryDocosahexaenoic acidFatty Acids Omega-3Second messenger systemFatty Acids UnsaturatedAnimalsHumanslipids (amino acids peptides and proteins)Signal transductionProtein kinase CSignal TransductionCalcium signalingDiacylglycerol kinasePolyunsaturated fatty acidProstaglandins, Leukotrienes and Essential Fatty Acids (PLEFA)
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In vivo analysis of noise dependent activation of white blood cells and microvascular dysfunction in mice

2021

This article contains supporting information on data collection for the research article entitled “Aircraft noise exposure drives the activation of white blood cells and induces microvascular dysfunction in mice” by Eckrich et al. We found that noise-induced stress triggered microvascular dysfunction via involvement of innate immune-derived reactive oxygen species. In this article, we present the instrumentation of mice with dorsal skinfold chambers for in vivo microscopic imaging of blood flow, interaction of leukocytes with the vascular wall (also by fluorescent labelling of blood cells) and vessel diameter. In addition, we explain the preparation of cerebral arterioles for measurement of…

chemistry.chemical_classificationReactive oxygen speciesPathologymedicine.medical_specialtyScienceQClinical BiochemistryIn vivo analysisVideo microscopyBlood flowMethod ArticleIn vivo fluorescence microscopy and cerebral arteriole cannulation to assess noise induced changes in activation of white blood cells and microvascular dysfunctionIn vitroCerebral arterioles cannulationMedical Laboratory TechnologyDorsal skinfold chamberchemistryIn vivoFluorescent labeling of blood cellsVideo microscopyMicroscopic imagingmedicineResearch articleMethodsX
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Trapping of Different Lipase Conformers in Water-Restricted Environments

1996

Based on a recently reported strategy to rationally activate lipolytic enzymes for use in nonaqueous media [Mingarro, I., et al. (1995) Proc. Natl. Acad. Sci. U.S.A. 92, 3308-3312], we compared the behavior in water-restricted environments of activated vs nonactivated forms of different lipases toward their natural substrates, triacylglycerols. To this end, nine lipases from varied origins (mammalian, fungal, and bacterial) were assayed using simple acidolyses as nonaqueous model reactions. The experimental results for several (though not all) lipases, discussed in the light of current structural and functional information, were collectively consistent with a model where, depending on the "…

chemistry.chemical_classificationbiologySwineChemistryWaterLipaseTrappingBiochemistrySubstrate SpecificityEnzyme ActivationKineticsEnzymePseudomonasbiology.proteinAnimalsOrganic chemistryAspergillus nigerLipasePancreasConformational isomerismMicellesRhizopusCandidaBiochemistry
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Mo-Based Oxidizers as Powerful Tools for the Synthesis of Thia- and Selenaheterocycles.

2019

A highly efficient synthetic protocol for the synthesis of thia- and selenaheterocycles has been developed. By employing a MoCl5 -mediated intramolecular dehydrogenative coupling reaction, a broad variety of structural motifs was isolated in yields up to 94 %. The electrophilic key transformation is tolerated by several labile moieties like halides and tertiary alkyl groups. Due to the use of disulfide or diselenide precursors, a high atom efficiency was achieved.

chemistry.chemical_classificationcyclization010405 organic chemistryChemistryoxidationOrganic ChemistryHalideGeneral Chemistry010402 general chemistry01 natural sciencesCombinatorial chemistryCatalysisCoupling reactionC−H activationsulfur heterocycles0104 chemical sciencesDiselenidemolybdenumAtom economyIntramolecular forceElectrophileStructural motifAlkylChemistry (Weinheim an der Bergstrasse, Germany)
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