Search results for " MS"
showing 10 items of 169 documents
A statistical design of experiments for optimizing the MALDI-TOF-MS sample preparation of polymers. An application in the assessment of the thermo-me…
2011
[EN] The sample preparation procedure for MALDI-TOF MS of polymers is addressed in this study by the application of a statistical Design of Experiments (DoE). Industrial poly (ethylene terephthalate) (PET) was chosen as model polymer. Different experimental settings (levels) for matrixes, analyte/matrix proportions and concentrations of cationization agent were considered. The quality parameters used for the analysis were signal-to-noise ratio and resolution. A closer inspection of the statistical results provided the study not only with the best combination of factors for the MALDI sample preparation, but also with a better understanding of the influence of the different factors, individua…
Assessing the MALDI-TOF MS sample preparation procedure to analyze the influence of thermo-oxidative ageing and thermo-mechanical degradation on poly…
2011
[EN] Multiple processing by means of successive injection cycles was used to simulate the thermo-mechanical degradation effects on the oligomeric distribution of PLA under mechanical recycling. Likewise, an accelerated thermal ageing over PLA glass transition was performed in order to simulate its service life. MALDI-TOF MS was used for the analysis and the sample preparation procedure was assessed by means of a statistical Design of Experiments (DoE). The quality effects in use for the analysis were signal-to-noise ratio and Resolution. Different matrixes, analyte/matrix proportions and the use of NaTFA as cationization agent were considered. A deep inspection of the statistical results pr…
Synthesis, Characterization, and Saccharide Binding Studies of Bile Acid − Porphyrin Conjugates
2007
Synthesis and characterization of bile acid-porphyrin conjugates (BAPs) are reported. Binding of saccharides with BAPs in aqueous methanol was studied by monitoring changes in the visible absorption spectral of the porphyrin-moieties. Although these studies clearly showed absorbance changes, suggesting quite high if non-selective binding, the mass spectral studies do not unambiguously support these results.
HPLC-DAD-ESI-MS2analytical profile of extracts obtained from purple sweet potato after green ultrasound-assisted extraction
2016
International audience; Ultrasound pre-treatment (UAE) was applied to assist the extraction of valuable compounds (polyphenols (especially anthocyanins), and proteins) from purple sweet potato (PSP). Under optimum conditions (ultrasound time (40 min); supplementary hot extraction (80 °C) up to 120 min; pH: 2.5; ethanol concentration: 58%), the highest concentrations of polyphenols (3.877 mg/g), anthocyanins (0.293 mg/g), and proteins (0.753 mg/g) were found, with minimal specific energy consumption (8406 J/mg).Moreover, anthocyanin and non-anthocyanin polyphenols in PSP extract from optimized extraction temperature were identified using HPLC-DAD-ESI-MS2. The major identified anthocyanins we…
Random walk approximation of BSDEs with H{\"o}lder continuous terminal condition
2018
In this paper, we consider the random walk approximation of the solution of a Markovian BSDE whose terminal condition is a locally Hölder continuous function of the Brownian motion. We state the rate of the L2-convergence of the approximated solution to the true one. The proof relies in part on growth and smoothness properties of the solution u of the associated PDE. Here we improve existing results by showing some properties of the second derivative of u in space. peerReviewed
Fast offline data reduction of laser ablation MC-ICP-MS Sr isotope measurements: Via an interactive Excel-based spreadsheet 'SrDR'
2020
Strontium isotopes are applied to a wide range of scientific fields and to different types of sample materials, providing valuable information foremost about provenance and age, but also on diagenetic processes and mixing relationships between different Sr reservoirs. The development of in-situ analytical techniques, such as laser ablation ICP-MS, has improved our understanding of Sr isotope variability in several field of application, because of the possibility to discriminate small-scale changes and their spatial distribution. However, large outputs of Sr isotope data are produced by laser ablation MC-ICP-MS systems, which necessitate of multiple offline steps to correct and assess the da…
Smiltsērkšķu ogu (Hippophae Rhamnoides) ekstrakcijas produktu sastāva izvērtējums ar hromatogrāfijas un masspektrometrijas metodēm
2022
Smiltsērkšķu ogu (Hippophae Rhamnoides) ekstrakcijas produktu sastāva izvērtējums ar hromatogrāfijas un masspektrometrijas metodēm. Zinātniskais vadītājs Dr. chem., asoc. prof. Pēteris Mekšs. Bakalaura darbs analītiskajā ķīmijā, 36 lappuses, 14 tabulas, 7 attēli, 30 literatūras avoti, 3 pielikumi, latviešu valodā. Darbā analizēti smiltsērkšķu eļļas ekstrakti ar n-heksānu, saulespuķu eļļu un olīveļļu, noteikts to ķīmiskais sastāvs ar gāzu hromatogrāfijas masspektrometrijas (GC-MS) metodi. Iegūtie masspektri tika atpazīti ar datu bāzi Nist02. Literatūras apskatā aplūkota informācija par smiltsērkšķu eļļas, saulespuķu eļļas un olīveļļas ķīmisko sastāvu, smiltsērkšķu eļļas stabilitāti, nozīmi c…
Combined use of liquid chromatography triple quadrupole mass spectrometry and liquid chromatography quadrupole time-of-flight mass spectrometry in sy…
2012
As a suitable way for routine screening of pesticides and control of other organic contaminants in water, the combination of liquid chromatography triple quadrupole tandem mass spectrometry (LC-QqQ-MS/MS) and liquid chromatography-hybrid quadrupole time-of-flight mass spectrometry (LC-QTOF-MS) has been applied to the analysis of 63 surface and waste water samples after conventional solid-phase extraction (SPE). The extracts were screened for 43 pesticides or degradation products by LC-QqQ-MS/MS achieving limits of detection (LOD) ranged from 0.04 to 2 ng L(-1). Of the 43 selected pesticides, 33 were detected in water samples. The ESI-QTOF MS instrument was run using two simultaneous acquisi…
(Supplementary Table 1) 230Th/U results for stalagmite Cuba Grande (CG) from Pinar del Rio
2010
We present 22 U-series ages for a stalagmite from north-western Cuba based on multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) and thermal ionisation mass spectrometry (TIMS). Our results reveal that the stalagmite continuously grew within the last ~1400a. Low uranium content of the sample and thus, extremely low 230Th concentrations limit the precision and accuracy of 230Th/U-dating by TIMS. Samples measured by MC-ICPMS show a high variability of 232Th content along the growth axis with some sections significantly affected by initial 230Th from a detrital phase. An a-priori bulk earth ratio for (238U/232Th) cannot be used to accurately account for this initial 230Th.…
A time domain triangle method approach to estimate actual evapotranspiration: Application in a Mediterranean region using MODIS and MSG-SEVIRI produc…
2016
Abstract In this study, spatially distributed estimates of regional actual evapotranspiration (ET) were obtained using a revised procedure of the so called “triangle method” to parameterize the Priestley–Taylor ϕ coefficient. In the procedure herein proposed, named Time-Domain Triangle Method (TDTM), the triangular feature space was parameterized considering pairs of T s –VI values obtained by exploring, for each pixel, only their temporal dynamics. This new method was developed using time series products provided by MODIS and MSG-SEVIRI sensors. Moreover the proposed procedure does not depend on ancillary data, and it is only based on remotely sensed vegetation indices and day–night time l…