Search results for "composites"

Performance of MaterBi(R) based ecocomposites

2011

Electrochemical synthesis of benzoxazoles from anilides - a new approach to employ amidyl radical intermediates.

2017

A novel electrochemical method for the synthesis of benzoxazoles from readily available anilides is reported. Various functionalities are tolerated and good yields can be achieved. By employing common electrode materials and a simple constant current protocol, this method is an attractive new alternative to conventional pathways.

Simple and scalable electrochemical synthesis of 2,1-benzisoxazoles and quinoline N-oxides.

2019

Cathodic reduction of the nitro moiety and subsequent intramolecular cyclization affords different substituted 2,1-benzisoxazoles and quinoline N-oxides. This methodology allows the synthesis of two different types of heterocycles from common simple starting materials, using electrons as a sole reagent for this transformation. The electrolysis can be conducted in a very simple undivided electrolysis cell under constant current conditions. This permits working on a larger scale compared to other electrochemical methodologies and represents a significant advantage.

Layer-wise and equivalent single layer models for smart multilayered plates

2014

Layer-wise and equivalent single layer plate models for magneto-electro-elastic multiphysics laminates are presented in a unified framework. They are based on variable kinematics and quasi-static behavior of the electromagnetic fields. The electromagnetic state of each single layer is preliminary determined by solving the corresponding governing equations coupled with the proper interface continuity and external boundary conditions. By so doing, the electromagnetic state is condensed into the plate kinematics and the layer governing equations are inferred by the principle of virtual displacements. This approach identifies effective mechanical layers, which are kinematically equivalent to th…

High-Temperature Hall Measurements on BaSnO3Ceramics

2005

Simultaneous Hall and conductivity measurements were performed in situ between 650° and 1050°C on n-type semiconducting BaSnO3ceramics. The variation of the Hall mobility and the Hall carrier density as a function of oxygen partial pressure between 102 and 105 Pa and of temperature was investigated. At temperatures below 900°C the conductivity exhibits a dependence on temperature and oxygen partial pressure which is mainly determined by variations of the Hall mobility. Above 900°C most of the significant dependence is due to a variation in carrier density. Furthermore, a simple defect model assuming doubly ionized oxygen vacancies and acceptor impurities is discussed for BaSnO3.

Photosensitivity of SiO2–Al and SiO2–Na glasses under ArF (193 nm) laser

2009

Abstract Photosensitivity of SiO 2 –Al and SiO 2 –Na glass samples was probed by means of the induced optical absorption and luminescence as well as by electron spin-resonance (ESR) after irradiation with excimer-laser photons (ArF, 193 nm). Permanent visible darkening in the case of SiO 2 –Al and transient, life time about one hour, visible darkening in the case of SiO 2 –Na was found under irradiation at 290 K. No darkening was observed at 80 K for either kind of material. This investigation is dedicated to revealing the electronic processes responsible for photosensitivity at 290 and 80 K. The photosensitivity of both materials is related to impurity defects excited directly in the case …

Electron paramagnetic resonance investigation on the hyperfine structure of the center in amorphous silicon dioxide

2007

Abstract We report an experimental investigation by electron paramagnetic resonance (EPR) spectroscopy on the hyperfine structure of the E δ ′ center in γ-ray irradiated amorphous silicon dioxide materials. This study has driven us to the determination of the intensity ratio between the hyperfine doublet and the main resonance line of this point defect. This ratio was obtained for a variety of silica samples and compared with the analogous ratio obtained for the E γ ′ defect. The comparison definitively confirms that the electronic wave function involved in the E δ ′ center is actually delocalized over four nearly equivalent Si atoms.

Biomimetic oxidation of pyrene and related aromatic hydrocarbons. Unexpected electron accepting abilities of pyrenequinones

2014

We present a mild catalytic method to oxidize PAHs and, in particular, pyrene. The pyrenediones are much better electron acceptors than benzoquinone in the gas phase and present similar accepting abilities in solution.

ELECTROSPUN NANOFIBROUS MATS IN FIBRE REINFORCED EPOXY LAMINATES

POLYMER ELECTROSPUN NANOFIBERS AS INTERLEAVES FOR ENANCHEMENT OF CFRP LAMINATES DELAMINATION RESISTANCE

2019

Electrospinning process is a technique to produce nanoscale fibers that has evinced more interest in recent years due to its versatility and potential for applications in several applications. The mall size and the concomitant ultra-high specific surface area of electrospun nanofibers make them suitable for several applications, such as tissue engineering, biosensors, filtration and advanced polymer composites (1). In particular for carbon fiber reinforced polymers (CFRPs) the huge specific surface area of electrospun nanofibers results in very large interfacial area between nanofibers and polymer matrix and therefore leads to substantial improvement of fiber-matrix interfacial interactions…