Search results for "polymers"
showing 10 items of 3567 documents
Thermomechanical properties and thermal degradation kinetics of poly(methyl methacrylate) (PMMA) and polycarbonate (PC) filled with cerium-doped yttr…
2016
This paper reports on the thermomechanical properties and thermal degradation kinetics of poly(methyl methacrylate) (PMMA) and polycarbonate (PC) composites filled with cerium-doped yttrium aluminium garnet (Ce:YAG) at different contents ranging between 0.1 and 5 wt%, and prepared by melt compounding. The interaction between PMMA and the filler was much stronger than that between PC and the filler, and this resulted in a significant improvement in the dynamic mechanical properties of the PMMA composites. The presence of filler did not significantly increase the thermal stability of the PC, while an observable increase in the thermal stability was only observed at higher filler loadings for …
Injection Molding and Mechanical Properties of Bio-Based Polymer Nanocomposites
2018
The use of biodegradable/bio-based polymers is of great importance in addressing several issues related to environmental protection, public health, and new, stricter legislation. Yet some applications require improved properties (such as barrier or mechanical properties), suggesting the use of nanosized fillers in order to obtain bio-based polymer nanocomposites. In this work, bionanocomposites based on two different biodegradable polymers (coming from the Bioflex and MaterBi families) and two different nanosized fillers (organo-modified clay and hydrophobic-coated precipitated calcium carbonate) were prepared and compared with traditional nanocomposites with high-density polyethylene (HDPE…
Promising Dendritic Materials: An Introduction to Hyperbranched Polymers
2011
In nature and universe from living to nonliving things, branching occurs anywhere and anytime, such as the Crab Nebula, forked lightning, river basins, trees, nerves, veins, snow crystals, nervures, and proteoglycan ranging from light-years to kilometers, and to microscale and nanoscales (see Figure 1.1 for selected branching patterns). Hence, branching is a general and important phenomenon that could result in faster and more efficient transfer, dissipation, and distribution of energy and/or matter.
One-Component DNA Mechanoprobes for Facile Mechanosensing in Photopolymerized Hydrogels and Elastomers.
2021
DNA mechanosensors offer unique properties for mechano-adaptive and self-reporting materials, such as programmable bond strength and geometrical strain response, tunable fluorescent strain sensing, interfacing to biological systems, and the ability to store mechanical information. However, the facile incorporation of advanced DNA motifs into polymer networks and achieving robustness in application settings remain difficult. Herein, we introduce one-component DNA mechanoprobes that can be easily polymerized into polymer hydrogels and even elastomers to allow strain-induced fluorescence sensing. The all-in-one mechanoprobe contains a DNA hairpin for programmable force sensing, an internal flu…
Novel hybrid polymer composites with graphene and MXene nano-reinforcements: computational analysis
2021
This paper presents a computational analysis on the mechanical and damage behavior of novel hybrid polymer composites with graphene and MXene nano-reinforcements targeted for flexible electronics and advanced high-strength structural applications with additional functions, such as real-time monitoring of structural integrity. Geometrical models of three-dimensional representative volume elements of various configurations were generated, and a computational model based on the micromechanical finite element method was developed and solved using an explicit dynamic solver. The influence of the geometrical orientation, aspect ratio, and volume fractions of the inclusions, as well as the interfa…
Processing-structure-property relationships of electrospun PLA-PEO membranes reinforced with enzymatic cellulose nanofibers
2020
Abstract Three different solvent mixtures were used to prepare electrospun membranes based on polylactic acid (PLA), polyethylene oxide (PEO) and enzymatic cellulose nanofibers (CNF). The materials were characterized from a morphological, spectroscopic, mechanical and rheological point of view. Furthermore, swelling test were performed in order to assess the water uptake of each sample. The results put into evidence that the choice of the solvents affects the structure and the properties of the membranes. Among the protocols tested, using chloroform/acetone/ethanol mixture was found to allow a high degree of CNF dispersion and a good electrospinnability of polymer solutions. These features …
Fabrication of an extremely cheap poly(3,4-ethylenedioxythiophene) modified pencil lead electrode for effective hydroquinone sensing
2021
Hydroquinone (HQ) is one of the major deleterious metabolites of benzene in the human body, which has been implicated to cause various human diseases. In order to fabricate a feasible sensor for the accurate detection of HQ, we attempted to electrochemically modify a piece of common 2B pencil lead (PL) with the conductive poly(3,4-ethylenedioxythiophene) or PEDOT film to construct a PEDOT/PL electrode. We then examined the performance of PEDOT/PL in the detection of hydroquinone with different voltammetry methods. Our results have demonstrated that PEDOT film was able to dramatically enhance the electrochemical response of pencil lead electrode to hydroquinone and exhibited a good linear co…
Influence of ZnO/graphene nanolaminate periodicity on their structural and mechanical properties
2018
International audience; Structural, electronic and mechanical properties of ZnO/Graphene (ZnO/G) nanolaminates fabricated by low temperature atomic layer deposition (ALD) and chemical vapor deposition (CVD) were investigated. We performed scanning and transmission electron microscopy (SEM/TEM), X-ray diffraction (XRD), electron energy loss spectroscopy (EELS), Raman spectroscopy, X-Ray photoelectron spectroscopy (XPS) and nanoindentation to characterize the ZnO/G nanolaminates. The main structural and mechanical parameters of ZnO/G nanolaminates were calculated. The obtained results were analyzed and interpreted taking into account mechanical interaction and charge effects occurring at the …
The solidification behavior of a PBT/PET blend over a wide range of cooling rate
2009
In recent years, much attention has been paid to the development of high-performance polyester blends, among which blends of polybutylene terephthalate/polyethylene terephthalate (PBT/PET) are expected to exhibit remarkable properties as far as their crystallization behavior is concerned. Through trial and error, appropriate commercial compositions have been chosen which could not be otherwise explained by a suitable interpretation of the mechanisms determining their solidification behavior. The solidification behavior of a 60/40 w/w PBT/PET blend was studied in a wide range of cooling conditions, according to a continuous cooling transformation (CCT) procedure developed previously, aiming …
Synthesis of novel reactive coalescing agents and their application in a latex coating
2002
The syntheses and the performance of five glycidyl compounds as novel reactive coalescing agents are presented. The reactive coalescing agents were synthesized with moderate yields, structures were verified using spectroscopic methods, and the properties of glycidyl compounds such as boiling points and evaporation rates were measured. The applicability of five glycidyl compounds as reactive coalescing agents was tested in characterized carboxyl functional latex. Properties like pendulum hardness, gloss, and efficiency of the glycidyl compound to reduce the minimum film-formation temperature (MFFT) of the latex were measured from the cured latex films. The application test results were compa…