0000000001298881

AUTHOR

Oscar Castillo

showing 68 related works from this author

Electrical conductivity and strong luminescence in copper Iodide double chains with isonicotinato derivatives

2015

Direct reactions between CuI and isonicotinic acid (HIN) or the corresponding esters, ethyl isonicotinate (EtIN) or methyl isonicotinate (MeIN), give rise to the formation of the coordination polymers [CuI(L)] with L=EtIN (1), MeIN (2) and HIN (3). Polymers 1-3 show similar structures based on a CuI double chain in which ethyl-, methyl isonicotinate or isonicotinic acid are coordinated as terminal ligands. Albeit, their supramolecular architecture differs considerably, affecting the distances and angles of the central CuI double chains and thereby their physical properties. Hence, the photoluminescence shows remarkable differences; 1 and 2 show a strong yellow emission, whereas 3 displays a…

Models MolecularThermogravimetric analysisPhotoluminescenceLuminescencePolymersInorganic chemistrySupramolecular chemistrychemistry.chemical_elementConductivityIsonicotinic acidLigandsNiacinCatalysisCopper iodidechemistry.chemical_compoundCoordination ComplexesElectrical conductivityCarboxylateMolecular StructureStructure elucidationOrganic ChemistryElectric ConductivityGeneral ChemistryIodidesCopperCoordination polymersCrystallographychemistryLuminescenceCopper
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Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

2012

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.

Solventchemistry.chemical_compoundMaterials scienceChemical engineeringchemistryMechanics of MaterialsCoordination polymerMechanical EngineeringDelaminationGeneral Materials ScienceComposite materialLayered structureAdvanced Materials
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Rational Design of Copper(II)-Uracil Nanoprocessed Coordination Polymers to Improve Their Cytotoxic Activity in Biological Media

2021

This work is focused on the rational structural design of two isostructural Cu(II) nano-coordination polymers (NCPs) with uracil-1-acetic acid (UAcOH) (CP1n) and 5-fluorouracil-1-acetic acid (CP2n). Suitable single crystals for ꭕ-ray diffraction studies of CP1 and CP2 were prepared under hydrothermal conditions, enabling their structural determination as 1D-CP ladder-like polymeric structures. The control of the synthetic parameters allows their processability into water colloids based on nanoplates (CP1n and CP2n). These NCPs are stable in water at physiological pHs for long periods. However, interestingly, CP1n is chemically altered in culture media. These transformations provoke the part…

Materials scienceCell SurvivalPolymersCytotoxicitychemistry.chemical_elementAntineoplastic Agentschemistry.chemical_compoundHydrolysisBiological mediaCoordination ComplexesCell Line TumorMoietyHumansGeneral Materials Science5-fluorouracilIsostructuralCytotoxicityUracilchemistry.chemical_classificationReactive oxygen speciesRational designUracilQuímicaCombinatorial chemistryCopperCoordination polymerschemistryNano-coordination polymersReactive Oxygen SpeciesCopper
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One-dimensional oxalato-bridged copper(II) complexes with 3-hydroxypyridine and 2-amino-4-methylpyridine

2001

Two new one-dimensional oxalato-bridged copper(II) compounds of formula [Cu(ox)L2]n (1) and {[Cu2(ox)2L%3]·L%}n (2) [ox oxalate dianion, L3-hydroxypyridine (pyOH) and L% 2-amino-4-methylpyridine (ampy)] have been synthesized and characterized by FT-IR spectroscopy, variable-temperature magnetic measurements and single-crystal X-ray diffraction. The crystal structure of 1 comprises chains of copper atoms in which cis-[Cu(pyOH)2] 2 units are sequentially bridged by asymmetric bis-bidentate oxalato ligands with an intrachain copper‐copper separation of 5.548(1) A, . Each copper atom is six-coordinated: four oxygen atoms belonging to two bridging oxalato ligands and two nitrogen atoms from two …

Chemistrychemistry.chemical_elementCrystal structureCopperMagnetic susceptibilitySquare pyramidal molecular geometryOxalateInorganic ChemistryCrystallographychemistry.chemical_compoundOctahedron4-MethylpyridineMaterials ChemistryPhysical and Theoretical ChemistryCoordination geometryInorganica Chimica Acta
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Reversible Solvent‐Exchange‐Driven Transformations in Multifunctional Coordination Polymers Based on Copper‐Containing Organosulfur Ligands

2014

The preparation by simple direct synthesis of a series of coordination polymers based on copper with chloride or bromide and dipyrimidinedisulfide is reported. The structural characterisations of these compounds reveal a rich structural variety as a result of the number of coordination modes available to the organosulfur ligand, in combination with the bridging capabilities of the halides. Interestingly, some of the polymers displayed fully reversible solvent exchange/removal crystal-to-crystal 2D to 0D and 2D to 2D transformations. These materials show multifunctional electronic properties. Thus, some of them are semiconductors and present weak antiferromagnetic interactions, and the CuI/C…

chemistry.chemical_classificationLigandChemistryInorganic chemistrychemistry.chemical_elementPolymerCrystal engineeringCopperInorganic ChemistrySolventParamagnetismchemistry.chemical_compoundBromidePolymer chemistryOrganosulfur compoundsEuropean Journal of Inorganic Chemistry
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Control and Simplicity in the Nanoprocessing of Semiconducting Copper-Iodine Double Chain Coordination Polymers

2018

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.8b00364

Supramolecular chemistrySubstituentchemistry.chemical_element02 engineering and technologyConductivity010402 general chemistryIsonicotinic acid01 natural sciencesInorganic Chemistrychemistry.chemical_compoundMultifunctionalMolecular recognitionElectrical conductivityPhysical and Theoretical ChemistryNanomaterialschemistry.chemical_classificationQuímicaPolymer021001 nanoscience & nanotechnologyCopper0104 chemical sciencesCoordination polymersCrystallographychemistry0210 nano-technologyDerivative (chemistry)Inorganic Chemistry
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Copper(II)–Thymine Coordination Polymer Nanoribbons as Potential Oligonucleotide Nanocarriers

2016

This is the peer reviewed version of the following article: Vegas, V. G., Lorca, R., Latorre, A., Hassanein, K., Gómez‐García, C. J., Castillo, O., ... & Amo‐Ochoa, P. (2017). Copper (II)–Thymine Coordination Polymer Nanoribbons as Potential Oligonucleotide Nanocarriers. Angewandte Chemie International Edition, 56(4), 987-991, which has been published in final form at https://doi.org/10.1002/anie.201609031. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions

Coordination polymerInorganic chemistrySupramolecular chemistryOligonucleotideschemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundColloidchemistry.chemical_classificationOligonucleotideNanoribbonsGeneral MedicineGeneral ChemistryPolymerQuímica021001 nanoscience & nanotechnologyCombinatorial chemistryCopper0104 chemical sciencesThymineCoordination polymerschemistryNanocarriers0210 nano-technologyNanocarriers
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Back Cover: Electrical Conductivity and Strong Luminescence in Copper Iodide Double Chains with Isonicotinato Derivatives (Chem. Eur. J. 48/2015)

2015

Electrical resistivity and conductivityChemistryOrganic ChemistryInorganic chemistryCover (algebra)General ChemistryLuminescenceCatalysisCopper iodideChemistry - A European Journal
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Ferromagnetic coupling through a carbonate bridge in the copper (II) chain [Cu(CO3)(4-apy)2] · H2O (4-apy = 4-aminopyridine)

1999

Abstract Atmospheric CO2 fixation by aqueous solutions containing copper(II) bromide and 4-aminopyridine (4-apy) yields the first carbonatobridged copper(II) chain of formula [Cu(CO3)(4-apy)2] · H2O that exhibits an intrachain ferromagnetic coupling.

Aqueous solutionInorganic chemistrychemistry.chemical_elementCrystal structureCopperInorganic ChemistryCoupling (electronics)Crystallographychemistry.chemical_compoundchemistryFerromagnetismBromideMaterials ChemistryCarbonateCupratePhysical and Theoretical ChemistryInorganic Chemistry Communications
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Electrical Conductivity and Luminescence in Coordination Polymers Based on Copper(I)-Halides and Sulfur-Pyrimidine Ligands

2011

The solvothermal reactions between pyrimidinedisulfide (pym(2)S(2)) and CuI or CuBr(2) in CH(2)Cl(2):CH(3)CN lead to the formation of [Cu(11)I(7)(pymS)(4)](n) (pymSH = pyrimidine-2(1H)-thione) (1) and the dimer [Cu(II)(μ-Br)(Br)L](2) (L = 2-(pyrimidin-2-ylamino)-1,3-thiazole-4-carbaldehyde) (2). In the later reaction, there is an in situ S-S, S-C(sp(2)), and C(sp(2))-N multiple bond cleavage of the pyrimidinedisulfide resulting in the formation of 2-(pyrimidin-2-ylamino)-1,3-thiazole-4-carbaldehyde. Interestingly, similar reactions carried out just with a change in the solvent (H(2)O:CH(3)CN instead of CH(2)Cl(2):CH(3)CN) give rise to the formation of coordination polymers with rather diffe…

Models MolecularLuminescencePyrimidinePolymersDimerInorganic chemistryElectric ConductivityHalidechemistry.chemical_elementSulfidesCrystallography X-RayLigandsSulfurCopperInorganic ChemistrySolventchemistry.chemical_compoundPyrimidineschemistryCoordination ComplexesPolymer chemistryPhysical and Theoretical ChemistryLuminescenceCopperBond cleavageInorganic Chemistry
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On the Road to MM′X Polymers: Redox Properties of Heterometallic Ni···Pt Paddlewheel Complexes

2014

On the quest of heterometallic mixed-valence MM'X chains, we have prepared two stable discrete bimetallic compounds: the reduced (PPN)[ClNi(μ-OSCPh)4Pt] (PPN = bis(triphenylphosphine)iminium; OSCPh = benzothiocarboxylato) and the oxidized [(H2O)Ni(μ-OSCPh)4PtCl] species. The role of the aqua and chlorido axial ligands is crucial to facilitate oxidation of the {Ni(μ-OSCPh)4Pt} core. Experimental and theoretical analyses indicate that a NiPt-Cl/Cl-NiPt isomerization process occurs in the oxidized species. The electronic structure of the reduced system shows two unpaired electrons, one located in a d(x(2)-y(2)) orbital of the Ni(II) ion and a second in the antibonding d(z(2)-dz(2)) combination…

010405 organic chemistryChemistryIminium010402 general chemistryPhotochemistryAntibonding molecular orbital01 natural sciencesRedox0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundUnpaired electron[CHIM]Chemical SciencesMolecular orbitalPhysical and Theoretical ChemistryTriphenylphosphineBimetallic stripIsomerizationComputingMilieux_MISCELLANEOUS
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Semiconductive and Magnetic One-Dimensional Coordination Polymers of Cu(II) with Modified Nucleobases

2013

Four new copper(II) coordination complexes, obtained by reaction of CuX2 (X = acetate or chloride) with thymine-1-acetic acid and uracil-1-propionic acid as ligands, of formulas [Cu(TAcO)2(H2O)4]·4H2O (1), [Cu(TAcO)2(H2O)2]n (2), [Cu3(TAcO)4(H2O)2(OH)2]n·4H2O (3), and [Cu3(UPrO)2Cl2(OH)2(H2O)2]n (4) (TAcOH = thymine-1-acetic acid, UPrOH = uracil-1-propionic acid) are described. While 1 is a discrete complex, 2-4 are one-dimensional coordination polymers. Complexes 2-4 present dc conductivity values between 10(-6) and 10(-9) S/cm(-1). The magnetic behavior of complex 2 is typical for almost isolated Cu(II) metal centers. Moderate-weak antiferromagnetic interactions have been found in complex…

Models MolecularPolymersInorganic chemistrychemistry.chemical_elementChlorideNucleobaseInorganic ChemistryMetalMagneticsCoordination ComplexesmedicineAntiferromagnetismPhysical and Theoretical Chemistrychemistry.chemical_classificationMolecular StructureNucleotidesPolymerInductive couplingCopperCrystallographySemiconductorschemistrySuperexchangevisual_artvisual_art.visual_art_mediumCoppermedicine.drugInorganic Chemistry
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Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer

2015

We present a structurally flexible copper–iodide–pyridine-based coordination polymer showing drastic variations in its electrical conductivity driven by temperature and sorption of acetic acid molecules. The dramatic effect on the electrical conductivity enables the fabrication of a simple and robust device for gas detection. X-ray diffraction studies and DFT calculations allow the rationalisation of these observations.

chemistry.chemical_classificationFabricationChemistryCoordination polymerIodideMetals and AlloysNanotechnologySorptionQuímicaGeneral ChemistryAcetic acidPhotochemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundAcetic acidCopper iodide pyridine coordination polymerElectrical resistivity and conductivityPyridineMaterials ChemistryCeramics and CompositesMoleculeChemical Communications
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Electrical Behaviour of Heterobimetallic [MM′(EtCS2)4] (MM′=NiPd, NiPt, PdPt) and MM′X-Chain Polymers [PtM(EtCS2)4I] (M=Ni, Pd)

2012

Herein, we report the isolation of new heterobimetallic complexes [Ni0.6Pd1.4ACHTUNGTRENUNG(EtCS2)4] (1), [NiPtACHTUNGTRENUNG(EtCS2)4] (2) and [Pd0.4Pt1.6ACHTUNGTRENUNG(EtCS2)4] (3), which were constructed by using transmetallation procedures. Subsequent oxidation with iodine furnished the MM'X monodimensional chains [Ni0.6Pt1.4ACHTUNGTRENUNG(EtCS2)4I] (4) and [Ni0.1Pd0.3Pt1.6ACHTUNGTRENUNG(EtCS2)4I] (5). The physical properties of these systems were investigated and the chain structures 4 and 5 were found to be reminiscent of the parent [Pt2ACHTUNGTRENUNG(EtCS2)4I] species. However, they were more sensitively dependent on the localised nature of the charge on the Ni ion, which caused spont…

chemistry.chemical_classificationmolecular electronicsOrganic ChemistryNanotechnologyGeneral ChemistryPolymerDFTinorganic polymerCatalysisIonCrystallographyTransmetalationchemistryConduction bandChemistry - A European Journal
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A bioinspired metal–organic approach to cross-linked functional 3D nanofibrous hydro- and aero-gels with effective mixture separation of nucleobases …

2020

The direct reaction between Cu(CH3COO)2 and uracil-1-acetic acid in water gives rise to the formation of a hydrogel consisting of entangled nanometric ribbons of a crystalline antiferromagnetic 1D Cu(ii) coordination polymer (CP) decorated with biocompatible uracil nucleobases. This hydrogel is the precursor for the preparation of a meso/macroporous ultralight aerogel that shows a remarkable Young's modulus. As a proof-of-concept of the molecular recognition capability of the terminal uracil moieties anchored at Cu(ii) CP chains, this material has been tested as the selective stationary phase for the separation of nucleobase derivatives in HPLC columns.

PolymersCoordination polymerNanofibersHydrogelsAerogelUracil02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesHigh-performance liquid chromatography0104 chemical sciencesNucleobaseMetalchemistry.chemical_compoundMolecular recognitionchemistryChemical engineeringMetalsvisual_artvisual_art.visual_art_mediumGeneral Materials ScienceDirect reaction0210 nano-technologyCopperNanoscale
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A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence

2016

The simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)] (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence.

LuminescenceSilverMaterials scienceThin filmsNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesMaterials ChemistryThin filmchemistry.chemical_classificationThermochromismCrystalline materialsQuímicaGeneral ChemistryPolymer021001 nanoscience & nanotechnology0104 chemical sciencesCrystallographychemistrySolubilizationFilm preparation0210 nano-technologyLuminescenceCoordination reactions
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Halo and Pseudohalo Cu(I)-Pyridinato Double Chains with Tunable Physical Properties

2015

The properties recently reported on the Cu(I)-iodide pyrimidine nonporous 1D-coordination polymer [CuI(ANP)] (ANP = 2-amino-5-nitropyridine) showing reversible physically and chemically driven electrical response have prompted us to carry a comparative study with the series of [CuX(ANP)] (X = Cl (1), X = Br (2), X = CN (4), and X = SCN (5)) in order to understand the potential influence of the halide and pseudohalide bridging ligands on the physical properties and their electrical response to vapors of these materials. The structural characterization of the series shows a common feature, the presence of -X-Cu(ANP)-X- (X = Cl, Br, I, SCN) double chain structure. Complex [Cu(ANP)(CN)] (4) pre…

chemistry.chemical_classificationPyrimidineHydrogen bondChemistrySupramolecular chemistryHalideNanotechnologySingle chainPolymerInorganic ChemistryDouble chainchemistry.chemical_compoundCrystallographyPhysical and Theoretical ChemistryLuminescenceInorganic Chemistry
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Synthesis, characterisation, crystal structures, and magnetic properties of one-dimensional oxalato-bridged metal(II) complexes with 3-hydroxypyridin…

2001

One-dimensional oxalato-bridged metal(II) compounds of formula [M(-ox)(L)2]n [L = 3-hydroxypyridine (pyOH) or isoquinoline (isq)] have been synthesised and characterised by FT-IR spectroscopy, TG-DTA techniques, variable-temperature magnetic measurements and X-ray diffraction methods. The complexes [M(-ox)(pyOH)2]n [M= Co (1), Ni (2)] are isomorphous and crystallise in the orthorhombic space group Pnab. The compounds [M(-ox)(isq)2]n [M= Co (3), Ni (4), Cu (5)] are also isomorphous and belong to the monoclinic space group C2/c. Crystal structures consist of zig-zag chains in which cis-[M(L)2] 2 + units are sequentially bridged by bis-bidentate oxalato ligands with intrachain M···M distances …

ChemistryCrystal structureMagnetic susceptibilityInorganic ChemistryMetalchemistry.chemical_compoundCrystallographyOctahedronvisual_artMaterials Chemistryvisual_art.visual_art_mediumAntiferromagnetismOrthorhombic crystal systemPhysical and Theoretical ChemistryIsoquinolineMonoclinic crystal system
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Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations

2017

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775

Metal saltsCoordination polymerPotassiumInorganic chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesInorganic ChemistryMetalchemistry.chemical_compoundFirst-principles calculationsGroup (periodic table)Physical and Theoretical ChemistryBenzenechemistry.chemical_classification010405 organic chemistryChemistryPolymerQuímica0104 chemical sciencesCoordination polymersCrystallographyMetal-dithiolene polymersvisual_artvisual_art.visual_art_mediumCoordination compoundsPlatinum
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One-dimensional oxalato-bridged copper(II) complex possessing two structurally different metallic centres

2001

Abstract The crystal structure of the oxalato-bridged copper(II) compound [Cu2(μ-ox)2(ampy)3]n 1 (ox=oxalate dianion, ampy=2-amino-3-methylpyridine) consists of infinite corrugated one-dimensional chains in which two types of copper(II) centres, five- and six-coordinated, are bridged sequentially by asymmetric bis-bidentate oxalato ligands. Magnetic susceptibility measurements show the occurrence of a significant intrachain antiferromagnetic coupling (J=−22.9 cm −1 ) .

Copper complexChemistryInorganic chemistrychemistry.chemical_elementCrystal structureCopperMagnetic susceptibilityOxalateAntiferromagnetic couplingInorganic ChemistryMetalCrystallographychemistry.chemical_compoundvisual_artMaterials Chemistryvisual_art.visual_art_mediumPhysical and Theoretical ChemistryInorganic Chemistry Communications
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Multifunctional coordination polymers based on copper with modified nucleobases, easily modulated in size and conductivity.

2019

This Accepted Manuscript will be available for reuse under a CC BY-NC-ND licence after 24 months of embargo period

Models MolecularNanoprocessingCoordination polymerPolymersSupramolecular chemistrychemistry.chemical_elementConductivity010402 general chemistry01 natural sciencesBiochemistryOxalateNucleobaseInorganic Chemistrychemistry.chemical_compoundBipyridineCoordination ComplexesCoordination polymerNucleobasesMolecular Structure010405 organic chemistryChemistryHydrogen bondQuímicaCopperMagnetic and electrical properties0104 chemical sciencesCrystallographyCopperJournal of inorganic biochemistry
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Asymmetric and Symmetric Dicopper(II) Paddle-Wheel Units with Modified Nucleobases

2015

New copper(II) paddle-wheel complexes with different modified nucleobases and simple molecules in the axial positions have been prepared by direct reactions between copper(II) salts and the corresponding uracil- or thymine-1-acetic acids under inert atmosphere to produce the two homoleptic complexes, [Cu2(μ-OOCCH2-T)4(G)2] and [Cu2(μ-OOCCH2-U)4(G)2], and the heteroleptic one [Cu2(μ-OOCCH2-T)2(μ-OOCCH2-U)2(G)2] (where OOCCH2-T = thymine-1-acetate, OOCCH2-U = uracil-1-acetate, and G = dimethylformamide, water, dimethylacetamide, or dimethyl sulfoxide). Interestingly, the crystal structures of this family of closely related molecules present significant differences in their supramolecular arra…

ChemistryStereochemistryBase pairSupramolecular chemistryGeneral ChemistryCrystal structureCondensed Matter PhysicsNucleobaseCrystallographychemistry.chemical_compoundPaddle wheelDimethylformamideMoleculeGeneral Materials ScienceHomolepticCrystal Growth & Design
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Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer (Adv. Mater. 15/2013)

2013

Solventchemistry.chemical_compoundMaterials sciencechemistryMechanics of MaterialsCoordination polymerMechanical EngineeringDelaminationGeneral Materials ScienceComposite materialAdvanced Materials
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CCDC 949552: Experimental Crystal Structure Determination

2013

Related Article: Pilar Amo-Ochoa, Oscar Castillo, Carlos J. Gómez-García, Khaled Hassanein, Sandeep Verma, Jitendra Kumar, and Félix Zamora|2013|Inorg.Chem.|52|11428|doi:10.1021/ic401758w

catena-[bis(mu~3~-3-(24-dioxo-34-dihydropyrimidin-1-yl)propanoato)-bis(mu~3~-hydroxy)-bis(mu~2~-aqua)-dichloro-tri-copper]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1415834: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Oscar Castillo, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Cryst.Growth Des.|15|5485|doi:10.1021/acs.cgd.5b01110

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(mu-(24-dioxo-34-dihydropyrimidin-1(2H)-yl)acetato)-bis(dimethyl sulfoxide)-di-copper(ii) dimethyl sulfoxide solvate
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CCDC 883365: Experimental Crystal Structure Determination

2013

Related Article: Almudena Gallego, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J. Gómez-García, Eva Mateo-Martí, José I. Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora|2013|Adv.Mater.|25|2141|doi:10.1002/adma.201204676

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu2- 22'-Disulfanediyldipyrimidine)-(mu2-chloro)-copper methanol solvate]Experimental 3D Coordinates
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CCDC 949551: Experimental Crystal Structure Determination

2013

Related Article: Pilar Amo-Ochoa, Oscar Castillo, Carlos J. Gómez-García, Khaled Hassanein, Sandeep Verma, Jitendra Kumar, and Félix Zamora|2013|Inorg.Chem.|52|11428|doi:10.1021/ic401758w

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu3-hydroxy)-bis(mu2-thymine-1-acetato)-bis(mu2-thymine-1-acetato)-diaqua-tri-copper(ii) tetrahydrate]Experimental 3D Coordinates
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CCDC 1583018: Experimental Crystal Structure Determination

2018

Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetraaqua-tris(mu-2-sulfanylbenzene-1-sulfinato)-(mu-benzene-12-dithiolato)-di-palladium-di-potassium unknown solvate]Experimental 3D Coordinates
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CCDC 1047310: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-iodo)-(isonicotinic acid)-copper(i)]Experimental 3D Coordinates
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CCDC 1582338: Experimental Crystal Structure Determination

2018

Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103

Space GroupCrystallographyCrystal SystemCrystal Structurehexakis(tetrahydrofuran)-potassium bis(36-dichlorobenzene-12-dithiolato)-platinum(iii)Cell ParametersExperimental 3D Coordinates
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CCDC 1415833: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Oscar Castillo, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Cryst.Growth Des.|15|5485|doi:10.1021/acs.cgd.5b01110

bis(mu-(5-Methyl-24-dioxo-34-dihydropyrimidin-1(2H)-yl)acetato)-bis(mu-(24-dioxo-34-dihydropyrimidin-1(2H)-yl)acetato)-bis(NN-dimethylformamide)-di-copper(ii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 921188: Experimental Crystal Structure Determination

2013

Related Article: Pilar Amo-Ochoa, Simone S. Alexandre, Samira Hribesh, Miguel A. Galindo, Oscar Castillo, Carlos J. Gómez-García, Andrew R. Pike, José M. Soler, Andrew Houlton, Ross W. Harrington, William Clegg, Félix Zamora|2013|Inorg.Chem.|52|5290|doi:10.1021/ic400237h

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu2-2-amino-9H-purine-6-thiolato)-cobalt(ii)]Cell ParametersExperimental 3D Coordinates
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CCDC 883368: Experimental Crystal Structure Determination

2013

Related Article: Almudena Gallego, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J. Gómez-García, Eva Mateo-Martí, José I. Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora|2013|Adv.Mater.|25|2141|doi:10.1002/adma.201204676

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(mu~3~-chloro)-tetrakis(22'-disulfanediyldipyrimidine)-tetra-copper(i)
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CCDC 1401258: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal Systemcatena-[(mu-iodo)-(mu-methyl isonicotinate)-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1415830: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Oscar Castillo, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Cryst.Growth Des.|15|5485|doi:10.1021/acs.cgd.5b01110

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-(5-Methyl-24-dioxo-34-dihydropyrimidin-1(2H)-yl)acetato)-bis(NN-dimethylformamide)-di-copper(ii) NN-dimethylformamide solvateExperimental 3D Coordinates
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CCDC 1583017: Experimental Crystal Structure Determination

2018

Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-aqua)-bis(mu-2-sulfanylbenzenesulfinato)-bis(tetrahydrofuran)-palladium-di-potassium]Experimental 3D Coordinates
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CCDC 980426: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu2-Bromo)-(mu2-bis(2-pyrimidyl)disulfide)-copper(i) acetonitrile solvate)Experimental 3D Coordinates
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2017

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-aqua)-bis(mu-benzene-12-dithiolato)-nickel-di-potassium]Experimental 3D Coordinates
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CCDC 980427: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographycatena-(bis(mu~3~-Bromo)-(mu~2~-22'-disulfanediyldipyrimidine)-di-copper(i))Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-aqua)-bis(mu-2-sulfanylbenzenesulfinato)-bis(tetrahydrofuran)-platinum-di-potassium]Experimental 3D Coordinates
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2015

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Space GroupCrystallographyCrystal Systemcatena-[(mu-iodo)-(mu-methyl isonicotinate)-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-iodo)-(methyl isonicotinate)-copper(i)]Experimental 3D Coordinates
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CCDC 921191: Experimental Crystal Structure Determination

2013

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(2-amino-9-pentofuranosyl-9H-purine-6-thiolato)-bis(2-amino-9-pentofuranosyl-19-dihydro-6H-purine-6-thione)-cobalt(iii) sulfate trihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 921190: Experimental Crystal Structure Determination

2013

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tris(2-amino-9-pentofuranosyl-9H-purine-6-thiolato)-cobalt(iii) sesquihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(Triphenylphosphoranyl)iminium tetrakis(mu2-thiobenzoato)-chloro-nickel-platinum dichloromethane solvate hemihydrateExperimental 3D Coordinates
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CCDC 980424: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographycatena-((mu2-Chloro)-bis(mu2-22'-disulfanediyldipyrimidine)-dichloro-di-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1551944: Experimental Crystal Structure Determination

2017

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CCDC 1934515: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu-44'-bipyridine)-bis(mu-thymine-1-acetato)-di-copper(i)]Cell ParametersExperimental 3D Coordinates
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CCDC 1047309: Experimental Crystal Structure Determination

2015

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2013

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestris(2-amino-9-(4-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-19-dihydro-6H-purine-6-thione)-cobalt(iii) dinitrate dihydrate
researchProduct

CCDC 949549: Experimental Crystal Structure Determination

2013

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CCDC 980425: Experimental Crystal Structure Determination

2014

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2013

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2015

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2015

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researchProduct

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2013

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2014

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2017

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2013

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researchProduct

CCDC 1583016: Experimental Crystal Structure Determination

2018

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researchProduct

CCDC 980428: Experimental Crystal Structure Determination

2014

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2015

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researchProduct

CCDC 883366: Experimental Crystal Structure Determination

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researchProduct

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researchProduct

CCDC 1415829: Experimental Crystal Structure Determination

2015

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researchProduct

CCDC 1496195: Experimental Crystal Structure Determination

2017

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