New Polylactic Acid Composites Reinforced with Artichoke Fibers

2015

In this work, artichoke fibers were used for the first time to prepare poly(lactic acid) (PLA)-based biocomposites. In particular, two PLA/artichoke composites with the same fiber loading (10% w/w) were prepared by the film-stacking method: the first one (UNID) reinforced with unidirectional long artichoke fibers, the second one (RANDOM) reinforced by randomly-oriented long artichoke fibers. Both composites were mechanically characterized in tensile mode by quasi-static and dynamic mechanical tests. The morphology of the fracture surfaces was analyzed through scanning electron microscopy (SEM). Moreover, a theoretical model, i.e., Hill's method, was used to fit the experimental Young's modu…

A review on basalt fibre and its composites

2015

Abstract In recent years, both industrial and academic world are focussing their attention toward the development of sustainable composites, reinforced with natural fibres. In particular, among the natural fibres (i.e. animal, vegetable or mineral) that can be used as reinforcement, the basalt ones represent the most interesting for their properties. The aim of this review is to illustrate the results of research on this topical subject. In the introduction, mechanical, thermal and chemical properties of basalt fibre have been reviewed. Moreover, its main manufacturing technologies have been described. Then, the effect of using this mineral fibre as reinforcement of different matrices as po…

Bending test for capturing the fractional visco-elastic parameters: theoretical and experimental investigation on giant reeds

2014

In this paper attention is devoted on searching a proper model for characterizing the behavior of giant reeds. To aim at this, firstly, meticulous experimental tests have been performed in the Laboratory of structural materials of University of Palermo. Further, the novel aspect of this paper is that of using an advanced Euler-Bernoulli model to fit experimental data of bending tests. Such a model of continuum beam takes into account different constitutive laws of visco-elasticity, being real materials visco-elastic.

Salt spray fog ageing of hybrid composite/metal rivet joints for automotive applications

2017

Abstract The present experimental investigation aims to investigate the effect of salt-fog exposition on the mechanical behaviour of composite/metal riveted joints. To this aim, two kinds of joint were exposed to salt-fog environmental conditions according to ASTM B117 standard, for fifteen weeks. In particular, two composite laminates (i.e. glass fibre and carbon fibre/epoxy composites) were used as composite substrate joined with the metal substrate (i.e. aluminium alloy Al 6060). Single-lap shear tests were carried out in order to evaluate the evolution of the mechanical performances and the damage mechanisms of the riveted joints during the ageing exposition. The results evidence that t…

Sustainable recycling technologies for thermoplastic polymers and their composites: A review of the state of the art

2022

This review article discusses the environmental and economic effects of recycling, as well as sustainable thermoplastic polymer recycling technologies. Several researchers have utilized recycled thermoplastics as matrices in the production of a variety of natural and synthetic-based composites, which is also the focus of this study. All of the industries (food and packaging, construction and building, transportation, and indoor usage) where recycled thermoplastics have a large market share (food and packaging, construction and building, transportation, and indoor usage) are covered in this review. The desirable properties of thermoplastic polymers, such as corrosion resistance, low density,…

Drilling characteristics and properties analysis of fiber reinforced polymer composites: A comprehensive review

2023

Fiber-reinforced polymer (FRP) composites play a vital role in the production of structural and semi-structural components for engineering applications. The drilling process is a commonly employed machining process for FRP composites to join the FRP structural elements. Usually, the FRP composites possess a heterogeneous nature because of their multi-layered structure, hybridization, and the presence of multi-phase materials. Hence, common problems like delaminations, fuzzing, buckling, cracking, matrix and fiber burning occur during the drilling operations. These problems cause dimensional inaccuracy, poor surface finish, and tool wear and reduce the mechanical strength of the composites. …

Effect of areal weight and chemical treatment on the mechanical properties of bidirectional flax fabrics reinforced composites

2010

Abstract In this paper several bidirectional flax fibers, usually used to made curtains, were employed as reinforcement of an epoxy matrix. Four different laminates were made by a vacuum bagging process, with varying both the areal weight and the treatment of the fabric. These structures were mechanically investigated carrying out both tensile and three point flexural tests. In order to evaluate the effect of the identified variables on the mechanical parameters (i.e. Young modulus and maximum stress) a statistical analysis was performed. Finally, by comparing the flax composite with a glass one, the convenience of the replacement of glass fiber was investigated in term of cost, weight and …

Flax, Basalt, E-Glass FRP and Their Hybrid FRP Strengthened Wood Beams: An Experimental Study

2019

In this study, the structural behavior of small-scale wood beams externally strengthened with various fiber strengthened polymer (FRP) composites (i.e., flax FRP (FFRP), basalt FRP (BFRP), E-glass FRP (&ldquo

Epoxy resins as a matrix material in advanced fiber-reinforced polymer (FRP) composites

2013

Abstract: This chapter discusses the epoxy resins which, thanks to their good and versatile properties, can be considered nowadays the most important class of thermosetting polymers. In particular the chapter first reviews both the epoxy resins commonly available on the market, including a new class of bio-derived epoxy resins, and the most-used curing agents. it then describes the principal characteristics of the epoxy resins and how it is possible to enhance them by adding several fillers to the epoxy system. Finally, the chapter analyzes the main engineering fields in which epoxy resins find application today and their possible future utilization.

PLA based biocomposites reinforced with Arundo donax fillers

2014

Abstract In this work, for the first time, a natural and almost inexpensive filler obtained by grinding the culms of Arundo donax was used to prepare PLA based biocomposites. The composites were prepared by melt compounding PLA with A. donax filler (ADF). The influence of the content and size of ADF on the morphology and on the mechanical and thermal properties of PLA–ADF composites was evaluated. Moreover, ADF was extracted from composites to evaluate the effect of processing on morphology and dimensions of the incorporated filler. Furthermore, the experimental elastic moduli of the biocomposites have been fitted, employing two theoretical models, i.e., Hill and Halpin–Tsai. The results sh…

Multifunctional polyurethane foams with thermal energy storage/release capability

2020

In this work, polyurethane (PU) insulating panels containing different amounts of a microencapsulated paraffin with a nominal melting temperature of 24 °C, used as phase change material (PCM), were produced. The resulting panels behaved as multifunctional materials able to thermally insulate and simultaneously storing/releasing thermal energy near room temperature. The panels were characterized from a microstructural, thermal and mechanical point of view. Viscosity measurements highlighted an increase in the viscosity values of the PU liquid precursors due to the addition of the capsules, and this could lead to some difficulties during the production stages, especially in the mixing and foa…

Effectiveness of sodium acetate treatment on the mechanical properties and morphology of natural fiber-reinforced composites

2021

This paper aims to investigate the ability of an eco-friendly and cheap treatment based on sodium acetate solutions to improve the mechanical properties of flax fiber-reinforced composites. Flax fibers were treated for 5 days (i.e., 120 h) at 25 °C with mildly alkaline solutions at 5%, 10% and 20% weight content of the sodium salt. Quasi-static tensile and flexural tests, Charpy impact tests and dynamical mechanical thermal (DMTA) tests were carried out to evaluate the mechanical properties of the resulting composites. Fourier transform infrared analysis (FTIR) was used to evaluate the chemical modification on the fibers surface due to the proposed treatment, whereas scanning electron micro…

Creep Behavior of Poly(lactic acid) Based Biocomposites

2017

Polymer composites containing natural fibers are receiving growing attention as possible alternatives for composites containing synthetic fibers. The use of biodegradable matrices obtained from renewable sources in replacement for synthetic ones is also increasing. However, only limited information is available about the creep behavior of the obtained composites. In this work, the tensile creep behavior of PLA based composites, containing flax and jute twill weave woven fabrics, produced through compression molding, was investigated. Tensile creep tests were performed at different temperatures (i.e., 40 and 60 °C). The results showed that the creep behavior of the composites is strongly inf…

Lemongrass Plant as Potential Sources of Reinforcement for Biocomposites: A Preliminary Experimental Comparison Between Leaf and Culm Fibers

2022

AbstractNowadays, the world requires more sustainable and eco-friendly materials to replace or limit the usage of synthetic materials. Moreover, several researchers focused their attention on the use of agricultural sources as reinforcement for biocomposites since they are abundant, cost-effective and environmentally favorable sources. In such a context, purpose of the present paper is the evaluation of lemongrass plant (Cymbopogon flexuosus) as possible source of natural reinforcement for biocomposites. To this aim, natural fibers were obtained from the leaf and the stem of lemongrass and their main properties were compared for the first time. To this scope, mechanical and thermal characte…

Dynamic Mechanical Behavior Analysis of Flax/Jute Fiber-Reinforced Composites under Salt-Fog Spray Environment

2020

Over the last decades, natural fiber-reinforced polymer composites (NFRPs) gained great attention in several engineering fields thanks to the reduction of the environmental impact and the end-of-life cost disposal. Unfortunately, the use of NFRPs is limited, mainly due to their weak resistance against humid environments. Since limited literature is available about the evolution of the dynamic mechanical response of NFRPs under aggressive environments, this paper aims to investigate the damping properties of flax, jute and flax/jute epoxy composites exposed to salt-fog up to 60 days. Furthermore, sodium bicarbonate fiber treatment was performed to improve the composites&rsquo

Experimental design of the bearing performances of flax fiber reinforced epoxy composites by a failure map

2018

Abstract This paper represents the first effort aimed to the investigation of the pin/hole contact stress and failure mechanisms of epoxy composites reinforced with woven flax fabrics, underwent to tensile bearing tests. In particular, the maximum loads and failure modes are evaluated at varying the laminate geometrical configuration. In order to optimize the use of polymer composites reinforced with flax fibers in structural applications, an experimental failure map, identifying main failure modes of mechanically fastened joints, is obtained as function of hole diameter, distance of the hole from the free edge of the laminate and laminate width. Moreover, a theoretical approach based on th…

Effect of external basalt layers on durability behaviour of flax reinforced composites

2016

Abstract Aim of this work is to evaluate the influence of external layers of basalt-mat on the durability behaviour of flax reinforced epoxy composites. To this scope, long-term ageing tests were performed on two different laminates in critical environmental conditions. The first laminate, named Flax, was constituted by stacking ten layers of bidirectional flax fabrics. The second one, named Flax–Basalt, was produced by replacing two external flax layers with two layers of basalt mat for each side of the laminate. Both laminates were exposed to salt-fog environmental conditions, according to ASTM B 117 standard, for 60 days. Five samples per laminate were removed from salt-fog spray chamber…

A new eco-friendly chemical treatment of natural fibres: Effect of sodium bicarbonate on properties of sisal fibre and its epoxy composites

2016

Abstract Several researchers have shown how sisal fibres possess remarkable tensile properties that yield them good candidates as reinforcement in biocomposite materials. This work aims to evaluate the effect of an eco-friendly and cost effective surface treatment method based on the use of commercial sodium bicarbonate (i.e. baking soda) on properties of sisal fibre and its epoxy composites. In particular, raw sisal fibres were treated with a 10%w/w of sodium bicarbonate solution for different periods (24, 120 and 240 h), at room temperature. Changes occurring in sisal fibres were characterized through scanning electron microscope, Fourier transform infrared spectroscopy, thermogravimetric…

Pull-off adhesion of hybrid glass-steel adhesive joints in salt fog environment

2016

The aim of this paper was to evaluate the durability behaviour of glass/steel adhesive joints exposed to salt fog environmental conditions for ten weeks, according to ASTM B117 standard. To this scope, pull-off mechanical tests were carried out in order to evaluate the performances evolution and damage phenomena of the adhesive joints during the ageing exposition. Two different types of adhesives were compared (i.e. epoxy and polyurethane ones). Moreover, the effects of the glass surface condition and the presence of a basalt mat layer within the adhesive thickness were evaluated. The mechanical performances were related with the occurred failure mechanisms. Epoxy-based joints showed higher…

Aging resistance of bio-epoxy jute-basalt hybrid composites as novel multilayer structures for cladding

2017

Abstract Aging resistance of jute reinforced laminates is compared with two jute/basalt hybrid laminates prepared with different stacking sequences (i.e., sandwich and intercalated configuration). To this aim, composites are exposed to cyclic conditions comprising hygrothermal stress and UV radiation to promote an accelerated aging, for a period of 84 days. Specimens of each laminate are tested after 14, 28, 56 and 84 days, respectively. Quasi-static flexural tests, Charpy impact tests and dynamic mechanical tests are performed according to international ASTM and ISO standards. Furthermore, scanning electron microscopy and differential scanning calorimetry are used to evaluate the morpholog…

A simplified predictive approach to assess the mechanical behavior of pinned hybrid composites aged in salt-fog environment

2020

Abstract Aim of this paper is to assess the predictive capabilities of a simplified theoretical approach on the failure load of aged pinned hybrid composites. In particular, the mechanical performances of glass-flax hybrid epoxy laminates exposed to salt spray fog environment, were used as input data in order to address the analytical model. Preliminarily, the relationship among mechanical performances, failure mechanisms, joint geometry and ageing time, was evaluated by double-lap joint tests on pinned samples at varying joint geometry and ageing time. The bearing and shear out limit stress of samples aged for 60 days under the salt-fog environment underwent a reduction of about 20% compar…

Failure Map of Composite Laminate Mechanical Joint

2007

The aim of this research is to investigate the pin/hole contact stress of a composite laminate and failure modes when submitted to tensile bearing tests. The limit loads and failure modes are evaluated as a function of pin diameter and hole position. Analyzing the joint geometry effect on the fracture mechanisms, a failure map is obtained, identifying three regions of typical failure modes of mechanically fastened joints. A theoretical approach is proposed to identify the field of each fracture mode to obtain a simple experimental methodology to support the design of a particular joint laminate. In addition, a simplified numerical model is proposed to evaluate near the hole the stress/stra…

Effect of glass fiber hybridization on the durability in salt-fog environment of pinned flax composites

2021

The aim of the present paper is to evaluate the effect of the hybridization with external layers of glass fibers on the durability of flax fiber reinforced composites in severe aging conditions. To this scope, full glass, full flax and hybrid glass–flax pinned laminates were exposed to a salt-fog environment for up to 60 days. Double-lap pinned joint tests were performed to assess the pin-hole joints performances at varying the laminate stacking sequence. In order to better discriminate the relationship between the mechanical behavior and the fracture mechanisms of joints at increasing the aging time, different geometries (i.e., by varying both the hole diameter D and the free edge distance…

Manufacture of marine composite sandwich structures

2016

Abstract The aim of this chapter is to present the main processes of manufacture of composite sandwich structures used in marine applications. In the introduction, sandwich structure classification and properties and advantages/disadvantages in their uses are presented. In the second and third section, the main used technologies to made sandwich are, respectively, described and compared. Then, the goodness of these techniques is evidenced with the discussion of some experimental results obtained by the authors in their studies. The last section concludes with a thorough list of the future trends.

Durability of Basalt/Hemp Hybrid Thermoplastic Composites

2019

The Achilles heel of thermoplastic natural fibre composites is their limited durability. The environmental degradation of the mechanical properties of hemp and hemp/basalt hybrid-reinforced high-density polyethylene (HDPE) composites has been investigated with a special focus on the effects of water ageing and accelerated ageing, including hygrothermal and UV radiation. Modification of the matrix was carried out using a maleic anhydride high-density polyethylene copolymer (MAPE) as a compatibilizer. Hybridization of hemp fibres with basalt fibres and the incorporation of MAPE were found to significantly decrease the water uptake (up to 75%) and increase the retention of mechanical propertie…

Influence of resin viscosity and vacuum level on mechanical performance of sandwich structures manufactured by vacuum bagging

2010

The choice of process parameters is critical in optimizing the mechanical properties of sandwich structures produced using the vacuum bagging technique. The aim of this paper is to analyze how the viscosity of the resin/curing agent system and the vacuum level influence the morphology and the mechanical behavior of sandwich beams with composite faces (epoxy resin and glass fiber fabric named COMBI 900) and a PVC foam core. Four different sandwich structures were produced by varying the viscosity of the epoxy resin/curing agent at constant maximum vacuum pressure. Three further structures were manufactured by varying the strength of the vacuum with the resin viscosity maintained constant at …

The effects of water absorption and salt fog exposure on agglomerated cork compressive response

2022

The replacement of synthetic foams with agglomerated cork in sandwich composites can meet the increasing environmental concerns. Its peculiar morphology and chemical composition lead to outstanding dimensional recovery that endorsed a broad investigation of its compressive behavior. The knowledge of neat material response is fundamental to obtain a reliable design dataset, but it is necessary to consider all the environmental factors (water, moisture and sunlight) that significantly modify material mechanical properties. In view of this, the present work investigates the effect of distilled and seawater absorption and salt fog exposure on the compressive behavior of two agglomerated corks w…

Effect of sodium bicarbonate treatment on mechanical properties of flax-reinforced epoxy composite materials

2017

This paper deals with the evaluation of the effect of an eco-friendly and cost-effective surface treatment based on the use of sodium bicarbonate on the mechanical properties of flax-reinforced epoxy composites. To this aim, unidirectional fabrics were soaked for five days in 5 and 10% in weight of sodium bicarbonate solution at 25℃. Quasi-static and dynamic mechanical tests were performed and the fracture surfaces of the composites were analyzed through scanning electron microscopy. Results evidenced that this treatment improves the fiber–matrix adhesion thus increasing the performances of the composites. Treating the fabrics with 10% w/w of bicarbonate solution leads to improvements of ∼…

Effect of silane coupling treatment on the adhesion between polyamide and epoxy based composites reinforced with carbon fibers

2020

The increasing efforts aimed to design structures with reduced weight and better mechanical performances has led in recent years to a growing use of fiber reinforced polymer materials in several fields such as marine. However, these materials can be composed of chemically very different elements and, hence, may be difficult to joint. This research aims to improve the adhesion between a thermoplastic matrix of polyamide reinforced with short carbon fibers (PA12-CR) and a carbon fiber reinforced epoxy matrix (CFRP). Two different silane coupling agents, (3-Aminopropyl)trimethoxysilane (AM) and (3-Glycidyloxypropyl)trimethoxysilane (EP), were applied, through the spray deposition method, on th…

Evaluation of continuous filament mat influence on the bending behaviour of GFRP pultruded material via Electronic Speckle Pattern Interferometry

2017

Abstract Pultrusion is a process allowing the production of unidirectional (roving) fibre-reinforced polymer (FRP) structural elements with constant cross section. Recently, also civil engineers focused their attention on pultruded composite materials as alternative to traditional ones (e.g., concrete, steel). Furthermore, to improve the transverse strength and stiffness with respect to the fibres direction, continuous filament mat (CFM) is often placed within the stacking sequence. The CFM influence on the global mechanical behaviour is not considered by appropriate actual international standards. In this paper, the influence of the CFM layers on the mechanical behaviour of glass fibres pu…

A systematic literature review on less common natural fibres and their biocomposites

2018

Abstract Interest in utilization of renewable resources is increasing because of public's environmental awareness and economic considerations. Lignocellulosic fibres have already attracted growing attention as reinforcement of polymeric matrices instead of synthetic ones (mainly glass) from the academic and industrial fields. In addition to kenaf, hemp, sisal, flax and jute, which are the subject of extensive investigations for composite applications since the 1970s, in the last years several researchers suggested the use of less common natural fibres, due to their low cost and availability. This paper reviews the extraction methods, chemical, morphological, thermal and mechanical propertie…

Mechanical behavior of carbon/flax hybrid composites for structural applications

2012

In this work, the influence of an unidirectional carbon fabric layer on the mechanical performances of bidirectional flax fabric/epoxy composites used for structural applications was studied. Two different bidirectional flax fabrics were used to produce flax fabric reinforced plastic (FFRP) laminates by a vacuum bagging process: one is normally used to make curtains; the other, heavier and more expensive than the previous one, is usually used as reinforcement in composite structures. In order to realize hybrid structures starting from FFRP, an unidirectional UHM carbon fabric was used to replace a bidirectional flax fabric. Tensile and three-point bending tests were performed to evaluate t…

On the mechanical behavior of BFRP to aluminum AA6086 mixed joints

2013

The aim of this work is to analyze the possibility to join aluminum alloy AA6086 and composite laminates reinforced with basalt fibers, an innovative material which use is growing in several applications as an alternative to glass fibers. To this goal, three joining techniques were investigated: mechanical by Self Piercing Riveting (in the next called SPR), adhesive by co-curing technique and mixed in which the joining techniques (i.e. adhesive and mechanical) were combined. Two manufacturing technologies (i.e. hand lay-up and vacuum bagging) were used both to produce composite substrates and to realize co-curing adhesion between the substrates to be joined. Mixed joints were realized by in…

On the response of flax fiber reinforced composites under salt-fog/dry conditions: Reversible and irreversible performances degradation

2022

Abstract Despite their scarce resistance to humid or wet conditions, natural fiber reinforced composites (NFRCs) seem to be able to partially recover their performances under discontinuous exposition to marine environment. To investigate this peculiarity, flax fiber reinforced composite was at first subjected to salt-fog spray condition at 35 °C for 15 and 30 days, respectively, and then stored in ‘‘dry” condition (i.e., 50% R.H. and 22 °C) between 0 and 21 days. The performances evolution was evaluated through flexural tests, water uptake and contact angle measurements. Moreover, the morphology of fractured mechanical samples was examined by using 3D optical microscope and scanning electro…

Pinned hybrid glass-flax composite laminates aged in salt-fog environment: Mechanical durability

2019

The aim of the present paper is to study the mechanical performance evolution of pinned hybrid glass-flax composite laminates under environment aging conditions. Hybrid glass-flax fibers/epoxy pinned laminates were exposed to salt-spray fog environmental conditions up to 60 days. With the purpose of assessing the relationship between mechanical performances and failure mechanisms at increasing aging time, single lap joints at varying joint geometry (i.e., hole diameter D and hole distance E from free edge) were characterized after 0 days (i.e., unaged samples), 30 days, and 60 days of salt-fog exposition. Based on this approach, the property&ndash

Characterization of a new natural fiber from Arundo donax L. as potential reinforcement of polymer composites.

2013

Abstract The aim of this paper is to study the possibility of using of Arundo donax L. fibers as reinforcement in polymer composites. The fibers are extracted from the outer part of the stem of the plant, which widely grows in Mediterranean area and is diffused all around the world. To use these lignocellulosic fibers as reinforcement in polymer composites, it is necessary to investigate their microstructure, chemical composition and mechanical properties. Therefore, the morphology of A. donax L. fibers was investigated through electron microscopy, the thermal behavior through thermogravimetric analysis and the real density through a helium pycnometer. The chemical composition of the natura…

Speckle Interferometry Analysis of Full-bending Behavior of GFRP Pultruded Material

2016

Abstract The use of Glass Fiber Reinforced Polymer materials (GFRP) has increased in the last years even among civil structural engineering due to their high specific strength, lightweight and excellent corrosion resistance. With application of the pultrusion method, the manufacture of large-scale profiles with various cross-section forms became potentially possible with relatively low costs. Usually two different technological approaches are available to realize the element: in the first one a mat-roving-mat sequence is adopted, in the second one only roving is present. Continuous filament mat (CFM, fibers distributed randomly in all directions) is often used to build up laminate thickness…

Effect of Sheep Wool Fibers on Thermal Insulation and Mechanical Properties of Cement-Based Composites

2019

The use of sheep wool as a filler of cement in order to produce mortar or plaster involves several advantages for environment and energy. Moreover, it is considered as a waste and, therefore, its use is characterized by low cost. The aim of this paper is to evaluate the influence of wool fibers on thermal conductivity and mechanical properties of cement. The samples were prepared using wool fibers, obtained from a breed of Sicilian sheep, with three different lengths (i.e., 1, 6, and 20 mm). Furthermore, in order to evaluate the influence of fiber content, the samples were prepared by varying the fiber weight fraction. The thermal conductivity of the samples was analyzed by using a heat flo…

Experimental assessment of the improved properties during aging of flax/glass hybrid composite laminates for marine applications

2018

The investigation for natural fibers composites in terms of performance, durability, and environmental impact for structural applications in marine environments is a relevant challenge in scientific and industrial field. On this context, the aim of this work is to assess the durability and mechanical stability in severe environment of epoxy/glass–flax hybrid composites. For the sake of comparison, also full flax and glass epoxy composites were investigated. All samples were exposed to salt–fog environmental conditions up to 60 aging days. Wettability behavior during time was compared with water uptake evolution to assess water sensitivity of hybrid composite configurations. Moreover, quasi-…

Natural Fibres and Their Composites.

2020

Due to several promising properties, such as their low density and specific properties, low price, easy processing, health advantages, renewability and recyclability, increasing attention was paid in the last years to natural fibres as alternatives to synthetic counterparts for the reinforcement of polymeric based composites [...]

Three-Point Flexural Behaviour of GFRP Sandwich Composites: A Failure Map

2010

In this work, the failure mechanisms of GFRP/PVC foam core sandwich structures subjected to three-point bending are analysed. By varying the skin thickness (t ) and the span length between supports (l), experimental tests were carried out in order to find the relationship between the geometrical configuration of the sandwiches and the failure mechanism. By plotting failure mechanism on a graph of l against t , a failure map was created identifying the three typical failure mode regions of these sandwiches. The graph clearly shows the failure mode corresponding to each combination of l and t . To help optimise the use of these sandwich beams as structural elements, a theoretical failure mode…

Effects of natural fibres reinforcement in lime plasters (kenaf and sisal vs. Polypropylene)

2014

Nowadays the tendency to realize environment-friendly products is becoming more widespread to ensure sustainable and smart development. The synthetic fibres, frequently used, are harmful to the environment because they are non-degradable and non-renewable. Their use has resulted in an increase of oil consumption. Therefore, the possibility of replacing them with natural fibres becomes increasingly concrete confirmed by the researches and investigations carried out. In this work three lime based plasters were prepared and analysed to evaluate the influence on their performance of different fibres used as reinforcement. In particular each plaster was realised by adding to the mortar the same …

Effect of UD carbon on the specific mechanical properties of glass mat composites for marine applications

2009

In this work the influence of a uniaxial carbon fabric layer on the mechanical performances of a glass mat/epoxy composite used for marine applications has been studied. All the structures have been made, at room temperature, by vacuum bagging technique. Tension and flexural tests have been carried out in order to evaluate the specific mechanical properties of the composite and to compare these with those of the marine aluminium alloy 6016-T4. The glass composites have higher specific strength but lower specific modulus than aluminium alloy. To increase the specific modulus of the composites, each layer of glass mat has been replaced with a layer of uniaxial carbon fabric. In addition, a s…

Behavior in compression of concrete cylinders externally wrapped with basalt fibers

2015

Abstract This paper gives additional information on the use of new class of composites constituted by Basalt Fiber Reinforced Polymer (BFRP) bonded with epoxy resin to concrete specimens as an alternative confinement material for compressed concrete members with respect to carbon or glass fibers. From the experimental point of view, concrete cylinders are wrapped with continuous fibers, in the form of sheets, applying both full and partial discrete wrapping with BFRP straps, and then tested in compression. For comparison, few other concrete cylinders are wrapped with Carbon Fiber Reinforced Polymer (CFRP) sheets and tested in compression. The number and type of plies (full or partial wrappi…

On the influence of the initial ramp for a correct definition of the parameters of fractional viscoelastic materials

2014

Creep and/or Relaxation tests on viscoelastic materials show a power-law trend. Based upon Boltzmann superposition principle the constitutive law with a power-law kernel is ruled by the Caputo's fractional derivative. Fractional constitutive law posses a long memory and then the parameters obtained by best fitting procedures on experimental data are strongly influenced by the prestress on the specimen. As in fact during the relaxation test the imposed history of deformation is not instantaneously applied, since a unit step function may not be realized by the test machine. Usually an initial ramp is present in the deformation history and the time at which the deformation attains the maximum …

Effects of anodizing surface treatment on the mechanical strength of aluminum alloy 5083 to fibre reinforced composites adhesive joints

2021

Abstract In this study, the anodizing process based on the use of tartaric sulfuric acid solution (TSA) was carried out on metal substrate to evaluate for the first time its effect on the adhesion strength and corrosion resistance of aluminium alloy (i.e., AA5083) to fibre (i.e., basalt or glass) reinforced composite adhesive joints for nautical applications. Furthermore, some TSA anodized samples were soaked in a NaOH solution to investigate the influence of this post-immersion step on the joint performances. With the aim to improve the fibre-matrix adhesion in the composite substrate thus further increasing the overall mechanical response of the joint, glass and basalt fibres were treated…

Mechanical properties of basalt fiber reinforced composites manufactured with different vacuum assisted impregnation techniques

2016

Abstract This work describes an experimental mechanical characterisation campaign on composites made out of a quasi-unidirectional basalt fabric. In order to evaluate the ability of commercial basalt fabrics and their composites to meet the potentials of basalt fibers, the work has used raw materials from commercial catalogs with no further modification. Two common manufacturing techniques for medium performance composites have been adopted: vacuum assisted resin infusion, and hand-impregnated vacuum bagging. Two panels, one for each technique, have been fabricated, able to provide a sufficient number of samples for a comprehensive stiffness and strength characterization through Tensile, Fl…

Bending test for capturing the vivid behavior of giant reeds, returned through a proper fractional visco-elastic model

2015

Abstract This paper presents results of experimental investigations made to evaluate the vivid behavior of giant reed Arundo donax. In particular, attention was paid to the relationship between visco-elastic properties and moisture content, which is widely recognized as one of the key factor that influences the mechanical properties of all wood-based materials. To this aim, after a controlled drying treatment on samples of reed, stress relaxation tests in three point bending configuration were performed to evaluate the effects of moisture content on visco-elastic behavior of the giant reed. Further, the novel aspect of this paper is that of using an Euler–Bernoulli model embedded with an ad…

Environmentally Friendly Composites and Surface Treatments for Metal-to-Composite Hybrid Joints for Marine Application

2022

In this study, the use of natural fibres (flax and basalt) in combination with a recyclable epoxy matrix based on cleavable amines is suggested for improving the sustainability of marine industry. In addition, a new and eco-friendly anodizing process based on tartaric sulfuric acid solution (TSA) and a pore widening step in a NaOH aqueous solution was carried out on aluminium alloy (AA5083) to evaluate its effect on the adhesion strength and damage tolerance after low velocity impact of co-cured adhesive joints with a basalt fibre reinforced and recyclable laminate. The durability in marine environment was simulated by exposing samples to salt-fog spray conditions over a period of 90 days. …

Mechanical behaviour and failure modes of metal to composite adhesive joints for nautical applications

2010

In this paper, the influence of several parameters on the mechanical behaviour and failure modes of hybrid bonded joints aluminium/composite was investigated. Particularly, the effects of metallic surface condition, adhesive properties and thickness on single-lap joint resistance were analysed. To these aims, two adhesives were used and, for each adhesive, two different adhesive thicknesses (0.5 and 1.5 mm) have been investigated. Furthermore, two sets of joints for each adhesive kind and thickness were investigated: the former was obtained using aluminium blanks which were previously mechanically treated with sandpaper (P60) and the latter using aluminium treated with sandpaper and with pr…

Effect of plasma treatment on the properties of Arundo Donax L. leaf fibres and its bio-based epoxy composites: A preliminary study

2016

Abstract A preliminary investigation about the effect of plasma treatment on the properties of natural fibres extracted from the leaf of the giant reed Arundo Donax L. and their compatibility with a bio-based epoxy resin is performed. To this aim, the influence of plasma treatment on the functional groups and on the thermal behaviour of fibre were investigated using Fourier transform infrared spectroscopy and thermogravimetric analysis. Moreover, the mechanical characterization of fibres was performed through fibre tensile tests. Short randomly oriented fibres/bio-based epoxy composites were manufactured by hand lay-up method followed by compression moulding, varying both fibres weight cont…

Failure maps to assess bearing performances of glass composite laminates

2018

Aim of this article is the assessment of the bearing mechanical performances of pin-loaded glass laminates as function of their geometrical configuration. To this concern, 32 specimens having different hole diameter (D), laminate width (W), and hole center to laminate free edge distance (E) have been tested under bearing conditions. The maximum bearing stress and the stress-displacement curves were analyzed as function both of hole to laminate free edge distance E and hole diameter D. Moreover, an experimental 2D failure map was created by placing the experimental results (i.e., the kind of failure mechanism occurred for each geometrical configuration) in the plane E/D versus W/D ratios. In…

Structural and Mechanical Modification Induced by Water Content in Giant Wild Reed (A. donax L.)

2018

Giant wild reed Arundo donax L. is an aggressive agricultural species with remarkable features such as fast-growing, untapped economic potential, eco-friendliness, and high specific properties (e.g., high strength/weight and modulus/weight ratios). Here, the bending properties of giant reed were studied at a molecular level to evaluate the effect of the conditions used during the preparation for their applications (also referred to as treatment conditions). The aim was to achieve new information potentially useful to suggest new possible applications of A. donax L. for structural applications in modern buildings. In this study, green reeds collected in a Sicilian plantation were dried for 2…

Bearing strength and failure behavior of pinned hybrid glass-flax composite laminates

2018

Abstract The aim of the present work is to evaluate the influence of external layers of glass woven fabric on the pin-hole strength of flax/epoxy laminates. Single lap bearing tests were carried out to evaluate the fastened joint performances depending on laminate stacking sequence. In order to better identify the mechanical behavior of the hybrid laminate, full glass and flax laminates were also compared. In particular, bearing stress and failure mechanisms were investigated at varying joint geometry. Furthermore, an experimental failure map, clustering main failure modes of pinned hybrid composite laminate, was used to better clarify the relationship between mechanical failure and geometr…

Assessment of Arundo donax Fibers for Oil Spill Recovery Applications

2019

In the last years, natural fibers are increasingly investigated as an oil recovery system in order to overcome the oil spillage phenomena, thus preserving environment and aquatic life. In particular, lignocellulose-based fibers have recently been employed with promising results. In such a context, the aim of this paper is to assess the oil sorption capability of natural fibers extracted from the stem of the giant reed Arundo donax L., a perennial rhizomatous grass belonging to the Poaceae family that grows naturally all around the world thanks to its ability to tolerate different climatic conditions. Sorption tests in several pollutants and water as a reference were carried out. The fibers …

Effect of Plasma Treatment on Mechanical and Thermal Properties of Marble Powder/Epoxy Composites

2016

The aim of this work was to study the effect of the plasma treatment on the behavior of composite structures reinforced with marble powder, obtained as processing waste in the “Custonaci” basin. Moreover, different filler amounts (i.e. 10%wt, 20%, 30% in weight) were investigated. For the mechanical characterization, tensile and flexural quasi-static tests, Charpy impact test, and dynamic mechanical thermal analysis (DMTA) were performed. For the thermal stability, thermogravimetric analysis was carried out. Finally, real density and fraction of voids were measured. It was observed that untreated marble powder, on one hand, increases tensile and flexural stiffness and improves thermal stabi…

Effect of Stacking Sequence and Sodium Bicarbonate Treatment on Quasi-Static and Dynamic Mechanical Properties of Flax/Jute Epoxy-Based Composites

2019

The present paper deals with the investigation of quasi-static and dynamic mechanical response of epoxy-based composites reinforced with flax and/or jute plain weave fabrics. In order to evaluate the influence of the stacking sequence, two monolithic laminates reinforced with flax or jute fibers and two hybrid flax/jute laminates were manufactured through the vacuum infusion technique. Furthermore, an eco-friendly and cost-effective surface treatment based on fiber soaking in a sodium bicarbonate solution was employed to improve the fiber-matrix adhesion. The mechanical characterization (by means of quasi-static flexural, dynamic mechanical thermal analysis and Charpy impact tests) allowed …

A DIC-based study of flexural behaviour of roving/mat/roving pultruded composites

2015

Abstract This paper reports a study of the flexural behaviour and resultant failure modes in E-glass/polyester pultruded composites. The digital image correlation (DIC) method is used to estimate the effect of fibre orientation on failure behaviour in thick beams, taking into account the presence of continuous filament mat layer (CFM) in the stacking sequence. In particular, the tests were carried out for specimens with off-axis angle of 0°, 7.5°, 15°, 30°, 45° and 90°. The crack initiation and the failure mechanisms depend on the mutual interaction between the stiffness properties of different areas in the stacking sequence. An influence index (I) was introduced to evaluate the magnitude o…

Effects of aging in salt spray conditions on flax and flax/basalt reinforced composites: Wettability and dynamic mechanical properties

2016

Abstract In the last years, the industrial policies are more attentive to issues concerning sustainability, recycling and environmental care. Therefore, the use of natural fibres in composite materials has spread more and more. This paper deals with flax and basalt fibres within an epoxy matrix by investigating the wettability and the dynamic mechanical properties of the resulting composites, subjected to long-term aging tests in critical environmental conditions. The first laminate was constituted by stacking ten layers of bidirectional flax fabrics. The second one was produced by replacing two external flax layers with two layers of basalt mat, for each side of the laminate. Both laminate…

Static and dynamic mechanical properties of Arundo Donax fillers-epoxy composites

2014

Abstract Aim of this work is to investigate the feasibility of using a natural and inexpensive filler obtained by grinding the culms of Arundo Donax as reinforcement of epoxy resins. The effect of the content and size of Arundo Donax fillers on static and dynamic mechanical properties was evaluated showing that the composites exhibit higher tensile moduli, comparable flexural moduli and lower strength properties in comparison to the neat resin. Moreover, changes in the storage and the loss moduli only above the glass transition temperature (i.e. in the rubbery region) were found while neither significant shifts of tan δ peaks to higher temperatures nor reductions in the peak height of the c…

An aging evaluation of the bearing performances of glass fiber composite laminate in salt spray fog environment

2019

The aim of the present paper is to assess the bearing performance evolution of pinned, glass-composite laminates due to environmental aging in salt-spray fog tests. Glass fibers/epoxy pinned laminates were exposed for up to 60 days in salt-spraying, foggy environmental conditions (according to ASTM B117 standard). In order to evaluate the relationship between mechanical failure mode and joint stability over increasing aging time, different single lap joints, measured by the changing hole diameter (D), laminate width (W) and hole free edge distance (E), were characterized at varying aging steps. Based on this approach, the property-structure relationship of glass-fibers/epoxy laminates was a…

Influence of sodium bicarbonate treatment on the aging resistance of natural fiber reinforced polymer composites under marine environment

2019

Abstract Aim of the current study is to investigate how an innovative and eco-friendly chemical treatment based on sodium bicarbonate solution (10 wt%) can improve the aging resistance in marine environment of epoxy based composites, reinforced with flax and jute fibers. To this scope, treated and untreated fiber reinforced composites were manufactured through vacuum infusion technique. The resulting composites were then exposed to salt-fog spray conditions up to 60 days, according to ASTM B117 standard. The assessment of their durability was made by means of tensile, flexural quasi-static tests and Charpy impact tests. Furthermore, the water uptake evolution of each composite was monitored…

Salt-fog spray aging of jute-basalt reinforced hybrid structures. Flexural and low velocity impact response

2017

Abstract In this work, a study on the aging resistance of jute and jute-basalt interply hybrid laminates exposed to salt-fog is presented with the aim to investigate the possibility to enhance the durability of natural fiber reinforced composites for marine application by a ply-substitution approach. In particular, jute and basalt/jute reinforced composite plates were manufactured by vacuum assisted resin infusion in two different staking sequences (i.e., intercalated and sandwich-like basalt-jute) and aged under salt fog conditions. The effects of the accelerated aging at increasing times on the mechanical response of laminates were assessed in both quasi static (three point bending) and d…

New Lignocellulosic Aristida adscensionis Fibers as Novel Reinforcement for Composite Materials: Extraction, Characterization and Weibull Distributio…

2019

In this research, the Aristida adscensionis fibers (AAFs) were taken out from the plants and its fundamental properties anlayzed for the first time. The AAFs were characterized and compared with other natural fibers by the use of physico-chemical analysis and various characterization techniques such as FT-IR, XRD, NMR, TGA, SEM and AFM. Chemical analysis showed that A. adscensionis fibers have a high cellulose content of 70.78% whereas the contents of lignin and wax are equal to 8.91% and 2.26%, respectively. The FT-IR, XRD and NMR analysis confirmed that AAFs are rich in cellulose content with CI and CS equal to 58.9% and 11.5 nm, respectively. Pycnometer analysis allowed to estimate a den…

An Innovative Treatment Based on Sodium Citrate for Improving the Mechanical Performances of Flax Fiber Reinforced Composites

2021

The goal of this paper is to evaluate the effectiveness of a cost-effective and eco-friendly treatment based on the use of sodium citrate (Na3C6H5O7) on the mechanical properties of flax fiber reinforced composites. To this scope, flax fibers were soaked in mildly alkaline solutions of the sodium salt at different weight concentration (i.e., 5%, 10% and 20%) for 120 h at 25 °C. The modifications on fibers surface induced by the proposed treatment were evaluated through Fourier transform infrared analysis (FTIR), whereas scanning electron microscope (SEM) and helium pycnometer were used to obtain useful information about composites morphology. The effect of the concentration of the treating …

Glass-basalt/epoxy hybrid composites for marine applications

2011

Abstract The aim of this work is to evaluate the influence of uniaxial basalt fabric layers on the mechanical performances of a glass mat/epoxy composite used for marine applications. Polymer composites, reinforced by glass mat (GFRP), and hybrid ones, reinforced by glass mat and unidirectional basalt fabric, have been produced by vacuum bagging technique. Three points bending and tensile tests have been carried out in order to evaluate the effect of number and position of basalt layers on the mechanical properties of the investigated structures. The experimental tests have showed that the presence of two external layers of basalt involves the highest increase in mechanical properties of hy…

In situ monitoring of moisture uptake of flax fiber reinforced composites under humid/dry conditions

2021

The use of green materials such as natural fiber-reinforced composites represents an increasingly stringent prerogative in the future planning of industrial and non-industrial production. The optimization of these materials is the main aim of the current research, focused on the evaluation of the behavior of flax fiber reinforced composites exposed to isothermal adsorption and desorption cycles, at varying the partial pressure of water vapor (P/P0). For this purpose, the moisture uptake and the morphology changes of the composite material and their constituents were in situ monitored through a measurement protocol, by using a dynamic vapor sorption (DVS) analysis, coupled with an environmen…

Effect of curing time on the performances of hybrid/mixed joints

2013

Abstract The aim of this work is the study of a mixed method used for the joining of aluminum alloys with glass reinforced polymer’s substrates (in the next GFRP). In particular, the technique of self-piercing riveting (in the next SPR) was applied on a co-cured joint in order to evaluate the influence of the time of inserting the rivet on the mechanical behavior of the mixed joints. Three different joints were realized: adhesive by co-curing technique, mechanical by self piercing riveting (in the next SPR) and a mixed one in which the joining techniques (i.e. adhesive and mechanical) were combined. In particular, to determine the optimum time to insert the rivet, three different times from…

Surface Modified Arundo Donax Natural Fibers for Oil Spill Recovery

2021

The use of green materials for oil recovery applications is the goal to be achieved to reduce the environmental impact of these essential processes. In this context, Arundo Donax L. is a plant known for its wide uses whose absorbent properties have been previously investigated. In this paper, the influence of silane surface treatment on the absorbent behavior of natural fibers extracted from the culms of this eco-friendly and cost-effective material was assessed. A close correspondence has been identified between the physical characteristics of the investigated oil and the fiber size, by means of microstructural and morphological analysis. Excellent results have been achieved with an absorp…

Performances Recovery of Flax Fiber Reinforced Composites after Salt-Fog Aging Test

2022

In the present paper, the performance recovery under conditions of discontinuous exposure to a marine environment of a natural fiber-reinforced composite (NFRC) reinforced by flax fibers was assessed. In particular, this laminate was initially exposed to salt-fog for 15 and 30 days, and then stored in a controlled air condition for up to 21 days. The flax fiber-reinforced composite showed coupled reversible and irreversible aging phenomena during the wet stage, as well as evidencing a significant mechanical recovery during the dry stage. Unlike the stiffness, the laminate showed a noticeable recovery of its flexural strength. This behavior affected the composite material toughness. A simpli…

Evolution of the bearing failure map of pinned flax composite laminates aged in marine environment

2020

Abstract Aim of the present paper is to evaluate how the bearing behavior of pinned flax composites can be influenced by their exposition to critical environment such as marine one. To this scope, flax fibers/epoxy pinned laminate was exposed up to 60 days to salt-fog environment, according to ASTM B 117 standard. In particular, samples having different hole diameter (D), laminate width (W), and hole center to laminate free edge distance (E) have been tested under single lap bearing tests at varying the aging exposition time. Following this procedure, an experimental 2D failure map clustering main failure modes was created by placing the experimental results in the plane E/D versus W/D rati…

Arundo Donax Fibers as Green Materials for Oil Spill Recovery

2020

Oil spillage is considered one of the most devastating forms of pollution, for its effect on the environment, particularly on aquatic life. This kind of disaster can impact in two ways, directly caused by the polluting spilled oil or due to the cleanup process. In fact, oil floating on water does not allow sunlight to pass through and its toxicity puts the life of aquatic animals at risk. Furthermore, other factors can also contribute to this damage. In fact, a wrong oil recovery system can add a further pollution level. Polymer sorbents used for the oil spill recovery, if not properly treated, increase the level of marine and ground pollution. For this reason, in the last years, green mate…

Artichoke (Cynara cardunculus L.) fibres as potential reinforcement of composite structures

2011

Abstract The aim of this paper is to examine the use of artichoke fibres as potential reinforcement in polymer composites. The fibres are extracted from the stem of artichoke plant, which grows in Southern Sicily. In order to use these lignocellulosic fibres as potential reinforcement in polymer composites, it is fundamental to investigate their microstructure, chemical composition and mechanical properties. Therefore, the morphology of artichoke fibres was investigated through electron microscopy, the thermal behaviour through thermogravimetric analysis and the real density through a helium pycnometer. The chemical composition of the natural fibres in terms of cellulose, lignin, and ash co…

Evaluation of aging behavior under salt-fog spray conditions of green sandwich structures

2018

In this paper, the aging resistance of sandwich structures made with cork agglomerate as core and flax-reinforced polymeric laminates as face sheets was investigated for the first time. In order to evaluate their durability in a hostile environment, a sandwich plate was manufactured by vacuum bagging technique and aged under salt-fog spray conditions, according to ASTM B 117 standard. The evolution of the sandwich mechanical properties during the aging exposition was analyzed by carrying out quasi-static flexural tests and Charpy impact tests both on unaged specimens and on specimens aged for 10, 25, and 60 days, respectively. The quasi-static experimental results showed that despite the sa…

Synergistic effect of fiber content and length on mechanical and water absorption behaviors of Phoenix sp. fiber-reinforced epoxy composites

2016

Phoenix sp. fiber-reinforced epoxy composites have been manufactured using compression molding technique. The effect of reinforcement volume content (0%, 10%, 20%, 30%, 40%, and 50%) and size (300 µm particles, 10 mm, 20 mm, and 30 mm fibers) on quasi-static and dynamic mechanical properties was investigated. Moreover, the water absorption properties of composites were analyzed at different environmental conditions (10℃, 30℃, and 60℃). For each reinforcement size, composites loaded with 40% in volume show highest tensile and flexural properties. Furthermore, composites with 300 µm particles present the best impact properties and the lowest water absorption, regardless of the environmental …

The durability of basalt fibres reinforced polymer (BFRP) panels for cladding

2015

The study focuses on two basalt composite laminate panels for cladding, produced by means of vacuum bagging technique. In particular, unidirectional and random basalt fabrics, with different areal weights, using epoxy resin as matrix, were used. According to the ISO 15686 methodology for the evaluation of durability, samples were subjected to cycles of artificial aging in climatic chamber and outdoor exposure, carrying out mechanical (i.e. quasi-static and dynamic) and calorimetric tests. The results show the effectiveness over time of produced basalt composite laminates and the initial increase of the mechanical performances after the first steps of accelerated aging.

The effect of alkaline treatment on mechanical properties of kenaf fibers and their epoxy composites

2015

Abstract In this work, kenaf fibers were pre-treated in a NaOH solution (6% in weight) at room temperature for two different periods (48 and 144 h). The chemical treatment of kenaf fibers for 48 h allowed to clean their surface removing each impurity whereas 144 h of immersion time had detrimental effect on the fibers surface and, consequently, on their mechanical properties. Untreated and NaOH treated kenaf fibers (i.e. for 48 h) were also used as reinforcing agent of epoxy resin composites. The effect of the stacking sequence (i.e. using unidirectional long fibers or randomly oriented short fibers) and the chemical treatment on the static mechanical properties was evaluated showing that t…

Experimental assessment of the shield-to-salt-fog properties of basalt and glass fiber reinforced composites in cork core sandwich panels applications

2018

Abstract In this paper, the effect of salt-fog exposition on the mechanical behavior of sandwich panels having cork agglomerate core was investigated. In particular, the aim of this research work is to assess the shield function of unidirectional basalt and E-glass reinforced polymer on the aging and failure mechanism of the core when such class of material are destined to operate in hostile environments (e.g., marine environment). To do this, the manufactured sandwich panels were exposed up to 60 days to salt-fog environment, according to ASTM B 117 standard. Unaged and aged specimens were analyzed through three point bending tests after aging time of 10, 25 and 60 days. Digital Image Corr…

Compatibilization of Polylactide/Poly(ethylene 2,5-furanoate) (PLA/PEF) Blends for Sustainable and Bioderived Packaging.

2022

Despite the advantages of polylactide (PLA), its inadequate UV-shielding and gas-barrier properties undermine its wide application as a flexible packaging film for perishable items. These issues are addressed in this work by investigating the properties of melt-mixed, fully bioderived blends of polylactide (PLA) and poly(ethylene furanoate) (PEF), as a function of the PEF weight fraction (1–30 wt %) and the amount of the commercial compatibilizer/chain extender Joncryl ADR 4468 (J, 0.25–1 phr). J mitigates the immiscibility of the two polymer phases by decreasing and homogenizing the PEF domain size; for the blend containing 10 wt % of PEF, the PEF domain size drops from 0.67 &p…

Evaluation and application of Opuntia ficus-indica insulation panel

2015

Today the attention to the building sustainability issue is increasingly important, because of the major responsibility of the buildings field in the environmental degradation: both in terms of energy consumption from non-renewable sources and the raw materials impoverishment. In addition, the level of comfort required by users are growing and the thermal insulation of buildings becomes the key element in the reduction of energy consumption and C02 emissions, both in the case of new construction and existing ones. The thermal insulation of buildings is the key element in the reduction of energy consumption and C02 emissions due to the cooling of building interiors, both in the case of new c…

Failure map of composite laminate mechanical joints

2005

Natural Fiber-Reinforced Composites

2012

Over the last decade, composites of polymers reinforced with natural fibres have received increasing attention, both from the academic world and from several industries. There is a wide range of natural fibres which can be applied as reinforcements or fillers thanks to their properties and availability; i.e. flax, hemp, jute, kenaf and sisal. Natural fibres are mainly attractive for the following reasons: specific properties, price, health advantages and recyclability. Particularly, industry is getting more and more interested in environment-friendly products and therefore the research on natural fibre based on composite materials is gaining importance. Some of the benefits linked to the us…

Ottimizzazione di strutture sandwich per applicazioni nautiche

2008

Prestress and experimental tests on fractional viscoelastic materials

2013

Creep and/or Relaxation tests on viscoelastic materials show a power-law trend. Based upon Boltzmann superposition principle the constitutive law with a power-law kernel is ruled by the Caputo’s fractional derivative. Fractional constitutive law posses a long memory and then the parameters obtained by best fitting procedures on experimental data are strongly influenced by the prestress on the specimen. As in fact during the relaxation test the imposed history of deformation is not instantaneously applied, since a unit step function may not be realized by the test machine. Aim of this paper, it is shown that, the experimental procedure, and in particular the initial ramp to reach the constan…

Failure mechanisms of flax/epoxy laminates with open hole: a failure map

2017

Aim of this paper is the investigation of the pin/hole contact stress and failure mechanisms of flax/epoxy composite laminates underwent to tensile bearing tests. In particular, the maximum loads and failure modes are evaluated at varying joint geometry. In order to optimize the use of composite materials in structural applications, an experimental failure map, identifying main failure modes of mechanically fastened joints, is obtained by evaluating failure modes (i.e., net tension, shear out, cleavage and bearing) as a function of the pin diameter and the position of the hole from the free edge of the laminate. Main goal of this paper is give a simple experimental methodology to support th…

Dependence of geometrical configuration on mechanical behaviour of GFRP composite sandwiches

2008

Effect of water absorption on thermal and mechanical properties of thermosetting resins for marine applications

2009

Bearing failure prediction: an experimental versus numerical approach

2006

Arundo Donax particles as reinforcement for PLA based composites

2015

Aim of this work was to use particles obtained by grinding the culms of Arundo Donax used as reinforcement for PLA based composites. The influence of the content (10 wt% and 20 wt%) and size (150-300 μm and 300-500 μm) of Arundo Donax filler (ADF) on the morphology and on the properties of PLA-ADF composites was evaluated. The composites were prepared by melt compounding the PLA with ADF using a co-rotating modular twin screw extruder. For comparison, neat PLA was processed under the same conditions. Both the neat PLA and the composites were characterized by SEM, DSC, tensile and flexural measurements.

Metal to composite joining through adhesives

2008

Modellazione del processo di pultrusione di un profilato composito a “C” composto da resina poliestere e fibra di vetro

2006

Glass/basalt hybrid sandwiches for nautical applications

2011

The durability of basalt fibres reinforced polymer (BFRP)

2014

The technology of dry assembly for the production of multi-layer panels has evolved over the past 30 years, becoming an efficient alternative to traditional systems. The direction taken by the market has been increasingly drawn to eco-sustainable systems and in this way, the interest in the use of laminated composite panels for cladding, basalt fibres based. Basalt is a natural rock, silica based, which is produced through a variety of industrial processes into filaments, wool, chopped strands and fabrics. It is characterized by high resistance in chemically aggressive environments, high fire resistance, high mechanical resistance to compression and bending. The study focuses on two types o…

Biocompositi a base di PLA rinforzati con cariche lignocellulosiche ricavate dalla canna comune

2014

The assessment over time of the performance of jute-basalt hybrid composites for cladding panels

2017

The technology of dry assembly to produce multi-layer panels is an efficient alternative to traditional systems. Eco-sustainable systems are increasingly studied, particularly fiber reinforced composites for external cladding, based on natural fibers. Nevertheless, durability data on these composites are still lacking, being this is a really actual theme, especially for their potential use in outdoor applications. In this way, hybridization of natural fibers with mineral fibers as basalt ones appears promising. In the present paper, the performance of jute-reinforced laminate was compared with those of two jute/basalt reinforced hybrid laminates. The laminates were manufactured by means of …

Artichoke fibres as potential reinforcement of composite materials: mechanical and thermal characterization

2011

Studio sperimentale dell’effetto dei parametri geometrici e di processo sulle performance meccaniche di sandwich compositi

2007

Durability of basalt/hemp hybrid composites

2017

This study focused on the performance of injection-molded short hemp fibre and hemp/basalt fibre hybrid high density polyethylene composites. Results showed that hybridization with basalt fibre enhanced the performance properties. Analysis of fiber length distribution in the composite and fracture surface was performed to study the fiber breakage and fracture mechanism. Prolonged moisture absorption and accelerated ageing of short hemp fibre and hemp-basalt hybrid reinforced thermoplastic composites was addressed. Ageing in water did not result in a reduction of the strength of the composite samples, while it was found to decrease stiffness of hemp fibre reinforced composites. Mechanical pr…

Analisi reologica di una resina epossidica utilizzata come adesivo per giunzioni miste

2012