showing 36 of ~574560 from 574555 documents

Extracorporeal shock wave lithotripsy with ultrasound-guided lithostar plus.

1992

Abstract Since 1989, the Siemens lithostar plus, an upgrade of the lithostar with the ultrasonically guided overhead module, has been available for clinical use. This unit may be used for the treatment of either biliary or urinary calculi. We report on 75 patients with urinary calculi treated between March 1989 and June 1990 with the lithostar overhead module. Stone localization showed a rate of: caliceal stones 33.5%, pelvic stones 44%, upper ureteral stones 9.3% and lower ureter stones 13%. The overall disintegration rate was 86%, with a stone-free rate after 3 months of 78%.

medicine.medical_specialtyUreteral Calculibusiness.industryUrologymedicine.medical_treatmentUrinary systemLithotripsyurologic and male genital diseasesExtracorporeal shock wave lithotripsyfemale genital diseases and pregnancy complicationsUltrasound guidedSurgeryKidney CalculiUretermedicine.anatomical_structureLithotripsymedicineHumansbusinessNuclear medicinehuman activitiesEuropean urology

Mass Yields in the Very Asymmetric Fission of 249Cf(nth,f)

1992

Independent fission yields and fragment kinetic energies in the very asymmetric (A=87−72) fission of 249Cf have been measured using the mass separator LOHENGRIN at the Institut Laue-Langevin in Grenoble. The mass yields were found to be up to a factor of 100 higher than predicted in the US ENDF-V file. A preliminary evaluation of the isotopic yields shows a strong increase of the proton odd-even effect from 7 % to 15 %. This can be explained by a decreasing excitation energy in this very asymmetric region.

PhysicsProtonFissionSeparator (oil production)Atomic physicsKinetic energyExcitation

Methods for the Identification of Tainting Terpenoids and other Compounds from Algae

1992

Off-flavour compounds produced by algae in freshwater ecosystems were studied for their structure using integrated sensory and spectroscopic methods: mass spectrometry (MS), nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR). Both solvent extraction and thermal desorption were used to isolate and to introduce the compounds into gas chromatography/mass spectrometry (GC/MS) and gas chromatography/Fourier transform infrared (GC/FTIR) systems. Ten ng of a terpenoid compound gave a readable IR spectrum. For 1H NMR studies the compounds were collected directly into NMR solvent by preparative gas chromatography. About 5 µg of a monoterpenoid compound was needed for a reliable 1…

SolventEnvironmental EngineeringChromatographyChemistryProton NMRThermal desorptionInfrared spectroscopyGas chromatographyFourier transform infrared spectroscopyMass spectrometryTerpenoidWater Science and TechnologyWater Science and Technology

Profesors Rihards Kondratovičs: biobibliogrāfiskais rādītājs

1992

Saturs: Priekšvārds. Bioloģijas zinātņu doktors profesors Rihards Kondratovičs / Helēna Mauriņa. Profesora R. Kondratoviča publicētie darbi (1953.-1992.). Profesora R. Kondratoviča rediģētie un recenzētie darbi. Profesoram R. Kondratovičam izsniegtās publicētās autorapliecības. Raksti par profesoru R. Kondratoviču. Profesora R. Kondratoviča publicēto darbu alfabētiskais rādītājs. Personu rādītājs.

Rododendri - bibliogrāfiskais rādītājsBotānika - bibliogrāfiskais rādītājsProfessors of the Latvian UniversityBioloģijas zinātņu profesori Latvijas UnivesitātēAcālijas - bibliogrāfiskais rādītājs:NATURAL SCIENCES::Biology [Research Subject Categories]Biobibliogrāfiskie rādītājiHistory of the University of LatviaBioloģija - bibliogrāfiskais rādītājsRododendru selekcija - bibliogrāfiskais rādītājsРододендры - библиографический указательLatvijas Universitātes vēstureLatvijas Universitātes profesoriRododendru introdukcija - bibliogrāfiskais rādītājsP. Stučkas Latvijas Valsts universitātes profesori

La psicología americana vista desde 'The Psychological Review': Evolución o revolución.

1992

El objetivo de este trabajo es averiguar qué modelo de interpretación historiográfica es el que se adecua al contenido de uno de los canales de comunicación científicos americanos más importantes, el Psychological Review, desde su fundación en 1894 hasta 1975. El estudio detallado de la información del Psychological Review nos permite observar en una primera etapa (1894-1945) la predominancia de los temas relativos a procesos psicológicos básicos, bajo una perspectiva metodólogica e instrumental variada y desde un marco orientado hacia el objetivismo y empirismo. Tras la ll Guerra Mundial, se constata cómo se reemplazan progresivamente y gradualmente las concepciones reduccionistas por enfo…

Psicologia

Síndrome uña-rótula

1992

Presentamos el estudio de 3 casos afectos de un síndrome "uña-rótula", con historia familiar positiva en uno de ellos. Este síndrome es un transtorno hereditario de transmisión autosómica dominante, caracterizado por displasia ungueal y de articulacione s y formación de una s excrecencia s óseas características a nive l del ilíaco (cuernos ilíacos). El síndrome completo se define por los cambios esqueléticos asociados a una nefropatía. Describimos las anomalías clínico-radiográficas de tres paciente s y realizamos una revisión de la literatura sobre esta displasia poco frecuente. The author s showed thre e patients affected by "nail patella" syndrome with positive familiar history in one ca…

Medicina clínicaUNESCO::CIENCIAS MÉDICAS:CIENCIAS MÉDICAS [UNESCO]Ciencias de la salud

Procesos sociocognitivos de la influencia minoritaria

1992

ResumenSe presenta un experimento (plan 2x2x2; N = 180) en el que se estudia la influencia directa e indirecta de una minoria en funcion: a) del grado de conflicto inducido por la retorica minoritaria; b) de si los jucicios mayoritarios son independientes o interdependientes; c) de las implicaciones altas o bajas del cambio de actitudes. Los resultados muestran que, como previsto por el modelo de la disociacion de la comparacion y de la validacion, cuando los juicios son efectuados de modo independiente, la influencia aumenta en funcion directa del conflicto inducido por la retorica minoritaria.Esta influencia se inhibe a nivel directo y se desplaza hacia un nivel indirecto en la condicione…

Social PsychologyRevista de Psicología Social

Nuevos desarrollos de la cooperación antártica: del Protocolo de 1991 al Acuerdo entre España y Argentina

1992

En este trabajo se analizan tres instrumentos de Derecho Internacional sobre la Antártida que se han adoptado en un breve periodo de tiempo, incrementando la cooperación antártica internacional. El Primero, es el Protocolo de Madrid (04.10.1991) al Tratado antártico sobre protección del medio ambiente. El segundo es la adopción del Anexo V sobre protección y administración de zonas al Protocolo al Tratado Antártico sobre protección del medio ambiente (Bonn, 18.10.1991). Finalmente, en un ámbito bilateral, destaca el Acuerdo de cooperación en materia antártica entre el Reino de España y la República Argentina (Madrid, 21.06.1991). Este tratado bilateral sobre cooperación antártica, que es el…

Dret internacionalMedi ambient Protecció

Institutional Forgiveness in Borana Assemblies

1992

BoranaJuridical anthropologycustomary lawOromo

Study of orientation of 3-Jet events in Z(0) hacronic decays using the DELPHY detector

1992

The study of the orientation of three-jet events from e+ e- --> Z0 --> multi-hadrons is presented, in particular the polar angle distributions of the thrust axis and of the normal to the three-jet plane, and the azimuthal correlations between the hadron plane and the one defined by the beam and thrust axes. The data are compared with results at lower energy and with QCD predictions. Good agreement with QCD predictions is observed. The scalar gluon theory is excluded by the data.

High Energy Physics::LatticeHigh Energy Physics::PhenomenologyHigh Energy Physics::ExperimentFísica nuclearNuclear Experiment

Condensation nuclei at the German Antarctic Station “Georg von Neumayer”

1992

Evaluations of measurements of the tropospheric surface condensation nuclei at the German Antarctic station for the last 8 years are presented. They show clearly the annual variation of the concentration with a maximum in austral summer, as previously seen by other investigators. In addition, a pronounced increase of the concentration of 9.63% per year has been found. The size distributions of the condensation nuclei of measurements over 2 years are evaluated and discussed. On average, they are of mono-modal shape, but individually most of them show a bimodal shape. DOI: 10.1034/j.1600-0889.1992.00009.x

Atmospheric Science010504 meteorology & atmospheric sciencesMeteorology010501 environmental sciencesAtmospheric sciences01 natural scienceslanguage.human_languageTroposphereGermanlanguageCloud condensation nucleiEnvironmental scienceAnnual variation0105 earth and related environmental sciencesTellus B: Chemical and Physical Meteorology

Receptor Binding Properties of the New and Specific Thromboxane Receptor Antagonist Bay U 3405

1992

Human platelet membranes were used to characterize the receptor binding properties of the specific thromboxane receptor antagonist 3H-SQ 29548 and the displacement of 3H-SQ 29548 from its binding site by the new thromboxane receptor antagonist Bay u 3405. The specific binding of 3H-SQ 29548 was saturable with an association rate constant of 1 x 10(-11) mol-1 min-1 and a dissociation rate constant of 0.032 min-1. Nonspecific binding of 3H-SQ 29548 was below 10%. When Scatchard plot analysis was performed on equilibrium saturation binding the kD was 69 nmol/l and the Bmax was calculated as 3.9 pmol/mg membrane protein. 3H-SQ 29548 was dose dependently displaced from its binding site by additi…

Thromboxane receptorMembraneMembrane proteinChemistryIn vivoBiological half-lifeBinding siteIC50BayMolecular biology

Stochastic Response on Non-Linear Systems under Parametric Non-Gaussian Agencies

1992

The probabilistic response characterization of non-linear systems subjected to non-normal delta correlated parametric excitation is obtained. In order to do this an extension of both Ito’s differential rule and the Fokker-Planck equation is presented, enabling one to account for the effect of the non-normal input. The validity of the approach reported here is confirmed by results obtained by means of a Monte Carlo simulation.

symbols.namesakeNonlinear systemGaussianMonte Carlo methodStatisticsProbabilistic logicsymbolsApplied mathematicsExtension (predicate logic)Differential (infinitesimal)ExcitationMathematicsParametric statistics

Behavior of the nuclear charge radii systematics in thes-dshell from muonic atom measurements

1992

The present work extends the systematics of nuclear charge radii obtained by the method of muonic atoms to nuclei with 8\ensuremath{\le}Z,N\ensuremath{\le}20. The accuracy of the measured muonic Lyman transition energies of generally \ensuremath{\le}10 eV leads to a precision in the model-independent nuclear charge radii differences of 2--3 am for the isotope shifts and 4--9 am for isotone shifts. Both isotope and isotone shifts within the s-d shell behave ``anomalously'' with respect to the systematics of heavier nuclei. However, such behavior is predicted on theoretical grounds, if mixing in the s-d shells and the strong deformation of some of the nuclei in this region are considered. We …

PhysicsNuclear and High Energy PhysicsIsotopeScatteringIsotoneNuclear TheoryShell (structure)Charge densityCharge (physics)Effective nuclear chargePhysics::Atomic PhysicsAtomic physicsNuclear ExperimentExotic atomPhysical Review C

La construcció naval a Catalunya a les vespres dels grans descobriments geogràfics (1350-1450)

1992

UNESCO::HISTORIAHumanidadesGrupo C:HISTORIA [UNESCO]Historia

Análisis histológico del crecimiento tisular en la fibra de carbono y en la prótesis de polietilenotereftalato cuando se utilizan como sustitutos del…

1992

Se realiza un análisis histológico del crecimiento tisular en la fibra de carbono y en la prótesis de polietilenotereftalato cuando se utilizan para reemplazar al ligamento cruzado anterior (LCA). La fibra de carbono induce la formación de un tejido conectivo organizado que se extiende siguiendo la dirección de las fibras, dando lugar a un tejido similar histológicamente al ligamento en las zonas donde se ha conservado la disposición longitudinal de los filamentos de carbono. En las zonas en las que los filamentos se han roto, la inducción fibroblástica es importante pero desordenada, dando lugar a un tejido conectivo irregular. La prótesis de polietilenotereftalato actúa como inductor de u…

Medicina clínicaUNESCO::CIENCIAS MÉDICAS:CIENCIAS MÉDICAS [UNESCO]Ciencias de la salud

Històries velles, habitacions noves

1992

UNESCO::HISTORIAHumanidadesGrupo C:HISTORIA [UNESCO]Historia

Multicentre study of gestrinone in cyclical breast pain FRIEDOLF PETERS

1992

Although the aetiology of cyclical mastalgia is poorly understood, the consistent finding of an increased prolactin stimulation response probably due to oestrogen dominance has led to the use of treatment with prolactin-lowering drugs and antioestrogens. The efficacy and safety in cyclical mastalgia of gestrinone, which has androgenic, anti-oestrogenic, and antiprogestagenic properties, were investigated in a multicentre study. In a double-blind randomisation procedure, 72 patients were allocated placebo and 73 treatment with gestrinone (2.5 mg twice a week) for 3 months. The patients recorded the severity of breast pain on a visual analogue scale before and during treatment and scored othe…

Gynecologymedicine.medical_specialtybusiness.industryVisual analogue scaleBreast painGeneral MedicineGestrinonePlaceboGastroenterologyProlactinlaw.inventionRandomized controlled triallawInternal medicineSeverity of illnessmedicinemedicine.symptombusinessMastodyniamedicine.drugThe Lancet

Slowed abduction saccades in bilateral internuclear ophthalmoplegia

1992

Horizontal eye movements were investigated in 65 patients with bilateral internuclear ophthalmoplegia utilizing direct current electro-oculography. Abduction saccades were slowed in 35 patients (53.8%), being hypermetric in 65.7% of them. Slowing of abduction saccades is attributed to impaired inhibition of the tonic resting activity of the antagonistic medial rectus muscle. Experimental data indicate that this slowing results from a lesion of an uncrossed connection between the pontine reticular formation and the oculomotor nucleus. The prevalence of hypermetric abduction saccades increased with increasing severity of adduction paresis on the opposite eye. This confirms the view that media…

medicine.medical_specialtygenetic structuresbusiness.industryInternuclear ophthalmoplegiaMedial rectus muscleLateral rectus muscleEye movementParamedian pontine reticular formationAnatomyAudiologymedicine.diseaseeye diseasesTonic (physiology)Oculomotor nucleusbody regionsOphthalmologymedicine.anatomical_structureMedicinesense organsNeurology (clinical)medicine.symptombusinessParesisNeuro-Ophthalmology

Dielectriic Dispersion Measurements of Salt-Water Saturated Porous Glass Compared with Local Porosity Theory.

1992

AbstractA recent study [1] of the dielectric frequency response of a two component composite performed on a single specimen shows that local porosity theory LPT [2] represents a substantial improvement compared with other theories predicting the complex dielectric dispersion [3,4,5]. The purpose of the present work is to extend this investigation to a systematic study on several specimens with different compositions.

Materials scienceSalt waterPorous glassComposite materialPorosityDispersion (chemistry)MRS Proceedings

SURGERY OF GERM CELL TUMORS IN PEDIATRIC AGE: Preliminart data od TCG)! series of the New Italian Protocol

1992

The authors report the preliminary data of the case studies of the new National Protocol TGC91 and examine the role of surgery in the treatment of these neoplasms

Paediatric neoplasms in pediatric ageSettore MED/38 - Pediatria Generale E SpecialisticaSettore MED/20 - Chirurgia Pediatrica E InfantileGerm cell tumorpediatric surgery

Familia, parentesco y alianza en la huerta de Valencia, siglo XVIII: La estrategia familiar de la consanguinidad

1992

:HISTORIA::Historia moderna [UNESCO]HumanidadesUNESCO::HISTORIA::Historia modernaHistoria

Los elementos mágicos del teatro de J. Lorenzo Palmireno

1992

FilologíasUNESCO::: [UNESCO]

Fracturas epifisiolisis graves de la extremidad proximal del radio: resultado tras tratamiento quirúrgico

1992

La fractura-epifisiolisis del cuello radial es una lesión grave que puede originar alteracione s en e l crecimiento epifisario. Presentamo s una seri e de 22 casos revisados con una antigüedad mínima de dos años. Fueron intervenidos 14 pacientes, de los que 10 estaban incluidos en el grupo III o en lesione s de Jeffery. Once enfermos fueron tratado s con cirugí a abierta. Cuando l a intervenció n consisti ó en reducció n abierta y osteosíntesis, los resultados clínicos fueron buenos en el 50%, pero cuando só- lo se practicó reducción cruenta sin asociar sistema estabilizador metálico, éstos llegaron al 100%. En cinco de los ocho paciente s del primer grupo se presentaron calcificacione s ar…

Medicina clínicaUNESCO::CIENCIAS MÉDICAS:CIENCIAS MÉDICAS [UNESCO]Ciencias de la salud

Synthesis and characterization of V2O5SiO2ZrO2 pigments by sol-gel method

1992

Abstract Polymeric gels in the V2O5 SiO2 ZrO2 system were prepared from tetraethylorthosilicate (TEOS), zirconium(IV)-n-propoxide and vanadium(IV) oxyacetylacetonate, precursors. The effects of prehydrolysis time of TEOS and drying gel method on the stabilization of tetragonal zirconia in the silica amorphous matrix, nucleation and growth of the zircon (ZrSiO4) phase, and stabilization of the blue and green stains of vanadium zircon were studied. Results provide evidence that long time of prehydrolysis and fast drying do not favour zircon crystallization but stabilize the tetragonal zirconia in the amorphous matrix.

ZirconiumMaterials scienceNucleationMineralogychemistry.chemical_elementVanadiumCondensed Matter PhysicsElectronic Optical and Magnetic Materialslaw.inventionPigmentchemistryChemical engineeringlawvisual_artPhase (matter)Materials ChemistryCeramics and Compositesvisual_art.visual_art_mediumCrystallizationSol-gelZirconJournal of Non-Crystalline Solids

Increase in Endogenous Fibrinolysis and Platelet Activity during Exercise in Young Volunteers

1992

Physicians at the Medical Clinic at the Johannes Gutenberg University in Mainz Germany compared data on 6 18-35 year old healthy women who took low-dose estrogen oral contraceptives (OCs) with data on 10 healthy women of same age who did not take OCs and with data on 12 18-35 year old males to examine gender differences of the coagulation system endogenous fibrinolytic activity and platelet aggregation under normal conditions and immediately after spiroergometric exercise beyond the anaerobic threshold. This type of exercise considerably boosted tissue plasminogen activator (t-PA) in both men and women (1.6-5.5 IU/ml and 1.8-5.3 IU/ml respectively; p < .005). The increase was not as high in…

medicine.medical_specialtybusiness.industrymedicine.drug_classmedicine.medical_treatmentmedicine.diseaseTissue plasminogen activatorThrombosisEndocrinologyClinical researchEstrogenInternal medicineFibrinolysismedicinePlatelet activationbusinessPlasminogen activatorAnaerobic exercisemedicine.drug

Behavior of Epithelial Differentiation Antigens (Carcinoembryonic Antigen, Epithelial Membrane Antigen, Keratin and Cytokeratin) in Transitional Cell…

1992

Results of an immunohistochemical study in normal urothelium and transitional cell carcinomas of the bladder are presented. Paraffin-embedded material was confronted with immunoantisera against carcinoembryonic antigen (CEA), keratin (K), cytokeratin (CK) and epithelial membrane antigen (EMA). Immunohistochemical findings confirm the changes in reactivity of dysplastic urothelium and carcinoma in situ for CEA, CK and EMA, in comparison with normal urothelium. Statistically significant differences were also found, depending upon tumor stage, in staining of transitional cell carcinomas for K and CK. Expression of CK correlated with the tumor differentiation grade: normal urothelium and well-d…

AdultMalePathologymedicine.medical_specialtyUrologyurologic and male genital diseasesEpitheliumCytokeratinCarcinoembryonic antigenAntigenAntigens NeoplasmKeratinBiomarkers TumormedicineHumansUrotheliumAgedNeoplasm Stagingchemistry.chemical_classificationCarcinoma Transitional CellMembrane GlycoproteinsbiologyMucin-1Middle Agedmedicine.diseaseAntigens Differentiationfemale genital diseases and pregnancy complicationsCarcinoembryonic AntigenTransitional cell carcinomaUrinary Bladder Neoplasmschemistrybiology.proteinKeratinsImmunohistochemistryFemaleCarcinoma in SituImmunostainingUrologia Internationalis

Panteon Orląt Lwowskich 1918-1992: powstanie -unicestwienie-odbudowa

1992

‘Wulfila as the Inventor of the Gothic Alphabet. The Tradition in Late Antiquity and the Middle Ages’

1992

medioevoWulfilaalfabeto (inventori di)gotico

Sviluppo partecipante e sistemi tradizionali: Il caso dei Borana dell'Etiopia

1992

In the development programs concerning the Ethiopian Borana local groups are assigned the role of principal group for development initiatives. As such, the project seems to meet the principle of participatory development. However, among the Borana, local communities have very little organizational significance and no say at all on matters regarding rights of property. Such authority is instead attributed to descent groups, which are not localized. In particular, clans have both the organizational capacity to coordinate collective investments on natural resources and the authority to guarantee personal and collective property rights. It is therefore suggested that a direct link with clans an…

Boranaorganizzazione pastoralediritti consuetudinaripastoral tenureOromopastoral developmentsviluppo pastoralesistema di discendenzacostumary rightsdescent system

El vaso crateroide de barniz negro decorado con ovas F - 4753: una probable producción calena

1992

lcsh:CHumanidadeslcsh:Archaeologylcsh:CC1-960UNESCO::HISTORIA::Ciencias auxiliares de la historia::Arqueologíalcsh:Auxiliary sciences of historyHistoria:HISTORIA::Ciencias auxiliares de la historia::Arqueología [UNESCO]

Análisis iconográfico del intradós de la escalera del coro en el Iglesia Arciprestal de Santa María de Morella

1992

OBRA CAPITAL DE LA ESCULTURA GOTICA VALENCIANA SON LOS RELIEVES Y ESCULTURAS DEL TRASCORO Y DE LA ESCALERA DE CARACOL QUE CONDUCE AL CORO EXENTO DE LA IGLESIA ARCIPRESTAL DE MORELLA (CASTELLON), DEBIDO AL MAESTRO DE OBRAS MORELLANO PERE SEGARRA, QUE LO CONSTRUYO ENTRE 1420 Y 1426. EN EL INTRADOS DE LA ESCALERA APARECE UNA GRAN CABEZA SOBRE LA QUE SE SITUA UN ENORME JARRON DEL QUE SURGE UNA ESPECIE DE ARBOL. A MODO DE HIPOTESIS ESTE ARBOL PODRIA SIMBOLIZAR EL ARBOL DE VIDA MISTICA DE CRISTO (ABC/LAG).

Escultura góticaCorosUNESCO::HISTORIA::Historia por especialidades::Historia del arteRelieveIconografía religiosaEscaleras:HISTORIA::Historia por especialidades::Historia del arte [UNESCO]

Recycling of degraded polyethylene: Blends with nylon 6

1992

Abstract Recycled polyethylene can be used for blending with nylon to obtain blends with mechanical properties better than those of blends with virgin polyethylene. Moreover, the mechanical properties of these blends are very close to and, in some cases, better than those of the pure nylon and those of blends made with functionalized polyolefines. The carbonyl groups of the photo-oxidized polyethylene react with amino end-groups of nylon 6, giving rise to graft copolymers which act as interfacial agents between the two incompatible phases. Large degrees of photo-oxidation of the polyethylene and intense mixing improve the properties of the blends.

Materials sciencePolymers and Plasticseducationtechnology industry and agricultureMixing (process engineering)food and beveragesPolyethyleneCondensed Matter Physicschemistry.chemical_compoundNylon 6chemistryMechanics of MaterialsMaterials ChemistryCopolymerComposite materialPolymer Degradation and Stability

A comparison theorem for the mean exit time from a domain in a K�hler manifold

1992

Let M be a Kahler manifold with Ricci and antiholomorphic Ricci curvature bounded from below. Let ω be a domain in M with some bounds on the mean and JN-mean curvatures of its boundary ∂ω. The main result of this paper is a comparison theorem between the Mean Exit Time function defined on ω and the Mean Exit Time from a geodesic ball of the complex projective space ℂℙ n (λ) which involves a characterization of the geodesic balls among the domain ω. In order to achieve this, we prove a comparison theorem for the mean curvatures of hypersurfaces parallel to the boundary of ω, using the Index Lemma for Submanifolds.

Comparison theoremRiemann curvature tensorGeodesicComplex projective spaceMathematical analysisKähler manifoldCurvaturesymbols.namesakesymbolsMathematics::Differential GeometryGeometry and TopologyAnalysisRicci curvatureMathematicsScalar curvatureAnnals of Global Analysis and Geometry

Kinetic behaviour of a structural phase transition in Langmuir-Blodgett multilayers studied by energy dispersive x-ray reflectivity

1992

Various multilayers of Cd stearate were prepared by means of the Langmuir-Blodgett technique and investigated at T = Ts - ΔT (Ts, melting point of LB film). The x-ray scattering spectrum was recorded in several time intervals using an energy dispersive set up. For ΔT = 3 ... 9 K the observed intensity reduction of Bragg peaks, which corresponds to the multilayer periodicity, is recorded as a function of time. In addition new peaks appear. This is interpreted in terms of a kinetically driven phase separation of the metastable LB-phase. The time needed for phase disorder and the nucleation of the new phase decreases for smaller ΔT. The measured layer spacing of the new phase is larger than th…

Phase transitionMaterials sciencebusiness.industryScatteringNucleationCondensed Matter PhysicsLangmuir–Blodgett filmMolecular physicsAtomic and Molecular Physics and OpticsX-ray reflectivityOpticsPhase (matter)MetastabilityMelting pointbusinessMathematical PhysicsPhysica Scripta

The Phases of Phosphatidyl Ethanolamine Monolayers

1992

For the first time phospholipid monolayers at the air/water interface have been studied by X-ray diffraction and reflection along the whole isotherm from the isotropic fluid to the ordered phases [1]. The model used to analyze the data — and the accuracy of the parameters deduced — were tested by comparing the results obtained with two lipids having the same head group but different chain lengths.

Diffractionchemistry.chemical_compoundCrystallographyReflection (mathematics)chemistryIsotropyMonolayerPhospholipidPhosphatidyl ethanolamineLipid monolayer