A muramidase from Acremonium alcalophilum hydrolyse peptidoglycan found in the gastrointestinal tract of broiler chickens

Abstract This study evaluates peptidoglycan hydrolysis by a microbial muramidase from the fungus Acremonium alcalophilum in vitro and in the gastrointestinal tract of broiler chickens. Peptidoglycan used for in vitro studies was derived from 5 gram-positive chicken gut isolate type strains. In vitro peptidoglycan hydrolysis was studied by three approaches: (a) helium ion microscopy to identify visual phenotypes of hydrolysis, (b) reducing end assay to quantify solubilization of peptidoglycan fragments, and (c) mass spectroscopy to estimate relative abundances of soluble substrates and reaction products. Visual effects of peptidoglycan hydrolysis could be observed by helium ion microscopy an…

Statistical Characterization of Self-Assembled Colloidal Crystals by Single-Step Vertical Deposition

Abstract We have statistically characterized the self-assembly of multi-layer polystyrene colloidal crystals, using the technique of vertical deposition, with parameters chosen to produce thick layers of self-assembled crystals in one deposition step. The size distribution of domains produced with this technique was seen to follow a log-normal distribution, hinting that aggregation or fragmentation phenomena play a role. In addition, using a lithographically directed self-assembly method, we have shown that the size of multi-layer, continuous crack-free domains in lithographically defined areas can be many times larger than in the surrounding areas. In a single deposition step, we have prod…

Influence of Phonon dimensionality on Electron Energy Relaxation

We studied experimentally the role of phonon dimensionality on electron-phonon (e-p) interaction in thin copper wires evaporated either on suspended silicon nitride membranes or on bulk substrates, at sub-Kelvin temperatures. The power emitted from electrons to phonons was measured using sensitive normal metal-insulator-superconductor (NIS) tunnel junction thermometers. Membrane thicknesses ranging from 30 nm to 750 nm were used to clearly see the onset of the effects of two-dimensional (2D) phonon system. We observed for the first time that a 2D phonon spectrum clearly changes the temperature dependence and strength of the e-p scattering rate, with the interaction becoming stronger at the …

Minimum detection limits and applications of proton and helium induced X-ray emission using transition-edge sensor array

Abstract We have determined minimum detection limits, MDLs, for elements 14 ⩽ Z ⩽ 86 using a transition-edge sensor array, TES array, and as a comparison using an Amptek X-123SDD silicon drift detector, SDD. This was done using a 3 MeV proton beam and a 5.1 MeV helium beam. MDLs were determined for a thin film sample on top of C substrate, and for a bulk sample containing mostly Al. Due to the higher peak-to-background ratio, lower detection limits were obtainable using the TES array for most of the elements. However, for elements 30 ⩽ Z ⩽ 45 the performance of the TES array was not as good as the SDD performance. This is due to the limitations of the TES used at energies >10 keV. The great…

Superconducting tantalum nitride-based normal metal-insulator-superconductor tunnel junctions

We report the development of superconducting tantalum nitride (TaN$_{x} $) normal metal-insulator-superconductor (NIS) tunnel junctions. For the insulating barrier, we used both AlO$_{x}$ and TaO$_{x}$ (Cu-AlO$_{x}$-Al-TaN$_{x} $ and Cu-TaO$_{x}$-TaN$_{x} $), with both devices exhibiting temperature dependent current-voltage characteristics which follow the simple one-particle tunneling model. The superconducting gap follows a BCS type temperature dependence, rendering these devices suitable for sensitive thermometry and bolometry from the superconducting transition temperature $T_{\text{C}}$ of the TaN$_{x} $ film at $\sim 5$ K down to $\sim$ 0.5 K. Numerical simulations were also performe…

Operation of transition-edge sensors with excess thermal noise

The superconducting transition-edge sensor (TES) is currently one of the most attractive choices for ultra-high resolution calorimetry in the keV x-ray band, and is being considered for future ESA and NASA missions. We have performed a study on the noise characteristics of Au/Ti bilayer TESs, at operating temperatures around ~100 mK, with the SQUID readout at 1.5 K. Experimental results indicate that without modifications the back-action noise from the SQUID chip degrades the noise characteristics significantly. We present a simple and effective solution to the problem: by installing an extra shunt resistor which absorbs the excess radiation from the SQUID input, we have reduced the excess …

Radial phononic thermal conductance in thin membranes in the Casimir limit: Design guidelines for devices

In a previous publication, we discussed the formalism and some computational results for phononic thermal conduction in the suspended membrane geometry for radial heat flow from a central source, which is a common geometry for some low-temperature detectors, for example. We studied the case where only diffusive surface scattering is present, the so called Casimir limit, which can be experimentally relevant at temperatures below $\sim$ 10 K in typical materials, and even higher for ultrathin samples. Here, we extend our studies to much thinner membranes, obtaining numerical results for geometries which are more typical in experiments. In addition, we interpret the results in terms of a small…

Fabrication of superconducting tantalum nitride thin films using infra-red pulsed laser deposition

We report the successful fabrication of superconducting tantalum nitride (TaN) thin films using a pulsed laser deposition technique with 1064 nm radiation. Films with thickness $ \sim $ 100 nm deposited on MgO (100) single crystals and on oxidized silicon (SiO$_{2} $) substrates exhibited a superconducting transition temperature of $\sim $ 8 K and 6 K, respectively. The topography of these films were investigated using atomic force and scanning electron microscopy, revealing fairly large area particulate free and smooth surfaces, while the structure of the films were investigated using standard $ \theta -2 \theta $ and glancing angle X-ray diffraction techniques. For films grown on MgO a fa…

Fabrication and Characterization of Epitaxial NbN/TaN/NbN Josephson Junctions Grown by Pulsed Laser Ablation

We report fabrication and characterization of epitaxial NbN/TaN/NbN Josephson junctions grown by pulsed laser ablation. These SNS junctions can be used as elements of rapid-single-flux-quantum (RSFQ) logic, which is a promising technology for high speed digital electronic devices. The NbN/TaN/NbN trilayer films were prepared on a single crystal MgO substrate by pulsed laser ablation, and patterned into junctions using a novel process utilizing e-beam lithography, chemical vapor deposition and e-beam evaporation. The quality of junctions was tested by measuring the temperature dependence of the junctions' IcRn values, observed to be quite close to theoretical values.

A Composite Phononic Crystal Design for Quasiparticle Lifetime Enhancement in Kinetic Inductance Detectors

A nanoscale phononic crystal filter (reflector) is designed for a kinetic inductance detector where the reflection band is matched to the quasiparticle recombination phonons with the aim to increase quasiparticle lifetime in the superconducting resonator. The inductor is enclosed by a 1 um wide phononic crystal membrane section with two simple hole patterns that each contain a partial spectral gap for various high frequency phonon modes. The phononic crystal is narrow enough for low frequency thermal phonons to propagate unimpeded. With 3D phonon scattering simulations over a 40 dB attenuation in transmitted power is found for the crystal, which was previously estimated to give a lifetime e…

Reduction of low-frequency 1/f noise in Al-AlOx-Al tunnel junctions by thermal annealing

We report that annealing Al-AlOx-Al tunnel junctions in a vacuum chamber at temperature of 400C reduces the characteristic 1/f noise in the junctions, in some cases by an order of magnitude. Both ultra high vacuum and high vacuum fabricated samples demonstrated a significant reduction in the 1/f noise level. Temperature dependence of the noise was studied between 4.2 and 340 Kelvin, with a linear dependence below 100 K, but a faster increase above. The results are consistent with a model where the density of charge trapping two level-systems within the tunneling barrier is reduced by the annealing process.

Normal Metal-Insulator-Superconductor Tunnel Junctions With Pulsed Laser Deposited Titanium Nitride as Superconductor

Here we report the fabrication of normal metal – insulator – superconductor (NIS) tunnel junctions using superconducting titanium nitride grown by pulsed laser deposition (PLD). The films for NIS junction fabrication were deposited on two different substrates: silicon nitride film and magnesium oxide. TiN films were characterized by means of electrical transport measurements, and films with superconducting transition temperatures above the liquid helium boiling point were chosen for fabrication of NIS junctions. Tunnel junction devices were successfully fabricated using electron beam lithography and shadow evaporation techniques. The insulator layer formation was performed using two differe…

Electron–phonon interaction in a thin Al–Mn film

Abstract Aluminum doped with manganese is an interesting novel material with applications in normal metal–insulator–superconductor (NIS) tunnel junction devices and transition-edge sensors at sub-Kelvin temperatures. We have studied the electron–phonon (e–p) coupling in a thin aluminum film doped with 1% manganese, with a measuring technique based on DC hot-electron effect. The electron temperature was measured with the help of symmetric normal metal–insulator–superconductor tunnel-junction pairs (SINIS-thermometers). Measurements show that the temperature dependence of the e–p interaction is not consistent with existing theories for disordered metals, but follows a higher power law.

Heat under the microscope

[Introduction] Recent advances in computational and spectroscopic tools offer new insights into the nature of thermal conduction at ever-finer length scales and ways to control it. Heat conduction is familiar to us all and yet requires a wide range of physics—statistical mechanics, crystallography, and quantum mechanics among them—to fully explain. At the macroscale, heat conduction can be described as a diffusion process in which energy moves along a temperature gradient. The heat flux dissipated by the gradient depends on a material property, the thermal conductivity, as described by the constitutive relation, Fourier’s law. The heat equation, which is derived from Fourier’s law and the c…

Domain wall induced modulation of low field H-T phase diagram in patterned superconductor-ferromagnet stripes

We present a systematic study of the magnetic domain wall induced modulation of superconducting transition temperature (Tc) in Nb/Ni bilayer stripes. By varying the thickness of the Ni layer from 20 nm to 100 nm we have been able to measure the low field Tc-H phase diagram spanning the Neel domain wall and Bloch domain wall range of thicknesses. Micromagnetic simulations and magnetic force microscopy measurements confirmed a stronger out-of-plane stray field in the Bloch domain walls compared to the Neel walls. A suppression in Tc was observed in the magnetization reversal region of the Ni film, the magnitude of which followed linearly to the strength of the out-of-plane stray field due to …

Impact of non-idealities on the conductance characteristics of superconductor-insulator-normal metal-insulator-superconductor tunnel junctions

We have investigated the effect of asymmetry in tunnelling resistance of individual normal metal-insulator-superconductor (NIS) tunnel junctions that constitute a SINIS pair, both experimentally and theoretically. Ours results clearly demonstrate that any finite asymmetry in the tunnelling resistance gives rise to an excess current, as compared to its symmetric counterpart, both below and around the gap edge. The signature of this excess current is visible almost up to the critical temperature. We find that this apparent broadening of the density of states is purely electrical in origin. Our calculations also show that any finite resistance that is in series with the tunnelling resistance, …

Stability, sub-gap current, 1/f-noise, and elemental depth profiling of annealed Al:Mn-AlOX-Al normal metal-insulator-superconducting tunnel junctions

In this paper we report a study of the effect of vacuum annealing at 400◦C on the properties of normal metal-insulator-superconductor (NIS) tunnel junctions, with manganese doped aluminium (Al:Mn) as the normal metal, aluminum as the superconductor and amorphous aluminum oxide as the tunneling barrier (Al:Mn-AlOx-Al). The annealing treatment improves the stability of the junctions, increases their tunneling resistance and does not have a negative impact on the low-temperature current-voltage characteristics. The measured 1 / f resistance noise of the junctions also changes after annealing, in the best case decreasing by over an order of magnitude. All these observations show that annealing …

Irreversibility of the threshold field for dendritic flux avalanches in superconductors

Hysteretic effects are seen in the upper and lower threshold fields for the appearance of dendritic flux instabilities, first explained in Yurchenko et al. [Phys. Rev. B 76 (2007) 092504], in NbN-films. We have measured the threshold fields at increasing and decreasing applied fields at different temperatures and proposed a mechanism explaining how the hysteresis arises by analyzing the field profiles inside the sample.

Fabrication and Modelling of Three-Dimensional Sub-kelvin Phononic Crystals

We have investigated the fabrication and computational modelling of threedimensional phononic crystals for the observation of full band gaps for thermal phonons at sub-kelvin temperatures. Self-assembled arrays of monodisperse polystyrene nanospheres have been fabricated using a vertical deposition technique. Optimal conditions for increasing crystal domain size and crystalline quality have been studied. In addition, the phononic band structure has been computed using the finite element method for the simple cubic lattice. The dependence of band structure on contact area between spheres has also been studied. For small enough contact area a large band gap is observed, predicting a strong in…

Intregrating metallic wiring with three-dimensional polystyrene colloidal crystals using electron-beam lithography and three-dimensional laser lithography

We demonstrate a method to fabricate narrow, down to a few micron wide metallic leads on top of a three-dimensional colloidal crystal self-assembled from polystyrene (PS) nanospheres of diameter 260 nm, using electron-beam lithography. This fabrication is not straightforward due to the fact that PS nanospheres cannot usually survive the harsh chemical treatments required in the development and lift-off steps of electron-beam lithography. We solve this problem by increasing the chemical resistance of the PS nanospheres using an additional electron-beam irradiation step, which allows the spheres to retain their shape and their self-assembled structure, even after baking to a temperature of 16…

Specific heat of thin phonon cavities at low temperature: Very high values revealed by zeptojoule calorimetry

The specific heat of phonon cavities is investigated in order to analyze the effect of phonon confinement on thermodynamic properties. The specific heat of freestanding very thin SiN membranes in the low-dimensional limit is measured down to very low temperatures (from 6 K to 50 mK). In the whole temperature range, we measured an excess specific heat orders of magnitude bigger than the typical value observed in amorphous solids. Below 1 K, a crossover in cp to a lower power law is seen, and the value of the specific heat of thinner membranes becomes larger than that of thicker ones demonstrating a significant contribution coming from the surface. We show that this high value of the specific…

Microwave nanobolometer based on proximity Josephson junctions

We introduce a microwave bolometer aimed at high-quantum-efficiency detection of wave packet energy within the framework of circuit quantum electrodynamics, the ultimate goal being single microwave photon detection. We measure the differential thermal conductance between the detector and its heat bath, obtaining values as low as $5\phantom{\rule{4.pt}{0ex}}\text{fW}/\mathrm{K}$ at $50\phantom{\rule{4.pt}{0ex}}\text{mK}$. This is one tenth of the thermal conductance quantum and corresponds to a theoretical lower bound on noise-equivalent power of order ${10}^{\ensuremath{-}20}\phantom{\rule{4.pt}{0ex}}\text{W}/\sqrt{\text{Hz}}$ at $50\phantom{\rule{4.pt}{0ex}}\text{mK}$. By measuring the dif…

Two-dimensional phononic thermal conductance in thin membranes in the Casimir limit

We discuss computational analysis of phononic thermal conduction in the suspended membrane geometry, in the experimentally commonly appearing case where heat can flow out radially in two dimensions from a central source. As we are mostly interested in the low-temperature behavior where bulk scattering of phonons becomes irrelevant, we study the limit where all phonon scattering takes place at the membrane surfaces. Moreover, we limit the discussion here to the case where this surface scattering is fully diffusive, the so called Casimir limit. Our analysis shows that in the two-dimensional case, no analytic results are available, in contrast to the well known 1D Casimir limit. Numerical solu…

Broadband Ultrahigh-Resolution Spectroscopy of Particle-Induced X Rays: Extending the Limits of Nondestructive Analysis

Nondestructive analysis (NDA) based on x-ray emission is widely used, for example, in the semiconductor and concrete industries. Here, we demonstrate significant quantitative and qualitative improvements in broadband x-ray NDA by combining particle-induced emission with detection based on superconducting microcalorimeter arrays. We show that the technique offers great promise in the elemental analysis of thin-film and bulk samples, especially in the difficult cases where tens of different elements with nearly overlapping emission lines have to be identified down to trace concentrations. We demonstrate the efficiency and resolving capabilities by spectroscopy of several complex multielement …

Infrared pulsed laser deposition of niobium nitride thin films

We have successfully fabricated superconducting niobium nitride thin films on single crystals of magnesium oxide using a pulsed laser deposition technique where 1064 nm (photon energy ~1.16 eV) laser pulses from an Nd:YAG laser were used for ablation. A correlation between the superconducting transition temperature, the nitrogen base pressure during deposition and the lattice parameter of the produced NbN films was observed. Superconductor-insulator-normal metal junctions fabricated using these NbN films as the superconductor revealed nonlinear electrical characteristics at 4.2 K associated with quasiparticle tunneling.

Analytical models for the pulse shape of a superconductor-ferromagnet tunnel junction thermoelectric microcalorimeter

AbstractThe superconductor-ferromagnet thermoelectric detector (SFTED) is a novel ultrasensitive radiation detector based on the giant thermoelectric effect in superconductor-ferromagnet tunnel junctions. We demonstrate analytical models and solutions in the time domain for a SFTED operated as a microcalorimeter (pulse excitation), in the linear small-signal limit. Based on these solutions, the signal current and temperature pulse response were studied for two different electrical circuit models, providing design conditions for stable and non-oscillatory response.Kindly check and confirm whether the corresponding author is correctly identified.The corresponding author is correct. 

Nanosecond voltage pulses from dendritic flux avalanches in superconducting NbN films

Combined voltage and magneto-optical study of magnetic flux flow in superconducting NbN films is reported. The nanosecond-scale voltage pulses appearing during thermomagnetic avalanches have been recorded in films partially coated by a metal layer. Simultaneous magneto-optical imaging and voltage measurements allowed the pulses to be associated with individual flux branches penetrating the superconductor below the metal coating. From detailed characteristics of pulse and flux branches, the electrical field in the superconductor is found to be in the range of 5-50 kV/m, while the propagation speed of the avalanche during its final stage is found to be close to 5 km/s. peerReviewed

High quality superconducting titanium nitride thin film growth using infrared pulsed laser deposition

Transition-Edge Sensors for Particle Induced X-ray Emission Measurements

In this paper we present a new measurement setup, where a transitionedge sensor detector array is used to detect X-rays in particle induced X-ray emission measurements with a 2 MeV proton beam. Transition-edge sensors offer orders of magnitude improvement in energy resolution compared to conventional silicon or germanium detectors, making it possible to recognize spectral lines in materials analysis that have previously been impossible to resolve, and to get chemical information from the elements. Our sensors are cooled to the operation temperature (65 mK) with a cryogen-free adiabatic demagnetization refrigerator, which houses a specially designed X-ray snout that has a vacuum tight window…

High-quality superconducting titanium nitride thin film growth using infra-red pulsed laser deposition

Superconducting titanium nitride (TiN) thin films were deposited on magnesium oxide, sapphire and silicon nitride substrates at 700 °C, using a pulsed laser deposition (PLD) technique, where infrared (1064 nm) pulses from a solid-state laser were used for the ablation from a titanium target in a nitrogen atmosphere. Structural studies performed with x-ray diffraction showed the best epitaxial crystallinity for films deposited on MgO. In the best films, superconducting transition temperatures, T C, as high as 4.8 K were observed, higher than in most previous superconducting TiN thin films deposited with reactive sputtering. A room temperature resistivity down to ~17 μΩ cm and residual resist…

Simultaneous Noise and Impedance Fitting to Transition-Edge Sensor Data using Differential Evolution

We discuss a robust method to simultaneously fit a complex model both to the complex impedance and the noise data for transition-edge sensors (TES). It is based on a differential evolution (DE) algorithm, providing accurate and repeatable results with only a small increase in computational cost compared to the standard least squares (LS) fitting method. Test fits are made using both DE and LS methods, and the results compared with previously determined best fits, with varying initial value deviations and limit ranges for the parameters. The robustness of DE is demonstrated with successful fits even when parameter limits up to a factor of 5 from the known values were used. It is shown that t…

Bio-imaging with the helium-ion microscope: A review

Scanning helium-ion microscopy (HIM) is an imaging technique with sub-nanometre resolution and is a powerful tool to resolve some of the tiniest structures in biology. In many aspects, the HIM resembles a field-emission scanning electron microscope (FE-SEM), but the use of helium ions rather than electrons provides several advantages, including higher surface sensitivity, larger depth of field, and a straightforward charge-compensating electron flood gun, which enables imaging of non-conductive samples, rendering HIM a promising high-resolution imaging technique for biological samples. Starting with studies focused on medical research, the last decade has seen some particularly spectacular …

Optimizing the operating temperature of a transition edge sensor

We discuss the theory for optimizing the operating temperature of a voltage biased superconducting transition edge sensor (TES) in terms of energy resolution and speed, considering only internal detector noise sources. The noise processes included in the modeling are the unavoidable Johnson and phonon noise. The phonon noise is calculated for the case of ballistic transport. If other external and excess internal noise sources are not dominant, an optimal operating temperature can be found to minimize the energy resolution. The detector slows down by approximately a factor of two at the optimal energy resolution point.

Bacteriophage imaging : past, present and future

The visualization of viral particles only became possible after the advent of the electron microscope. The first bacteriophage images were published in 1940 and were soon followed by many other publications that helped to elucidate the structure of the particles and their interaction with the bacterial hosts. As sample preparation improved and new technologies were developed, phage imaging became important approach to morphologically classify these viruses and helped to understand its importance in the biosphere. In this review we discuss the main milestones in phage imaging, how it affected our knowledge on these viruses and recent developments in the field. peerReviewed

Antibacterial Efficiency of Surface-Immobilized Flavobacterium-Infecting Bacteriophage

Control of bacterial diseases by bacteriophages (phages) is gaining more interest due to increasing antibiotic resistance. This has led to technologies to attach phages on surfaces to form a biomaterial that can functionally display phages that interact with bacteria, to carry out successful infection cycles. Such a material could be applied in many environments, where the target pathogens are expected. Although this approach has been applied successfully in a few studies already, the basis of the antibacterial effect by the immobilized phages is unclear, and the interpretation of the results depends on the study. Here, we studied the phage attachment density, their detachment rate and infe…

Phonon Cooling of Nanomechanical Beams with Tunnel Junctions

We demonstrate electronic cooling of 1D phonon modes in suspended nanowires for the first time, using normal-metal-insulator-superconductor (N-I-S) tunnel junctions. Simultaneous cooling of both electrons and phonons to a common temperature was achieved. In comparison with nonsuspended devices, better cooling performance is achieved in the whole operating range of bath temperatures between 0.1-0.7 K. The observed low-temperature thermal transport characteristics are consistent with scattering of ballistic phonons at the nanowire-bulk contact as being the mechanism limiting thermal transport. At the lowest bath temperature of the experiment approximately 100 mK, both phonons and electrons in…

Bioimaging: Imaging Bacterial Colonies and Phage-Bacterium Interaction at Sub-Nanometer Resolution Using Helium-Ion Microscopy (Adv. Biosys. 8/2017)

A new beamline for energy-dispersive high-resolution PIXE analysis using polycapillary optics

Abstract A new beamline for high energy resolution PIXE measurements is presented. This new setup includes options for both in-air and vacuum measurements. For the high energy resolution transition-edge sensor array, a polycapillary lens is used for detecting low-energy X-rays down to 0.5 keV and to increase the effective solid angle. X-ray transmission of the polycapillary lens was characterized using two calibration standards. The gain obtained by adding a polycapillary lens was 1.6–2.3 at energies between 2.1 keV and 4.5 keV. From 1.04 to 1.74 keV the gain is increased to 2.1–3.0, and at energies 4.9–8.0 keV the gain is between 1.6 and 0.65. The measured gain agreed well with theoretical…

Reentrant stability of superconducting films and the vanishing of dendritic flux instability

We propose a mechanism responsible for the abrupt vanishing of the dendritic flux instability found in many superconducting films when an increasing magnetic field is applied. The onset of flux avalanches and the subsequent reentrance of stability in NbN films were investigated using magneto-optical imaging, and the threshold fields were measured as functions of critical current density ${j}_{c}$. The results are explained with excellent quantitative agreement by a thermomagnetic model published recently [D. V. Denisov et al., Phys. Rev. B 73, 014512 (2006)], showing that the reentrant stability is a direct consequence of a monotonously decreasing ${j}_{c}$ versus field.

Ballistic phonon transport in dielectric membranes

We have calculated the ballistic phononic heat transport in dielectric membranes as a function of radiator temperature and membrane thickness. The phonon modes of such membranes are known as Lamb-modes from elasticity theory. The striking result is that, for a fixed temperature, the radiated power first decreases with decreasing membrane thickness, but then develops a minimum when the transition to two dimensionality is reached. Further decrease of the membrane thickness in the 2D limit leads to increasing radiated power.

Direct measurement of the electron‐phonon relaxation rate in thin copper films

We have used normal metal-insulator-superconductor (NIS) tunnel junction pairs, known as SINIS structures, for ultrasensitive thermometry at sub-Kelvin temperatures. With the help of these thermometers, we have developed an ac-technique to measure the electron-phonon (e-p) scattering rate directly, without any other material or geometry dependent parameters, based on overheating the electron gas. The technique is based on Joule heating the electrons in the frequency range DC-10 MHz, and measuring the electron temperature in DC. Because of the nonlinearity of the electron-phonon coupling with respect to temperature, even the DC response will be affected, when the heating frequency reaches th…

Response time of a thermometer based on normal metal–insulator–superconductor (NIS) tunnel junctions

Abstract We have measured the thermal response of a superconductor–normal metal–superconductor (SINIS) tunnel junction structure at substrate temperature ∼60 mK by directly heating the electron system in the normal metal island. In our structure, we find the response time is determined by the electron–phonon coupling in the electron temperature range 300– 600 mK . By using AC heating, the cut-off frequency caused by this response time has been measured, showing that SINIS structures operate as a thermometer up to a few MHz in this temperature range.

Normal metal - insulator - superconductor thermometers and coolers with titanium-gold bilayer as the normal metal

We have fabricated superconductor - insulator - normal metal - insulator - superconductor (SINIS) tunnel junctions in which Al acts as the superconductor, AlOx is the insulator, and the normal metal consists of a thin Ti layer (5 nm) covered with a thicker Au layer (40 nm). We have characterized the junctions by measuring their current-voltage curves between 60 mK and 750 mK. For comparison, the same measurements have been performed for a SINIS junction pair whose normal metal is Cu. The Ti-Au bilayer decreases the SINIS tunneling resistance by an order of magnitude compared to junctions where Cu is used as normal metal, made with the same oxidation parameters. The Ti-Au devices are much mo…

Low-Temperature Coherent Thermal Conduction in Thin Phononic Crystal Membranes

In recent years, the idea of controlling phonon thermal transport coherently using phononic crystals has been introduced. Here, we extend our previous numerical studies of ballistic low-temperature heat transport in two-dimensional hole-array phononic crystals, and concentrate on the effect of the lattice periodicity. We find that thermal conductance can be either enhanced or reduced by large factors, depending on the the lattice period. Analysis shows that both the density of states and the average group velocity are strongly affected by the periodic structuring. The largest effect for the reduction seen for larger period structures comes from the strong reduction of the group velocities, …

Nanofabrication on 2D and 3D Topography via Positive‐Tone Direct‐Write Laser Lithography

Direct laser writing (DLW) lithography using two‐photon absorption is a powerful technique mostly used for fabrication of complex structures in micro‐ and nanoscale, by photopolymerizing a negative‐tone resist. In contrast, in this study it is demonstrated that DLW is also well suited for fabricating nano‐ to microscale metallic structures using lift‐off and a positive‐tone photoresist. It is shown first that versatile, fast and large area fabrication is possible on flat two‐dimensional insulating substrates, and an expression for how the line width varies with the scanning speed is derived, with excellent agreement with the experiments. Even more interestingly, a unique application for the…

Complete stabilization and improvement of the characteristics of tunnel junctions by thermal annealing

We have observed that submicron sized Al--AlO{$_x$}--Al tunnel junctions can be stabilized completely by annealing them in vacuum at temperatures between $350^{\circ}$C and $450^{\circ}$C. In addition, low temperature characterization of the samples after the annealing treatment showed a marked improvement of the tunneling characteristics due to disappearance of unwanted resonances in the current. Charging energy, tunneling resistance, barrier thickness and height all increase after the treatment. The superconducting gap is not affected, but supercurrent is reduced in accordance with the increase of tunneling resistance.

Development of an Inductive NIS Thermometer

We have studied an inductive readout for normal metal-insulator-superconductor (NIS) tunnel junctions by using on-chip planar inductors and a DC SQUID (superconducting quantum interference device) to develop a sensitive and fast thermometer for studies of nanoscale heat conduction and bolometry. Our initial results show the feasibility of the concept, with a good sensitivity for temperatures below 1 K for aluminum as the superconductor when voltage biased close to the superconductor energy gap. peerReviewed

Metal frame as local protection of superconducting films from thermomagnetic avalanches

Thermomagnetic avalanches in superconducting films propagating extremely fast while forming unpredictable patterns, represent a serious threat for the performance of devices based on such materials. It is shown here that a normal-metal frame surrounding a selected region inside the film area can provide efficient protection from the avalanches during their propagation stage. Protective behavior is confirmed by magneto-optical imaging experiments on NbN films equipped with Cu and Al frames, and also by performing numerical simulations. Experimentally, it is found that while conventional flux creep is not affected by the frames, the dendritic avalanches are partially or fully screened by them…

Large 256-Pixel X-ray Transition-Edge Sensor Arrays With Mo/TiW/Cu Trilayers

We describe the fabrication and electrical characterization of 256-pixel X-ray transition-edge sensor (TES) arrays intended for materials analysis applications. The processing is done on 6-in wafers, providing capabilities on a commercial scale. TES films were novel proximity coupled Mo/TiW/Cu trilayers, where the thin TiW layer in between aims to improve the stability of the devices by preventing unwanted effects such as Mo/Cu interdiffusion. The absorber elements were electrodeposited gold of thickness 2 μm. The single-pixel design discussed here is the so-called Corbino geometry. Most design goals were successfully met, such as the critical temperature, thermal time constant, and transit…

Heavy ion induced Ti X-ray satellite structure for Ti, TiN, and TiO2 thin films

Minimizing coherent thermal conductance by controlling the periodicity of two-dimensional phononic crystals

Periodic hole array phononic crystals (PnC) can strongly modify the phonon dispersion relations, and have been shown to influence thermal conductance coherently, especially at low temperatures where scattering is suppressed. One very important parameter influencing this effect is the period of the structure. Here, we measured the sub-Kelvin thermal conductance of nanofabricated PnCs with identical hole filling factors, but three different periodicities, 4, 8, and 16 $\mu$m, using superconducting tunnel junction thermometry. We found that all the measured samples can suppress thermal conductance by an order of magnitude, and have a lower thermal conductance than the previously measured small…

Low temperature heat capacity of phononic crystal membranes

Phononic crystal (PnC) membranes are a promising solution to improve sensitivity of bolometric sensor devices operating at low temperatures. Previous work has concentrated only on tuning thermal conductance, but significant changes to the heat capacity are also expected due to the modification of the phonon modes. Here, we calculate the area-specific heat capacity for thin (37.5 - 300 nm) silicon and silicon nitride PnC membranes with cylindrical hole patterns of varying period, in the temperature range 1 - 350 mK. We compare the results to two- and three-dimensional Debye models, as the 3D Debye model is known to give an accurate estimate for the low-temperature heat capacity of a bulk sam…

Lab-based Ultrafast Molecular Structure

The proliferation of various laser-driven approaches to sub-picosecond hard X-ray and short-wavelength radiation generation in the past few decades has opened many avenues for the laboratory-based development of traditionally facility-based short wavelength ultrafast molecular structure science. Together with the introduction of microcalorimeter detection schemes, this opens the floodgates to widespread, decentralized implementation of what were until recently specialist short wavelength techniques. A parallel situation exists for the contemporary adoption of sub-wavelength resolution optical microscopies. In what follows, a few ultrafast molecular structure developments and their rationale…

Applications and non-idealities of submicron Al–AlOx–Nb tunnel junctions

We have developed a technique to fabricate sub-micron, 0.6µm×0.6µm Al-AlOx-Nb tunnel junctions using a standard e-beam resist, angle evaporation and double oxidation of the tunneling barrier, resulting in high quality niobium, as determined by the the high measured values of the critical temperature TC ∼ 7.5 K and the gap ∆ ∼ 1.3 meV. The devices show great promise for local nanoscale thermometry in the temperature range 1 - 7.5 K. Electrical characterization of the junctions was performed at sub-Kelvin temperatures both with and without an external magnetic field, which was used to suppress superconductivity in Al and thus bring the junction into a normal-metal-insulator-superconductor (NI…

Ray optics behavior of flux avalanche propagation in superconducting films

Experimental evidence of wave properties of dendritic flux avalanches in superconducting films is reported. Using magneto-optical imaging the propagation of dendrites across boundaries between a bare NbN film and areas coated by a Cu layer was visualized, and it was found that the propagation is refracted in full quantitative agreement with Snell's law. For the studied film of 170 nm thickness and a $0.9\phantom{\rule{0.28em}{0ex}}\ensuremath{\mu}\mathrm{m}$ thick metal layer, the refractive index was close to $n=1.4$. The origin of the refraction is believed to be caused by the dendrites propagating as an electromagnetic shock wave, similar to damped modes considered previously for normal …

Engineering thermal conductance using a two-dimensional phononic crystal

Controlling thermal transport has become relevant in recent years. Traditionally, this control has been achieved by tuning the scattering of phonons by including various types of scattering centres in the material (nanoparticles, impurities, etc). Here we take another approach and demonstrate that one can also use coherent band structure effects to control phonon thermal conductance, with the help of periodically nanostructured phononic crystals. We perform the experiments at low temperatures below 1 K, which not only leads to negligible bulk phonon scattering, but also increases the wavelength of the dominant thermal phonons by more than two orders of magnitude compared to room temperature…

Imaging and Ion-Beam Milling of Biological Specimens with the Helium-Ion Microscope

Imaging Bacterial Colonies and Phage-Bacterium Interaction at Sub-Nanometer Resolution Using Helium-Ion Microscopy

Imaging of microbial interactions has so far been based on well‐established electron microscopy methods. This study presents a new way to study bacterial colonies and interactions between bacteria and their viruses, bacteriophages (phages), in situ on agar plates using helium ion microscopy (HIM). In biological imaging, HIM has advantages over traditional scanning electron microscopy with its sub‐nanometer resolution, increased surface sensitivity, and the possibility to image nonconductive samples. Furthermore, by controlling the He beam dose or by using heavier Ne ions, the HIM instrument provides the possibility to mill out material in the samples, allowing for subsurface imaging and in …

Observation of disorder-induced weakening of electron-phonon interaction in thin noble-metal films

We have used symmetric normal metal-insulator-superconductor (NIS) tunnel junction pairs, known as SINIS structures, for ultrasensitive thermometry in the temperature range 50 - 700 mK. By Joule heating the electron gas and measuring the electron temperature, we show that the electron-phonon (e-p) scattering rate in the simplest noble metal disordered thin films (Cu,Au) follows a $T^4$ temperature dependence, leading to a stronger decoupling of the electron gas from the lattice at the lowest temperatures. This power law is indicative e-p coupling mediated by vibrating disorder, in contrast to the previously observed $T^3$ and $T^2$ laws.

Energy of dendritic avalanches in thin-film superconductors

A method for calculating stored magnetic energy in a thin superconducting film based on quantitative magneto-optical imaging is developed. Energy and magnetic moment are determined with these calculations for full hysteresis loops in a thin film of the superconductor NbN. Huge losses in energy are observed when dendritic avalanches occur. Magnetic energy, magnetic moment, sheet current and magnetic flux distributions, all extracted from the same calibrated magneto-optical images, are analyzed and discussed. Dissipated energy and the loss in moment when dendritic avalanches occur are related to each other. Calculating these losses for specific spatially-resolved flux avalanches is a great ad…

Superconductor-ferromagnet tunnel junction thermoelectric bolometer and calorimeter with a SQUID readout

Superconductor-ferromagnet thermoelectric detector (SFTED) is a novel ultrasensitive radiation detector based on the giant thermoelectric effect in superconductor-ferromagnet tunnel junctions. This type of detector can be operated without the need of additional bias lines, and is predicted to provide a performance rivaling transition-edge sensors and kinetic inductance detectors. Here we report our numerical studies on the SFTED noise equivalent power, energy resolution and time constant, and the feasibility of a SQUID readout in both bolometric and calorimetric regimes, with the goal to provide practical design parameters for the detector fabrication and the readout circuitry implementatio…

Beating Darwin-Bragg losses in lab-based ultrafast x-ray experiments

The use of low temperature thermal detectors for avoiding Darwin-Bragg losses in lab-based ultrafast experiments has begun. An outline of the background of this new development is offered, showing the relevant history and initiative taken by this work. (C) 2017 Author(s). Funding Agencies|Knut and Alice Wallenberg Foundation; ERC [226136]; Finnish Funding Agency for Technology and Innovation TEKES; Academy of Finland [260880]; NIST Innovations in Measurement Science program; DOE Office of Basic Energy Sciences

Effective medium theory for the low-temperature heat capacity of a metasolid plate

Nanopatterning can be used to strongly control the thermal properties of solids, but theoretical understanding relies often on complex numerical simulations. Here, an analytical theory is derived for the low temperature heat capacity of a nanopatterned phononic crystal plate, focusing on the geometry of a square lattice of cylindrical holes in an isotropic matrix material. Its quasistatic elastic properties were studied using an anisotropic effective medium theory, that is, considering it as a homogenized metasolid. The effective elastic parameters can then be used as an input for an anisotropic plate theory, yielding analytical expressions for the dispersion relations of the three lowest p…

Thermoelectric Radiation Detector Based on Superconductor-Ferromagnet Systems

We suggest an ultrasensitive detector of electromagnetic fields exploiting the giant thermoelectric effect recently found in superconductor-ferromagnet hybrid structures. Compared with other types of superconducting detectors where the detected signal is based on variations of the detector impedance, the thermoelectric detector has the advantage of requiring no external driving fields. This is especially relevant in multipixel detectors, where the number of bias lines and the heating induced by them are an issue. We propose different material combinations to implement the detector and provide a detailed analysis of its sensitivity and speed. In particular, we perform a proper noise analysis…

Superconducting tunnel junction fabrication on three-dimensional topography via direct laser writing

Superconducting junctions are widely used in multitude of applications ranging from quantum information science and sensing to solid-state cooling. Traditionally, such devices must be fabricated on flat substrates using standard lithographic techniques. In this study, we demonstrate a highly versatile method that allows for superconducting junctions to be fabricated on a more complex topography. It is based on maskless direct laser writing (DLW) two-photon lithography, which allows writing in 3D space. We show that high-quality normal metal-insulator-superconductor (NIS) tunnel junctions can be fabricated on top of a 20 $\mu$m tall three-dimensional topography. Combined with more advanced r…

Ray optics behavior of flux avalanche propagation in superconducting films

Experimental evidence of wave properties of dendritic flux avalanches in superconducting films is reported. Using magneto-optical imaging the propagation of dendrites across boundaries between a bare NbN film and areas coated by a Cu layer was visualized, and it was found that the propagation is refracted in full quantitative agreement with Snell’s law. For the studied film of 170 nm thickness and a 0.9 μm thick metal layer, the refractive index was close to n = 1.4. The origin of the refraction is believed to be caused by the dendrites propagating as an electromagnetic shock wave, similar to damped modes considered previously for normal metals. The analogy is justified by the large dissipa…

Electron-phonon interaction in thin copper and gold films

We have studied the electron-phonon (e-p) interaction in thin Cu and Au films at sub-Kelvin temperatures with the help of the hot electron effect, using symmetric normal metal-insulator-superconductor tunnel junction pairs as thermometers. By Joule heating the electron gas and measuring the electron and the lattice temperatures simultaneously, we show that the electron-phonon scattering rate follows a $T^{4}$ temperature dependence in both metals. The result is in accordance with the theory of e-p scattering in disordered films with vibrating boudaries and impurities, in contrast to the $T^{3}$-law expected for pure samples, and $T^{2}$-law for static disorder.

Table-top ultrafast X-ray microcalorimeter spectrometry for molecular structure

This work presents an x-ray absorption measurement by use of ionizing radiation generated by a femtosecond pulsed laser source. The spectrometer was a microcalorimetric array whose pixels are capable of accurately measuring energies of individual radiation quanta. An isotropic continuum x-ray spectrum in the few-keV range was generated from a laser plasma source with a water-jet target. X rays were transmitted through a ferrocene powder sample to the detector, whose pixels have average photon energy resolution E ¼ 3:14 eV full-width-at-half-maximum at 5.9 keV. The bond distance of ferrocene was retrieved from this first hard-x-ray absorption fine-structure spectrum collected with an energyd…

Maximizing phonon thermal conductance for ballistic membranes

At low temperatures, phonon scattering can become so weak that phonon transport becomes ballistic. We calculate the ballistic phonon conductance G for membranes using elasticity theory, considering the transition from three to two dimensions. We discuss the temperature and thickness dependence and especially concentrate on the issue of material parameters. For all membrane thicknesses, the best conductors have, counter-intuitively, the lowest speed of sound.